Search results for "Stability."
showing 10 items of 3015 documents
Interplay of acidity and ionic liquid structure on the outcome of a heterocyclic rearrangement reaction
2021
The study of suitable probe reactions is a powerful tool to investigate the properties of nonconventional solvents such ionic liquids (ILs). In particular, we studied the acid-catalyzed mononuclear rearrangement of heterocycles (MHR) of the Z-phenylhydrazone of 5-amino-3-benzoyl-1,2,4-oxadiazole into the relevant 1,2,3-triazole, in solution of ILs by means of kinetic measurements. We chose as solvents six ILs differing both in the cation and anion, in the presence of five carboxylic and sulfonic acids as catalysts. For a useful comparison, the reaction was also performed in 1,4-dioxane and methanol. In general, the reaction occurs faster in ILs, compared to conventional solvents, according …
Lignin recovery from spent alkaline pulping liquors using acidification, membrane separation, and related processing steps: A Review
2019
The separation of lignin from the black liquor generated during alkaline pulping is reviewed in this article with an emphasis on chemistry. Based on published accounts, the precipitation of lignin from spent pulping liquor by addition of acids can be understood based on dissociation equilibria of weak acid groups, which affects the solubility behavior of lignin-related chemical species. Solubility issues also govern lignin separation technologies based on ultrafiltration membranes; reduction in membrane permeability is often affected by conditions leading to decreased solubility of lignin decomposition products and the presence of colloidal matter. Advances in understanding of such phenomen…
Modeling the hydrological and mechanical effect of roots in shallow landslide analysis
2015
The additional cohesion exercised by vegetation roots (cr) provides an important contribution to the slope stability. This study proposes a methodology for estimating the cr term in a hillslope landslide analysis within a coupled ecohydrological-stability model. The coupled model simulates the spatial distribution and temporal dynamics of the Factor of Safety (FS) as a function of soil moisture dynamics, by taking into account the hydrological effects of vegetation through the root water uptaking. The additional mechanical root cohesion is estimated in a Fiber Bundle Model framework that allows for the evaluation of the root strength as a function of stress-strain relationships of populatio…
Hydrological and mechanical effects of roots in shallow landslide analysis: A physically-based approach
2015
This study provides the first insights of a methodology for estimating the additional cohesion exercised by vegetation roots in a hillslope landslide analysis within a coupled ecohydrological-stability model. The existing coupled system is able to simulate the spatial distribution and temporal dynamics of Factor of Safety (FS) as a function of soil moisture dynamics. The model takes into account the hydrological effects of vegetation which, through the root water uptaking, contributes in reducing the soil water content and, thus, in increasing the slope stability. The additional mechanical root cohesion is estimated in a Fiber Bundle Model (FBM) framework that allows for the evaluation of t…
Photoactivity and Chemical Reactivity in Titanium(IV)-Organic Frameworks
2020
La presente tesis doctoral ha sido realizada como compendio de publicaciones y lleva por título “Fotoactividad y reactividad química en redes metal-orgánicas de titanio(IV)” (Photoactivity and Chemical Reactivity in Titanium(IV)-Organic Frameworks). La tesis se encuentra dividida en cinco capítulos además de un capítulo final de conclusiones y un resumen en castellano. El primer capítulo trata de una introducción acerca de las redes metal-orgánicas (del inglés Metal-Organic Frameworks, MOFs) de titanio(IV) existentes hasta la fecha para dar una visión general de su variedad estructural, así como de las estrategias sintéticas empleadas y las propiedades fotocatalíticas de estos materiales. E…
Pattern formation in hyperbolic reaction-transport systems and applications to dryland ecology
2023
Pattern formation and modulation is an active branch of mathematics, not only from the perspective of fundamental theory but also for its huge applications in many fields of physics, ecology, chemistry, biology, and other sciences. In this thesis, the occurrence of Turing and wave instabilities, giving rise to stationary and oscillatory patterns, respectively, is theoretically investigated by means of two-compartment reaction-transport hyperbolic systems. The goal is to elucidate the role of inertial times, which are introduced in hyperbolic models to account for the finite-time propagation of disturbances, in stationary and transient dynamics, in supercritical and subcritical regimes. In p…
Anterolateral thigh perforator flap made by customized 3D-printing fabrication of fixed positioning guide for oromaxillofacial reconstruction:a preli…
2022
Oromaxillofacial carcinomas frequently result in serious tissue defect due to enlarged resection for treating their extensive invasion, which require challenging reconstruction. Three-dimensional (3D) printing is an advanced technology which has greatly promoted the progress of craniomaxillofacial reconstructive surgery. This present study aimed to investigate the advantages of anterolateral thigh (ALT) perforator flap manufactured by 3D printing fixed positioning guide template in curing oromaxillofacial defect. Twenty patients with oromaxillofacial defects resulted from severe primary malignant tumors were divided into experimental group assisted by digital technique (n=8) and controlled …
Optimality of Increasing Stability for an Inverse Boundary Value Problem
2021
In this work we study the optimality of increasing stability of the inverse boundary value problem (IBVP) for the Schrödinger equation. The rigorous justification of increasing stability for the IBVP for the Schrödinger equation were established by Isakov [Discrete Contin. Dyn. Syst. Ser. S, 4 (2011), pp. 631--640] and by Isakov et al. [Inverse Problems and Applications, Contemp. Math. 615, American Math Society, Providence, RI, 2014, pp. 131--141]. In [Discrete Contin. Dyn. Syst. Ser. S, 4 (2011), pp. 631--640] and [Inverse Problems and Applications, Contemp. Math. 615, American Math Society, Providence, RI, 2014, pp. 131--141], the authors showed that the stability of this IBVP increases …
Anion exchange membrane based on alkali doped poly(2,5-benzimidazole) for fuel cell
2012
Abstract The properties of alkali doped poly(2,5-benzimidazole) membrane with different alkali doping levels for fuel cell application are reported in this work. The alkali doping level played an important role for the ion conductivity of the membrane. The ion conductivity significantly increased with alkali doping level. The ion conductivity also increased with the temperature. The ion conductivity of the alkali doped ABPBI membrane (alkali doping level = 0.37), reached to 2.3 × 10 − 2 S cm − 1 at room temperature and 7.3 × 10 − 2 S cm − 1 at 100 °C. The water uptake of the alkali doped ABPBI membrane was increased from 9.1% to 19.2% with increasing alkali doping level at room temperatur…
Pd and PdAu on mesoporous silica for methane oxidation: Effect of SO2
2007
Abstract Palladium and gold–palladium catalysts supported on mesoporous silica were prepared by incipient wetness impregnation. They were characterized by XPS, XRD, BET, and FTIR acidity measurements. The activity was tested in the oxidation of methane under lean conditions. The effect of adding SO 2 to the reactant mixture was investigated. Test reactions were consecutively performed to evaluate the thermal stability and poisoning reversibility. The palladium catalyst performed quite well in terms of the light-off temperature ( T 50 300 °C) and SO 2 tolerance. Moreover, the activity, which decreased after a night treatment in SO 2 at 350 °C, was completely recovered in subsequent cycles. …