Search results for "Stability."

Trapping Amorphous Intermediates of Carbonates – A Combined Total Scattering and NMR Study

2018

Crystallization via metastable phases plays an important role in chemical manufacturing, biomineralization, and protein crystallization, but the kinetic pathways leading from metastable phases to the stable crystalline modifications are not well understood. In particular, the fast crystallization of amorphous intermediates makes a detailed characterization challenging. To circumvent this problem, we devised a system that allows trapping and stabilizing the amorphous intermediates of representative carbonates (calcium, strontium, barium, manganese, and cadmium). The long-term stabilization of these transient species enabled a detailed investigation of their composition, structure, and morpho…

Erratum to “Cerium effect on the phase structure, phase stability and redox properties of Ce-doped strontium ferrates”

2008

Structural Stability

2020

The notion of structural stability was first introduced by the Russian math- ematicians Alexandr Andronov and Lev Pontryagin (cf. Andronov and Potryangin 1937). However, there are traces of such a concept in the work of the French math- ematician Henry Poincaré (cf. Poincaré 1880). In more recent years, interesting developments about structural stability included writings of important math- ematicians like Mauricìo Peixoto (cf. at least Peixoto 1960), Stephen Smale (cf. at least Smale 1971) and René Thom (1972, 1980) (see structural morpho- dynamics). From an intuitive point of view, structural stability refers to a particular systemic property known as robustness. Put in general terms, a s…

Physically based modeling of rainfall-triggered landslides: a case study in the Luquillo forest, Puerto Rico

2013

This paper presents the development of a rainfall-triggered landslide module within an existing physically based spatially distributed ecohydrologic model. The model, tRIBS-VEGGIE (Triangulated Irregular Networks-based Real-time Integrated Basin Simulator and Vegetation Generator for Interactive Evolution), is capable of a sophisticated description of many hydrological processes; in particular, the soil moisture dynamics are resolved at a temporal and spatial resolution required to examine the triggering mechanisms of rainfall-induced landslides. The validity of the tRIBS-VEGGIE model to a tropical environment is shown with an evaluation of its performance against direct observations made w…

On new means with interesting practical applications: Generalized power means

2021

Means of positive numbers appear in many applications and have been a traditional matter of study. In this work, we focus on defining a new mean of two positive values with some properties which are essential in applications, ranging from subdivision and multiresolution schemes to the numerical solution of conservation laws. In particular, three main properties are crucial—in essence, the ideas of these properties are roughly the following: to stay close to the minimum of the two values when the two arguments are far away from each other, to be quite similar to the arithmetic mean of the two values when they are similar and to satisfy a Lipchitz condition. We present new means with these pr…

Solvent-free ball-milling subcomponent synthesis of metallosupramolecular complexes.

2015

Subcomponent self-assembly from components A, B, C, D, and Fe(2+) under solvent-free conditions by self-sorting leads to the construction of three structurally different metallosupramolecular iron(II) complexes. Under carefully selected ball-milling conditions, tetranuclear [Fe4 (AD2 )6 ](4-) 22-component cage 1, dinuclear [Fe2 (BD2 )3 ](2-) 11-component helicate 2, and 5-component mononuclear [Fe(CD3 )](2+) complex 3 were prepared simultaneously in a one-pot reaction from 38 components. Through subcomponent substitution reaction by adding subcomponent B, the [Fe4 (AD2 )6 ](4-) cage converts quantitatively to the [Fe2 (BD2 )3 ](2-) helicate, which, in turn, upon addition of subcomponent C, …

Light-driven proton transport of bacteriorhodopsin incorporated into long-term stable liposomes of a polymerizable sulfolipid

1983

Abstract The chromoprotein bacteriorhodopsin from Halobacterium halobium has been incorporated into liposomes made of a fully synthetic, polymerizable lipid. Bacteriorhodopsin is found to be active in these polymer liposomes. The advantage in the use of such polymer systems concerning long-term stability in comparison with liposomes made of natural lipid is demonstrated.

Extreme sensitivity of superconductivity to stoichiometry in Fe1+?Se

2009

The recently discovered iron arsenide superconductors appear to display a universal set of characteristic features, including proximity to a magnetically ordered state and robustness of the superconductivity in the presence of disorder. Here we show that superconductivity in Fe1+?Se, which can be considered the parent compound of the superconducting arsenide family, is destroyed by very small changes in stoichiometry. Further, we show that nonsuperconducting Fe1+?Se is not magnetically ordered down to 5 K. These results suggest that robust superconductivity and immediate instability against an ordered magnetic state should not be considered as intrinsic characteristics of iron-based superco…

Vortex instability and vortex-glass transition in Bi 2 Sr 2 CaCu 2 O 8 and YBa 2 Cu 3 O 7 thin films

2000

We investigated the current-voltage (I-V) curves of high-T c superconductors at very low and very high dissipation levels. In the limit of low driving currents the barriers for vortex movement become infinite in the vortex-glass state. Using long measurement bridges up to 0.5 m we were able to sample an electric field range from 1 V/m down to 10 -8 V/m in one experimental setup. The resulting I-V curves allowed us to verify an excellent glass scaling of the I-V curves, which revealed an increased dynamical exponent of the glass transition. We also found a considerable dependence of the vortex-glass scaling on the probed electric-field range. At very high dissipation levels the I-V curves of…

Origin of the fast magnetization relaxation at low temperatures in HTS with strong pinning

2010

The temperature T variation of the normalized magnetization relaxation rate S in high-temperature superconductors (HTS) with strong vortex pinning exhibits a maximum in the low-T range. This was reported for various HTS, and the origin of the faster relaxation at low T appearing in standard magnetization relaxation measurements was usually related to specific pinning properties of the investigated specimens. Since the observed behaviour seems to be characteristic to all HTS with enhanced pinning (generated by random and/or correlated disorder), we show that the S(T) maximum can be explained in terms of classic collective vortex creep. The influence of thermo-magnetic instabilities in the lo…