Search results for "Static"
showing 10 items of 1528 documents
Isolated Mn-12 single-molecule magnets grafted on gold surfaces via electrostatic interactions
2005
Electrostatic interactions drive the adsorption of polycationic single-molecule magnets onto anionic monolayers self-assembled on gold surfaces. Well-isolated magnetic clusters have been deposited and characterized using scanning tunneling microscopy and X-ray photoemission spectroscopy.
The effect of quantum size confinement on the optical properties of PbSe nanocrystals as a function of temperature and hydrostatic pressure
2013
A study based on photoluminescence and absorption measurements as a function of temperature and pressure for PbSe nanocrystals with sizes in the range 3–13 nm reveals the influence of size quantum confinement on the observed variation. In the case of the temperature variation, the effective bandgap changes from showing a positive rate of change to showing a negative one (for a quantum dot 3 nm in diameter), which can be accounted for by incorporating a linear variation of the carrier effective masses into a simple calculation of the exciton ground state in the quantum dot. In the case of the pressure variation, we observe a clear inverse correlation between the absolute value of the pressur…
Computational evidence in favor of a two-state, two-mode model of the retinal chromophore photoisomerization
2000
In this paper we use ab initio multiconfigurational second-order perturbation theory to establish the intrinsic photoisomerization path model of retinal chromophores. This is accomplished by computing the ground state ( S 0 ) and the first two singlet excited-state ( S 1 , S 2 ) energies along the rigorously determined photoisomerization coordinate of the rhodopsin chromophore model 4- cis -γ-methylnona-2,4,6,8-tetraeniminium cation and the bacteriorhodopsin chromophore model all- trans -hepta-2,4,6-trieniminium cation in isolated conditions. The computed S 2 and S 1 energy profiles do not show any avoided crossing feature along the S 1 reaction path and maintain an energy gap >20 kcal⋅…
Stochastic seismic analysis of hydrodynamic pressure in dam reservoir systems
2002
Hydrodynamic seismic-induced pressure requires careful consideration in the aseismic design of dams. Effects induced by earthquake excitation may cause many-fold increments of hydrostatic pressure. In this study earthquake excitation has been modelled by means of random process theory obtaining the response statistics of a dam-reservoir dynamical system. The analysis has been conducted assuming a rigid retaining wall of the reservoir and dissipative fluid. Copyright © 2002 John Wiley & Sons, Ltd.
Innovative remotely-controlled bending device for thin silicon and germanium crystals
2020
Steering of negatively charged particle beams below 1 GeV has demonstrated to be possible with thin bent silicon and germanium crystals. A newly designed mechanical holder was used for bending crystals, since it allows a remotely-controlled adjustment of crystal bending and compensation of unwanted torsion. Bent crystals were installed and tested at the MAMI Mainz MIcrotron to achieve steering of 0.855-GeV electrons at different bending radii. We report the description and characterization of the innovative bending device developed at INFN Laboratori Nazionali di Legnaro (LNL).
Experimental evidence on photo-assisted O$^-$ ion production from Al$_2$O$_3$ cathode in cesium sputter negative ion source
2020
The production of negative ions in cesium sputter ion sources is generally considered to be a pure surface process. It has been recently proposed that ion pair production could explain the higher-than-expected beam currents extracted from these ion sources, therefore opening the door for laser-assisted enhancement of the negative ion yield. We have tested this hypothesis by measuring the effect of various pulsed diode lasers on the O$^-$ beam current produced from Al$_2$O$_3$ cathode of a cesium sputter ion source. It is expected that the ion pair production of O$^-$ requires populating the 5d electronic states of neutral cesium, thus implying that the process should be provoked only with s…
Non-Markovian dynamics from band edge effects and static disorder
2017
It was recently shown [S. Lorenzo et al., Sci. Rep. 7, 42729 (2017)] that the presence of static disorder in a bosonic bath - whose normal modes thus become all Anderson-localised - leads to non-Markovianity in the emission of an atom weakly coupled to it (a process which in absence of disorder is fully Markovian). Here, we extend the above analysis beyond the weak-coupling regime for a finite-band bath so as to account for band edge effects. We study the interplay of these with static disorder in the emergence of non-Markovian behaviour in terms of a suitable non-Markovianity measure.
Perspective: Polarizable continuum models for quantum-mechanical descriptions
2016
Polarizable continuum solvation models are nowadays the most popular approach to describe solvent effects in the context of quantum mechanical calculations. Unexpectedly, despite their widespread use in all branches of quantum chemistry and beyond, important aspects of both their theoretical formulation and numerical implementation are still not completely understood. In particular, in this perspective we focus on the numerical issues of their implementation when applied to large systems and on the theoretical framework needed to treat time dependent problems and excited states or to deal with electronic correlation. Possible extensions beyond a purely electrostatic model and generalization…
Timing Properties and Spectral States in Aquila X‐1
2003
We have analyzed five X-ray outbursts of the neutron-star soft X-ray transient Aql X-1 and investigated the timing properties of the source in correlation with its spectral states as defined by different positions in the color-color and hardness-intensity diagrams. The hard color and the source count rate serve as the distinguishing parameters giving rise to three spectral states: a low-intensity hard state, an intermediate state and a high-intensity soft state. These states are respectively identified with the extreme island, island and banana states that characterize the atoll sources. The large amount of data analyzed allowed us to perform for the first time a detailed timing analysis of…
Timing of accreting millisecond pulsars
2008
We review recent results from the X-ray timing of accreting millisecond pulsars in LMXBs. This is the first time a timing analysis is performed on accreting millisecond pulsars, and for the first time we can obtain information on the behavior of a very fast pulsar subject to accretion torques. We find both spin-up and spin-down behaviors, from which, using available models for the accretion torques, we derive information on the mass accretion rate and magnetic field of the neutron star in these systems. We also report here the first measure of the orbital period derivative for an accreting millisecond pulsar, derived for SAX J1808.4-3658 over a timespan of more 7 years.