Search results for "Stimulated raman"

Collisional Broadening of Rotational Lines in the Stimulated Raman Pentad Q-Branch of CD4

1992

Self- and argon-broadening coefficients are reported for a number of Raman Q-branch transitions in the nu(1) and nu(2) + nu(4) bands of (C-12)D4 at room temperature (296 K). The coefficients display a variation with j and with C exp n (symmetry species A, E, F) that is essentially independent of collision partner and which is similar to the j- and C exp n-dependence found in previous measurements of the IR line-broadening coefficients. The rotationally inelastic collision rates previously measured by Foy et al. (1988) for (C-13)D4 (V4 = 0, 1) in collision with (C-13)D4 or Ar account for only a part of the Raman broadening rate, suggesting possibly significant contributions to the linewidths…

Electrostrictive limit in the detection of weak stimulated Raman signals in gases

1997

0377-0486; It is shown experimentally that, in stimulated Raman spectroscopy, electrostriction induced by the pump laser gives rise to a non-resonant signal detected on the probe laser. This phenomenon limits the detectivity of the experiment. A qualitative interpretation is given. (C) 1997 by John Wiley & Sons, Ltd.

Two-laser multiphoton adiabatic passage in the frame of the Floquet theory. Applications to (1+1) and (2+1) STIRAP

1998

We develop an adiabatic two-mode Floquet theory to analyse multiphoton coherent population transfer in N-level systems by two delayed laser pulses, which is a generalization of the three-state stimulated Raman adiabatic passage (STIRAP). The main point is that, under conditions of non-crossing and adiabaticity, the outcome and feasibility of a STIRAP process can be determined by the analysis of two features: (i) the lifting of degeneracy of dressed states at the beginning and at the end of the laser pulses, and (ii) the connectivity of these degeneracy-lifted branches in the quasienergy diagram. Both features can be determined by stationnary perturbation theory in the Floquet representation…

Measurement and Analysis of the Raman Intensities of 12CD4

1995

0022-2852; The stimulated Raman spectrum of 12CD4 was recorded at high resolution, in the spectral range 1963 to 2260 cm(-1). Intensities of the rovibrational transitions were estimated by fitting the line profiles. The recorded elementary spectrum was 1 cm(-1) wide; all recordings were then intensity calibrated. Afterward, the relative Raman intensities were analyzed by using a polarizability model developed previously [A. Boutahar and M. Loete, Can. J. Phys. 69, 26-35 (1991); J. P. Champion, M. Loete, and G. Pierre, in ''Spectroscopy of the Earth's Atmosphere and Interstellar Molecules'' (K. Narahari Rao and A. Weber, Eds.), pp. 388-397, Academic Press, Boston. 1992]. The investigated reg…

HIGH RESOLUTION STIMULATED RAMAN SPECTROSCOPY WITH A 3 MHz ACCURACY WAVEMETER

1987

Roadmap on STIRAP applications

2019

STIRAP (stimulated Raman adiabatic passage) is a powerful laser-based method, usually involving two photons, for efficient and selective transfer of populations between quantum states. A particularly interesting feature is the fact that the coupling between the initial and the final quantum states is via an intermediate state, even though the lifetime of the latter can be much shorter than the interaction time with the laser radiation. Nevertheless, spontaneous emission from the intermediate state is prevented by quantum interference. Maintaining the coherence between the initial and final state throughout the transfer process is crucial. STIRAP was initially developed with applications in …

Rovibrational controlled-NOT gates using optimized stimulated Raman adiabatic passage techniques and optimal control theory

2009

Implementation of quantum controlled-NOT (CNOT) gates in realistic molecular systems is studied using stimulated Raman adiabatic passage (STIRAP) techniques optimized in the time domain by genetic algorithms or coupled with optimal control theory. In the first case, with an adiabatic solution (a series of STIRAP processes) as starting point, we optimize in the time domain different parameters of the pulses to obtain a high fidelity in two realistic cases under consideration. A two-qubit CNOT gate constructed from different assignments in rovibrational states is considered in diatomic (NaCs) or polyatomic $({\text{SCCl}}_{2})$ molecules. The difficulty of encoding logical states in pure rota…

Zeno-like phenomena in STIRAP processes

2011

The presence of a continuous measurement quantum Zeno effect in a stimulated Raman adiabatic passage is studied, exploring in detail a sort of self-competition of the damping, which drives the system toward a loss of population and, at the same time, realizes the conditions for optimizing the adiabatic passage.

Arbitrary qudit gates by adiabatic passage

2013

We derive an adiabatic technique that implements the most general SU($d$) transformation in a quantum system of $d$ degenerate states, featuring a qudit. This technique is based on the factorization of the SU($d$) transformation into $d$ generalized quantum Householder reflections, each of which is implemented by a two-shot stimulated Raman adiabatic passage with appropriate static phases. The energy of the lasers needed to synthesize a single Householder reflection is shown to be remarkably constant as a function of $d$. This technique is directly applicable to a linear trapped ion system with $d+1$ ions. We implement the quantum Fourier transform numerically in a qudit with $d=4$ (defined…

Generation of entanglement in systems of intercoupled qubits

2014

We consider systems of two and three qubits, mutually coupled by Heisenberg-type exchange interaction and interacting with external laser fields. We show that these systems allow one to create maximally entangled Bell states, as well as three qubit Greenberger-Horne-Zeilinger and W states. In particular, we point out that some of the target states are the eigenstates of the initial bare system. Due to this, one can create entangled states by means of pulse area and adiabatic techniques, when starting from a separable (non-entangled) ground state. On the other hand, for target states, not present initially in the eigensystem of the model, we apply the robust stimulated Raman adiabatic passag…