Search results for "Stability"
showing 10 items of 3085 documents
Cu cluster shell structure at elevated temperatures
1991
Equilibrium structures of small (3--29)-atom Cu clusters are determined by simulated annealing, and finite-temperature ensembles are simulated by Monte Carlo techniques using the effective-medium theory for the energy calculation. Clusters with 8, 18, and 20 atoms are found to be particularly stable. The equilibrium geometrical structures are determined and found to be determined by a Jahn-Teller distortion, which is found to affect the geometry also at high temperatures. The ``magic'' clusters retain their large stability even at elevated temperatures.
High-Temperature Stable Gold Nanoparticle Catalysts for Application under Severe Conditions: The Role of TiO2 Nanodomains in Structure and Activity
2015
Metal nanoparticles with precisely controlled size are highly attractive for heterogeneous catalysis. However, their poor thermal stability remains a major concern in their application at realistic operating conditions. This paper demonstrates the possibility of synthesizing gold nanoparticles with exceptional thermal stability. This has been achieved by using a simple conventional deposition–precipitation technique. The material employed as catalyst consists of gold supported on a TiO2-impregnated SiO2 bimodal mesoporous support. The resulting material shows gold nanoparticles with a narrow size distribution around 3.0 nm, homogeneously dispersed over the TiO2/SiO2 material. Most interesti…
Seed- and wall-induced heterogeneous nucleation in charged colloidal model systems under microgravity
2011
Understanding the process that drives an undercooled fluid to the crystal state is still a challenging issue for condensed matter physics and plays a key role in designing new materials. The crystallization kinetics and the resulting polycrystalline morphology are given by a complex interplay of crystal nucleation, growth, and ripening. A great deal of progress has been made in recent years using colloidal suspensions as model systems in the study of crystallization. Close analogies to atomic systems are observed which can be exploited to address questions not accessible in atomic solidification. Here we present systematic measurements of the crystallization kinetics of a charged colloidal …
Safely Dissolvable and Healable Active Packaging Films Based on Alginate and Pectin
2019
Extensive usage of long-lasting petroleum based plastics for short-lived application such as packaging has raised concerns regarding their role in environmental pollution. In this research, we have developed active, healable, and safely dissolvable alginate-pectin based biocomposites that have potential applications in food packaging. The morphological study revealed the rough surface of these biocomposite films. Tensile properties indicated that the fabricated samples have mechanical properties in the range of commercially available packaging films while possessing excellent healing efficiency. Biocomposite films exhibited higher hydrophobicity properties compared to neat alginate films. T…
Limits of stability in supported graphene nanoribbons subject to bending
2016
Graphene nanoribbons are prone to in-plane bending even when supported on flat substrates. However, the amount of bending that ribbons can stably withstand remains poorly known. Here, by using molecular dynamics simulations, we study the stability limits of 0.5-1.9 nm wide armchair and zigzag graphene nanoribbons subject to bending. We observe that the limits for maximum stable curvatures are below ~10 deg/nm, in case the bending is externally forced and the limit is caused by buckling instability. Furthermore, it turns out that the limits for maximum stable curvatures are also below ~10 deg/nm, in case the bending is not forced and the limit arises only from the corrugated potential energy…
Poor optical stability of molecular dyes when used as absorbers in water-based tissue-simulating phantoms
2019
Biomedical optical systems and models can be easily validated by the use of tissue-simulating phantoms. They can consist of water-based turbid media which often include inks (India ink and molecular dyes) as absorbers. Optical stability of commonly exploited inks under the influence of light, pH changes and the addition of TiO2 and surfactant, was studied. We found that the exposure to ultraviolet and visible light can crucially affect the absorption properties of molecular dyes. On average, absorption peaks decreased by 47.3% in 150 exposure hours. Furthermore, dilution can affect ink’s pH and by that, its decay rate under light exposure. When TiO2 was added to the phantoms, all molecular …
Turing pattern formation in the Brusselator system with nonlinear diffusion.
2013
In this work we investigate the effect of density dependent nonlinear diffusion on pattern formation in the Brusselator system. Through linear stability analysis of the basic solution we determine the Turing and the oscillatory instability boundaries. A comparison with the classical linear diffusion shows how nonlinear diffusion favors the occurrence of Turing pattern formation. We study the process of pattern formation both in 1D and 2D spatial domains. Through a weakly nonlinear multiple scales analysis we derive the equations for the amplitude of the stationary patterns. The analysis of the amplitude equations shows the occurrence of a number of different phenomena, including stable supe…
Numerical study of blow-up and dispersive shocks in solutions to generalized Korteweg–de Vries equations
2015
Abstract We present a detailed numerical study of solutions to general Korteweg–de Vries equations with critical and supercritical nonlinearity, both in the context of dispersive shocks and blow-up. We study the stability of solitons and show that they are unstable against being radiated away and blow-up. In the L 2 critical case, the blow-up mechanism by Martel, Merle and Raphael can be numerically identified. In the limit of small dispersion, it is shown that a dispersive shock always appears before an eventual blow-up. In the latter case, always the first soliton to appear will blow up. It is shown that the same type of blow-up as for the perturbations of the soliton can be observed whic…
Further experiences on unsteady seepage flow
1973
The present paper describes the results of a study on the unsteady flow in a horizontal homogeneous filter, which is accomplished when the level of the reservoir that recharges the filter is instantly drawn up. This study was carried out at the University of Palermo Institute of Hydraulics as a part of a research program concerning artificial recharge of ground water and the geotechnical problems involving the stability of porous media subject to the variations of surrounding pressures. A numerical procedure, aiming at solving the equation of Boussinesq by a finite difference method, was adopted and an electronic computer was used. A Hele-Shaw filter model was used to carry out several expe…
Drilling Systems: Stability and Hidden Oscillations
2013
There are many mathematical models of drilling systems Despite, huge efforts in constructing models that would allow for precise analysis, drilling systems, still experience breakdowns. Due to complexity of systems, engineers mostly use numerical analysis, which may lead to unreliable results. Nowadays, advances in computer engineering allow for simulations of complex dynamical systems in order to obtain information on the behavior of their trajectories. However, this simple approach based on construction of trajectories using numerical integration of differential equations describing dynamical systems turned out to be quite limited for investigation of stability and oscillations of these s…