Search results for "Stability"

Equilibrio fra poteri e libertà dai Trattati in diritto dell'Unione europea e diritto internazionale

2014

Riflessione sulla categoria civilistica dell'invalidità applicata ai Trattati internazionali e a quella peculiare species costituita dai Trattati istitutivi dell'Unione Europea. Si dà conto altresì delle modalità di modifica degli stessi e dell'estinzione.

Isomerism of [64Cu-NOTA-Bn]-labeled radiotracers: separation of two complex isomers and determination of their interconversion energy barrier using i…

2011

The model complex [(64)Cu((S)-p-NH(2)-Bn-NOTA)](-) ([(64)Cu]1) was used to study the isomerism of [(64)Cu-NOTA-Bn]-labeled radiotracers. Two complex isomers [(64)Cu]1a and [(64)Cu]1b, which were formed at a ratio of 1:9 during the complexation of [(64)Cu]Cu(2+) with (S)-p-NH(2)-Bn-NOTA, were separated using ion pair chromatography. To study the interconversion, the nonradioactive complex isomers Cu1a and Cu1b were separated and thermally treated at 90 °C in both ammonium acetate solution and deionized water. A faster interconversion rate was observed for both isomers with lower concentrations of ammonium ions. At the end of reaction, the thermodynamic Cu1a to Cu1b equilibrium ratio was 6:94…

Weak alkali and alkaline earth metal complexes of low molecular weight ligands in aqueous solution

2008

This work is aimed at reviewing the chemical literature dealing with thermodynamic aspects of the weak complex formation (species with log K values less than about 3) between alkali and alkaline earth metal ions with low molecular weight inorganic and organic ligands in aqueous solution. The following ligands (up to hexavalent anions) were examined in detail: (i) hydroxide, chloride, sulfate, carbonate and phosphate as inorganic, and (ii) carboxylates, amines, amino acids, complexones and nucleotides as organic ligands. The paper also identifies the main reasons responsible for the dispersion of the stability data on ion pairs in the literature. When possible, the trend of stability for the…

Collision induced fragmentations of multiply charged sodium bis(2-ethylhexyl)-sulfosuccinate aggregates in gas phase: neutral loss versus charge sepa…

2016

Abstract Stability and fragmentation patterns of multicharged aggregates of sodium bis(2-ethylhexyl)-sulfosuccinate (NaAOT) in gas phase have been investigated by ion mobility mass spectrometry (IM-MS) and tandem mass spectrometry (MS-MS). Positively doubly charged NaAOT aggregates show at low collision energy a preference for the loss of NaAOT molecules, whereas fragmentation through charge separation process is favored at higher collision energy. By increasing the charge state of the aggregates, the fragmentation through charge separation tends to predominate especially at low aggregation number and only charge separation fragmentation is observed for positively quadruply charged species.…

Effect of biochar on the physical and structural properties of a sandy soil

2019

Abstract Biochar application to soil can be considered as a means to improve soil quality, thereby optimizing irrigation management and reducing irrigation needs, especially in dryland regions. This paper is aimed at investigating the effect of biochar (BC) on a desert sandy soil (Al Foah, United Arab Emirates) in terms of bulk density, porosity, water retention, plant available water (AWmax), aggregate stability (AS) and specific surface area (BET-SSA). BC was produced from forest biomass (Italy). Soil water retention was measured by the High Energy Moisture Characteristic (HEMC) and by pressure plate measurements, by using BC fractions equal to 0 (soil only), 0.014, 0.091, 0.23, 0.33 and …

Myoglobin on Silica: A Case Study of the Impact of Adsorption on Protein Structure and Dynamics

2013

International audience; If protein structure and function changes upon adsorption are well documented, modification of adsorbed protein dynamics remains a blind spot, despite its importance in biological processes. The adsorption of metmyoglobin on a silica surface was studied by isotherm measurements, microcalorimetry, circular dichroïsm, and UV-visible spectroscopy to determine the thermodynamic parameters of protein adsorption and consequent structure modifications. The mean square displacement and the vibrational densities of states of the adsorbed protein were measured by elastic and inelastic neutron scattering experiments. A decrease of protein flexibility and depletion in low freque…

Improving competitiveness, economic capital and financial stability through dynamic performance management in the italian state. A new sustainable de…

2013

A comprehensive study on the atom flow in the cross-field discharge of a Hall thruster

2011

The flow properties of Xe atoms were investigated in the 1 kW class PPS100-ML Hall effect thruster by means of Doppler-shifted laser-induced fluorescence spectroscopy in the near infrared. Fluorescence spectra of the resonant level and the metastable level have been acquired inside and outside the thruster channel under several operating conditions. Analytical treatment and modelling of the measured lineshapes indicate the atom axial velocity increases inside the channel to a value well above the sound speed before decreasing quickly in the near-field plume. Numerical simulations performed with a fluid/kinetic hybrid approach allow us to explain the shape of the velocity profile. Atomic flo…

Locking Reconstruction Double Plating of Distal Humeral Fractures: How Many Screws in the Distal Ulnar Column Segment in A3 Fracture Provide Superior…

2009

Objectives: Two 90-degree configurations of locking reconstruction plates with different numbers of screws in the distal ulnar column segment of distal extra-articular humeral fractures with metaphyseal comminution (A3) were biomechanically investigated. Methods: Eight pairs of fresh-frozen human humeri were used. For paired comparison, the humeri were divided into 2 randomized groups. In both groups, double-plate osteosyntheses with locking reconstruction plates were performed in 90-degree configurations. In group 1, the posteriorly placed radial column plate exceeded the capitellum and the ulnar column plate extended into the ulnar sulcus. The ulnar plate was molded around the medial epic…

Validation of the German version of the Kujala score in patients with patellofemoral instability : a prospective multi-centre study

2017

Introduction: The Kujala score is the most frequently used questionnaire for patellofemoral disorders like pain, instability or osteoarthritis. Unfortunately, we are not aware of a validated German version of the Kujala score. The aim of our study was the translation and linguistic validation of the Kujala score in German-speaking patients with patella instability and the assessment of its measurement characteristics. Materials and methods: The German Kujala score was developed in several steps of translation. In addition to healthy controls, the Kujala German was assessed in consecutive patients undergoing reconstruction of the medial patellofemoral ligament for recurrent patellar dislocat…