Search results for "Stain"
showing 10 items of 5524 documents
SVET, AFM and AES study of pitting corrosion initiated on MnS inclusions by microinjection
2003
As pitting is a random phenomenon, it is difficult to predict where a pit will appear on the surface and consequently the use of local probes is rendered difficult. In this work, a new method to study pitting corrosion on a MnS inclusion on 316L stainless steel is proposed. It consists in modifying locally the chemistry in its vicinity by injecting with a microcapillary an aggressive solution of NaCl, H2SO4 or HCl. Once a pit appears, scanning vibrating electrode technique (SVET) is used to follow the current fluctuations over and around the pit when the metal is polarized at a passive potential. In another series of experiments the effect of local activation of MnS inclusion was studied ex…
Relationships between the Impedance of Oxide Scales on Martensitic and Austenitic Steels and Corrosion Rate in Liquid Lead-Bismuth Eutectic
2004
Abstract The impedance properties (resistance and capacitance) of oxide scales on the martensitic/ferritic steel HT-9 and austenitic stainless steel Type 316L (UNS S31603) were examined during immersion in lead-bismuth eutectic (LBE) using a technique similar to electrochemical impedance spectroscopy. These scales were created by preoxidizing the samples in an air/water vapor environment at 800°C for various times prior to immersion in LBE. Calculation of oxide conductivity for samples immersed in LBE at 200°C for 200 h yielded σHT9 ≈ 4 × 10−7 (Ω × cm)−1 while σ316 ≈ 3 × 10−8 (Ω × cm)−1. The influence of temperature alone gave the anticipated Arrhenius behavior with Ea equal to 0.12 eV, whi…
Kinetics of Sigma Phase Precipitation in Niobium-Stabilized Austenitic Stainless Steel and Effect on the Mechanical Properties
2014
Stabilized austenitic stainless steels are widely used in nuclear and oil industries. The 316 Nb steel grade presented in this study holds a small amount of delta ferrite in the austenitic matrix which tends to transform into sigma phase during prolonged exposures in the temperature range of 600-1000°C. Sigma phase is promoted by ferritic elements such as chromium, molybdenum, niobium and silicon. Time-Temperature-Transformation (TTT) diagram of the δ-ferrite evolution is established thanks to DSC experiments and quantitative metallographic analysis. It is observed that the highest sigma phase formation rate occurs between 800 and 900°C, and that the transformation of ferrite begins after a…
Understanding sigma-phase precipitation in a stabilized austenitic stainless steel (316Nb) through complementary CALPHAD-based and experimental inves…
2014
Abstract Sigma-phase precipitation in a 316Nb “stabilized” austenitic stainless steel was studied through complementary CALPHAD-based and dedicated experimental investigations. Thermokinetic calculations performed using Thermo-Calc (with the DICTRA module) and MatCalc software showed that the sigma phase (σ) precipitated directly at γ-austenite grain boundaries (GB) via a common solid-state reaction when carbon and nitrogen contents fell below a critical threshold. Residual δ ferrite was found to be more susceptible to σ-phase precipitation; this type of precipitation occurred via two mechanisms that depended on the concentration profiles of δ-ferrite stabilizing elements induced by previou…
Assessing the electricity consumption of outdoor lighting systems in the presence of automatic control: The OL-BAC factors method
2020
Abstract Building automation systems are able to influence significantly buildings’ energy performance. The BAC factors method, presented for the first time by the International Standard EN 15232, is the most used and simple instrument for evaluating the impact of such systems in terms of reduction of the electrical and thermal energy consumption of buildings services. Nevertheless, Standard EN 15232 does not take into consideration the automation of lighting systems serving buildings’ external areas like passages, gardens, entrance walkways, etc. In some cases, such areas can be very extended and, as a consequence, responsible for a not negligible percentage of the overall electricity cons…
Fuzzy set qualitative comparative analysis (fsQCA) applied to the adaptation of the automobile industry to meet the emission standards of climate cha…
2021
Abstract Facing global climate change challenges entails a sustainable development of transportation. Governments and automobile manufacturers are highly aware of how a large-scale deployment of Electric Vehicles (EVs) can reduce greenhouse gas (GHG) emissions and mitigate global warming. This study aids the design of the adaptation strategies of the automotive industry to meet global goals on climate change by means of a fuzzy-set qualitative comparative analysis (fsQCA), which makes it possible to measure the level of actors’ satisfaction. This allows identification of a combination of factors leading to the outcome while dealing with uncertain environments due to the heterogeneous nature…
Stochastic differential calculus for wind-exposed structures with autoregressive continuous (ARC) filters
2008
In this paper, an alternative method to represent Gaussian stationary processes describing wind velocity fluctuations is introduced. The technique may be considered the extension to a time continuous description of the well-known discrete-time autoregressive model to generate Gaussian processes. Digital simulation of Gaussian random processes with assigned auto-correlation function is provided by means of a stochastic differential equation with time delayed terms forced by Gaussian white noise. Solution of the differential equation is a specific sample of the target Gaussian wind process, and in this paper it describes a digitally obtained record of the wind turbolence. The representation o…
Template electrodeposition and characterization of nanostructured Pb as a negative electrode for lead-acid battery
2019
Abstract Despite Lead Acid Battery (LAB) is the oldest electrochemical energy storage system, diffusion in the emerging sectors of technological interest is inhibited by its drawbacks. The principal ones are low energy density and negative plate sulphating on high rate discharging. In this work, it is shown the possibility of overcoming such drawbacks by using nanostructured lead as a negative electrode. Lead nanowires (NWs) were fabricated by electrochemical deposition in template, which is an easy, cheap, and easily scalable process. Their morphology and crystal structure have been characterized by electron microscopy and X-ray diffraction, respectively. An electrochemical cell simulating…
Recent Advances in Electrochromics for Smart Windows Applications
1998
Electrochromic smart windows are able to vary their throughput of radiant energy by low-voltage electrical pulses. This function is caused by reversible shuttling of electrons and charge balancing ions between an electrochromic thin film and a transparent counter electrode. The ion transport takes place via a solid electrolyte. Charge transport is evoked by a voltage applied between transparent electrical conductors surrounding the electrochromic film/electrolyte/counter electrode stack. This review summarizes recent progress concerning (i) calculated optical properties of crystalline WO3, (ii) electrochromic properties of heavily disordered W oxide and oxyfluoride films produced by reactiv…
Differential branching fractions and isospin asymmetries of B -> K ((*)) μ(+) μ(-) decays
2014
The isospin asymmetries of $B \to K\mu^+\mu^-$ and $B \to K^{*}\mu^+\mu^-$ decays and the partial branching fractions of the $B^0 \to K^0\mu^+\mu^-$, $B^+ \to K^+\mu^+\mu^-$ and $B^+ \to K^{*+}\mu^+\mu^-$ decays are measured as functions of the dimuon mass squared, $q^2$. The data used correspond to an integrated luminosity of 3$~$fb$^{-1}$ from proton-proton collisions collected with the LHCb detector at centre-of-mass energies of 7$\,$TeV and 8$\,$TeV in 2011 and 2012, respectively. The isospin asymmetries are both consistent with the Standard Model expectations. The three measured branching fractions, while individually consistent, all favour lower values than their respective Standard M…