Search results for "Stack"
showing 10 items of 392 documents
Dual-Mode Chiral Self-Assembly of Cone-Shaped Subphthalocyanine Aromatics
2020
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of the American Chemical Society, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/jacs.0c07291
On the superconductivity of graphite interfaces
2014
We propose an explanation for the appearance of superconductivity at the interfaces of graphite with Bernal stacking order. A network of line defects with flat bands appears at the interfaces between two slightly twisted graphite structures. Due to the flat band the probability to find high temperature superconductivity at these quasi one-dimensional corridors is strongly enhanced. When the network of superconducting lines is dense it becomes effectively two-dimensional. The model provides an explanation for several reports on the observation of superconductivity up to room temperature in different oriented graphite samples, graphite powders as well as graphite-composite samples published i…
An Ensemble Learning Method for Emotion Charting Using Multimodal Physiological Signals
2022
Emotion charting using multimodal signals has gained great demand for stroke-affected patients, for psychiatrists while examining patients, and for neuromarketing applications. Multimodal signals for emotion charting include electrocardiogram (ECG) signals, electroencephalogram (EEG) signals, and galvanic skin response (GSR) signals. EEG, ECG, and GSR are also known as physiological signals, which can be used for identification of human emotions. Due to the unbiased nature of physiological signals, this field has become a great motivation in recent research as physiological signals are generated autonomously from human central nervous system. Researchers have developed multiple methods for …
On the Structure and Chiral Aggregation of Liquid Crystalline Star‐Shaped Triazines H‐Bonded to Benzoic Acids
2020
The ability of a star-shaped tris(triazolyl)triazine derivative to hierarchically build supramolecular chiral columnar organizations through the formation of H-bonded complexes with benzoic acids was studied from a theoretical and experimental point of view. The combined study has been done at three different levels including the study of the structure of the triazine core, the association with benzoic acids in stoichiometry 1:3, and the assembly of 1:3 complexes in helical aggregates. Although the star-shaped triazine core crystallizes in a non-C3 conformation, the C3 -symmetric conformation is theoretically predicted to be more stable and gives rise to a favorable C3 supramolecular 1:3 co…
Introduction of a spatial layer in the Semantic Web framework : a proposition through the Web platform ArchaeoKM
2011
Spatial technology has gained momentum under database systems. More specifically, the spatial operations and spatial functions are used to carry out spatial analysis which can be executed through these database systems. In addition, there has been significant amount of research in the field of the geospatial ontology domain in order to achieve the semantic interoperability between different data sources. Although, data interoperability is one of the main objectives of the Semantic Web technologies, the potentiality of the underlying knowledge tools and techniques have not been completely identified. With the growing influence of the Semantic Web technologies towards the application based on…
Synthesis and helical supramolecular organization of discotic liquid crystalline dibenzo[hi,st]ovalene
2019
Dibenzo[hi,st]ovalene (DBOV) has emerged as a new polycyclic aromatic hydrocarbon (PAH) with intriguing optical properties with strong red emission. Nevertheless, DBOV derivatives thus far synthesized either had mesityl groups that hinder the pi-pi stacking of the aromatic cores or showed low solubility, and the self-assembly of DBOVs has not been investigated. In this work, two 3,4,5-tris(dodecyloxy)phenyl (TDOP) groups are introduced at the meso-positions of DBOV in order to enhance its solubility without compromising the intermolecular interactions. The obtained DBOV-TDOP forms at elevated temperatures a discotic liquid crystalline phase. Due to pi-pi-stacking interactions as well as loc…
NASH EQUILIBRIA IN A MODEL OF MULTIPRODUCT PRICE COMPETITION: AN ASSIGNMENT PROBLEM
2003
We study the market interaction of a finite number of single-product firms and a representative buyer, where the buyer consumes bundles of these goods. The buyers' value function determines their willingness to pay for subsets of goods. We show that subgame perfect Nash-equilibrium outcomes are solutions of the linear relaxation of an integer programming assignment problem and that they always exits. The (subgame perfect) Nash-equilibrium price set is characterized by the Pareto frontier of the associated dual problem's projection on the firms' price vectors. We identify the Nash-equilibrium prices for monotonic buyers' value functions and, more importantly, we show that some central soluti…
An active bivergent rolling-hinge detachment system: Central Menderes metamorphic core complex in western Turkey.
2001
Two symmetrically arranged detachment systems delimit the central Menderes metamorphic core complex and define a bivergent continental breakaway zone in the Anatolide belt of western Turkey. Structural analysis and apatite fission-track thermochronology show that a large east-trending syncline within the Alpine nappe stack in the central part of the orogen is related to late Miocene-early Pliocene to recent core-complex formation. The syncline formed as a result of two opposite-facing rolling hinges in the footwalls of each of the two detachments. Back-rotation of the syncline limbs suggests that the detachments rotated from an initial dip of 50 degrees -60 degrees to a currently shallow or…
Unusual packing of ET molecules caused by π–π stacking interactions with TRISPHAT molecules in two [ET][TRISPHAT] salts (ET=bis(ethylenedithio)tetrat…
2007
Abstract The synthesis, structure and physical properties of two new radical salts formed with the organic donor bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF or ET) and a racemic mixture of the chiral anion (tris(tetrachlorobenzenediolato)phosphate(V)) (TRISPHAT) are reported. The structure of the salts (ET)4[TRISPHAT]4 · 3.5H2O (1) and (ET)(TRISPHAT) · CH2Cl2 · CH3CN (2) has been solved by X-ray single crystal diffraction. Unusual packings of ET molecules are obtained in the two structures. The electrical properties indicate that both compounds are insulators. This is in agreement with the isolation of the ET molecules and their complete ionization. On the other hand, the anisotropy of …
Radical salts of TTF derivatives with the metal-metal bonded [Re2Cl8]2- anion
2008
Abstract Four new salts of the radical cations of TMTSF (tetramethyltetraselenafulvalene), TMTTF (tetramethyltetrathiafulvalene), BEDT-TTF (bisethylenedithiotetrathia-fulvalene) (ET) and o-Me2TTF (o-4,4′-dimethyltetrathiafulvalene) with the metal–metal bonded dianion [Re2Cl8]2− were synthesized, and their structures and physical properties investigated. The structures of these semiconducting salts feature one-dimensional stacking of the donor molecules interleaved with [Re2Cl8]2− anions and interstitial solvent molecules.