Search results for "Stabilization"
showing 10 items of 128 documents
A Density Functional Study of Open-Shell Cyclopentadienyl−Molybdenum(II) Complexes. A Comparison of Stabilizing Factors: Spin-Pairing, Mo−X π Bonding…
2000
International audience; The dissociation of PH3 from the 18-electron system CpMoX(PH3)3 to afford the corresponding 16-electron CpMoX(PH3)2 fragment has been investigated theoretically by density functional theory for X = H, CH3, F, Cl, Br, I, OH, and PH2. The product is found to prefer a triplet spin state for all X ligands except PH2, the singlet−triplet gap varying between 1.7 kcal/mol for OH to 8.7 kcal/mol for F. The Mo−PH3 bond dissociation energy to the 16-electron ground state varies dramatically across the series, from 4.5 kcal/mol for OH to 23.5 kcal/mol for H, and correlates with experimental observations on trisubstituted phosphine derivatives. Geometry-optimized spin doublet Cp…
OSL dating of sediments from the Gobi Desert, Southern Mongolia
2010
Abstract The present study focuses on the chronological relationship between alternating dune sand and silty water-lain sediments in the central part of the Khongoryn Els dune field in the Gobi Desert, Southern Mongolia. The 23 m high section evolved from the construction of a natural dam by west–east moving sand dunes and fluvial inundation by a river system from the mountain ranges in the south. To resolve the chronology of events, optically stimulated luminescence (OSL) dating was applied and from sedimentological and geochemical analysis the depositional processes could be characterised. Quartz OSL dating of these sediments is hindered by feldspar contamination. Thus, dating of coarse-g…
Immobilization of natural anti-oxidants on carbon nanotubes and aging behavior of ultra-high molecular weight polyethylene-based nanocomposites
2014
The use of natural antioxidants is an attractive way to formulate nanocomposites with extended durability and with potential applications in bio-medical field. In this work, Vitamin E (VE) in the form of α-tocopherol and Quercetin (Q) are physically immobilized on the outer surface of multi-walled carbon nanotubes (CNTs). Afterward, the CNTs-VE and CNTs-Q are used to formulate thermally stable ultra high molecular weight polyethylene based nanocomposites. The obtained results in the study of the thermo-oxidation behavior suggest a beneficial effect of the natural anti-oxidant carbon nanotubes systems. The unexpected excellent thermo-resistance of the nanocomposites seems to be due to a syne…
Design of the stabilization control system of a high-speed craft
2016
In this paper, the main causes of technical malfunction of a hydrofoil was analyzed. In particular, a preliminary analysis evaluates the economic impact for the navigation company of the periodical maintenance related to the keeping of the vessel in dry dock. The study demonstrated that the main critical points are focused on the fragility of the stabilization control system. The increasing of operating costs has motivated the realization of a study aimed at redesigning the stabilization system. The continuing failure of the stabilization system (usually in water-immersed) severely limits the use of the high-speed craft. The proposed design solution considers the positioning of the control …
Dual Inequalities for Stabilized Column Generation Revisited
2014
Column generation (CG) models have several advantages over compact formulations: they provide better linear program bounds, may eliminate symmetry, and can hide nonlinearities in their subproblems. However, users also encounter drawbacks in the form of slow convergence, also known as the tailing-off effect, and the oscillation of the dual variables. Among different alternatives for stabilizing the CG process, Ben Amor et al. [Ben Amor H, Desrosiers J, Valério de Carvalho JM (2006) Dual-optimal inequalities for stabilized column generation. Oper. Res. 54(3):454–463] suggest the use of dual-optimal inequalities (DOIs) in the context of cutting stock and bin packing problems. We generalize th…
A mathematical model for wastewater modification processes assessment in a stabilization reservoir
2012
The paper presents a mathematical model for the simulation of the ecological status of a wastewater stabilization reservoir (WSR). WSRs are hypertrophic aquatic systems devoted to storage of water resources in warm countries where shortage conditions have quite often to be faced. Several factors that affect the stabilization reservoir effluent quality were taken into account: hydraulics and hydrology, solar radiation, atmospheric reaeration, algae, zooplankton, organic matter, pathogen bacteria, and sediment-water interaction. The model quantifies the specific influence of each factor on effluent quality, evaluating the correlation between the different considered factors. State variables i…
Effect of internal noise on the relaxation time of an yttria stabilized zirconia-based memristor
2022
The effects of temperature on the switching kinetics of an yttrium-stabilized zirconia-based memristor from a low-resistance state to a high-resistance state have been experimentally investigated. It was found that the memristor relaxation time depends on the temperature in a non-monotonous way, with a maximum observed at the temperature close to 55 °C. This nonmonotonic behavior is a signature of the noise-enhanced stability phenomenon observed in all physical and complex systems characterized by metastable states.
Arbuscular mycorrhizal fungi, partners of the rhizostabilization process of an orphan mining site
2012
International audience
Arbuscular mycorrhizal fungi, partners of the rhizostabilization proccess of an orphan mining site
2012
International audience
Influence of bacterial physiology on processing of selenite, biogenesis of nanomaterials and their thermodynamic stability
2019
We explored how Ochrobactrum sp. MPV1 can convert up to 2.5 mM selenite within 120 h, surviving the challenge posed by high oxyanion concentrations. The data show that thiol-based biotic chemical reaction(s) occur upon bacterial exposure to low selenite concentrations, whereas enzymatic systems account for oxyanion removal when 2 mM oxyanion is exceeded. The selenite bioprocessing produces selenium nanomaterials, whose size and morphology depend on the bacterial physiology. Selenium nanoparticles were always produced by MPV1 cells, featuring an average diameter ranging between 90 and 140 nm, which we conclude constitutes the thermodynamic stability range for these nanostructures. Alternativ…