Search results for "Stokes"

showing 10 items of 242 documents

Inelastic neutron and low-frequency Raman scattering in a niobium-phosphate glass for Raman gain applications

2011

Abstract We present measurements of the vibrational spectrum of a binary niobium-phosphate glass in the THz frequency range using inelastic neutron and Raman scattering. The spectra of these glasses show a low-frequency enhancement of the vibrational density of states (“boson peak”). Using a recently developed theory of vibrational excitations in disordered solids we are able to reconcile the measured neutron and Raman spectra using fluctuating elastic and Pockels constants as a model concept. As the spontaneous Raman susceptibility is a key parameter for Raman amplification our results suggest a significant gain profile for application of niobium-phosphate glasses in Raman amplifiers.

Raman amplificationChemistryAnalytical chemistryNeutron scatteringCondensed Matter PhysicsMolecular physicsInelastic neutron scatteringElectronic Optical and Magnetic Materialssymbols.namesakeX-ray Raman scatteringRaman coolingMaterials ChemistryCeramics and CompositessymbolsCoherent anti-Stokes Raman spectroscopyRaman spectroscopyRaman scatteringJournal of Non-Crystalline Solids
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Variability of the Si-O-Si angle in amorphous-SiO2 probed by electron paramagnetic resonance and Raman spectroscopy

2009

We report an experimental investigation by electron paramagnetic resonance (EPR) and Raman spectroscopy on a variety of amorphous silicon dioxide materials. Our study by EPR have permitted us to point out that the splitting of the primary hyperfine doublet of the Eγ′ center shows a relevant sample-to-sample variability, changing from ∼41.8 to ∼42.6 mT in the set of materials we considered. The parallel study by Raman spectroscopy has enabled us to state that this variability is attributable to the different Si-O-Si angle characterizing the matrices of the different materials. © 2009 Elsevier B.V. All rights reserved.

Raman scatteringMaterials Chemistry2506 Metals and AlloysAnalytical chemistryRadiation effectCeramics and CompositeCondensed Matter Physiclaw.inventionsymbols.namesakelawElectron spin resonanceMaterials Chemistryamorphous silica structureCoherent anti-Stokes Raman spectroscopyElectron paramagnetic resonanceHyperfine structureRadiationChemistryElectronic Optical and Magnetic MaterialSettore FIS/01 - Fisica SperimentaleSilicaCondensed Matter PhysicsRaman scattering Microwave Radiation effects Magnetic properties Raman spectroscopy Silica Radiation Electron spin resonance DefectsElectronic Optical and Magnetic MaterialsAmorphous solidMolecular geometryRaman spectroscopyCeramics and CompositessymbolsMagnetic propertieDefectRaman spectroscopyMicrowaveRaman scatteringMicrowave
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Raman Scattering Applied to Materials Science

2015

Abstract One of the most powerful techniques to extract physical and chemical information of a material is the light scattering. Opposite to x-ray scattering for instance, where an average of the sample properties is obtained, Raman scattering is a local probe which can be used to detect inhomogeneities, local strain, lack of crystallinity, anharmonicities or information on the electronic structure by means of resonant Raman scattering. In this work, we will analyze the main contributions of Raman scattering in Materials Sciences. After a brief introduction of the technique and the equipment needed for the physical measurements, we will give practical examples of Raman scattering measuremen…

Raman scatteringMaterials sciencematerials scienceScatteringbusiness.industrysemiconductorsGeneral MedicineElectronic structureSmall-angle neutron scatteringLight scatteringsymbols.namesakeOpticsX-ray Raman scatteringsymbolsinsulatorsCoherent anti-Stokes Raman spectroscopybusinessRaman scatteringX-ray scattering techniquesProcedia Materials Science
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3D digitization of transparent objects by polalization techniques in IR & by triangulation in UV

2011

Two non-conventional methods for the 3D digitization of transparent objects via non-contact measurement are reported in this thesis. 3D digitization is a well acknowledged technique for opaque objects and various commercial solutions based on different measurement approaches are available in the market offering different types of resolution at different prices. Since these techniques require a diffused or lambertian surface, their application to transparent surfaces fails. Indeed, rays reflected by the transparent surface are perturbed by diverse inter-reflections induced by the refractive properties of the object. Therefore, in industrial applications like quality control, the transparent …

Reconstruction par polarisation dans l'IRLow cost systemApproximation du modèle orthographique[INFO.INFO-OH]Computer Science [cs]/Other [cs.OH]Objets transparentscoût)3D digitizationMéthode de validation des paramètres de StokesExcellent accuracyFluorescence tracking and characterizationTransparent objectsValidation method for optimal configuration setupScanning par laser UVIndustrialisable (en terme de précisionIndustrial applicationsOrthographic approximation approachShape from polarization in IRStokes parameters validation method[INFO.INFO-OH] Computer Science [cs]/Other [cs.OH]Scanning from UV laserMéthode de validation pour une configuration optimale du système[ INFO.INFO-OH ] Computer Science [cs]/Other [cs.OH]Non telecentric lenseNumérisation 3DLentille non télécentrique"tracking" et caractérisation de la fluorescence
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Collisional shifting and broadening coefficients for the rovibrational anisotropic S(J) lines of nitrogen studied by inverse Raman spectroscopy

1996

0377-0486; Line shifting and broadening coefficients of the anisotropic S(J) lines (v = 0, J --> v = 1, J + 2) of the nitrogen molecule were measured at room temperature using high-resolution stimulated Raman spectroscopy. A rotational quantum number dependence of the S(J) line shifts was observed. In order to avoid an asymmetry of experimental origin, a suitable theoretical profile was fitted to the experimental lineshapes. This study allows the testing of the theoretical methods for calculating the line broadening coefficients in anisotropic Raman scattering, which have already been used in the analysis of infrared absorption data. The behaviour of the modified sum rule and the RPA (rando…

SCALING ANALYSISChemistryRANGEInversechemistry.chemical_elementN2Rotational–vibrational spectroscopyNitrogenQ-BRANCHN-2OXYGENsymbols.namesakeDEPENDENCEsymbolsSPECTRASCATTERINGGeneral Materials ScienceCoherent anti-Stokes Raman spectroscopyAtomic physicsAnisotropyRaman spectroscopyTEMPERATURESpectroscopy
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Diagonalization of indefinite saddle point forms

2020

We obtain sufficient conditions that ensure block diagonalization (by a direct rotation) of sign-indefinite symmetric sesquilinear forms as well as the associated operators that are semi-bounded neither from below nor from above. In the semi-bounded case, we refine the obtained results and, as an example, revisit the block Stokes operator from fluid dynamics.

Saddle pointMathematical analysisFluid dynamicsBlock (permutation group theory)Perturbation theory (quantum mechanics)Stokes operatorRotation (mathematics)Mathematics
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CFD simulations of dense solid–liquid suspensions in baffled stirred tanks: Prediction of the minimum impeller speed for complete suspension

2012

Abstract In the literature on mechanically agitated solid–liquid systems, several methods are described to estimate the minimum impeller speed Njs at which all particles are suspended, but few studies have been devoted so far to their critical comparative assessment [67] . In the present paper, several alternative Njs prediction methods are applied to CFD results obtained for selected test cases covering a broad range of suspension conditions and impeller speeds. Results are compared with one another and with classic empirical correlations [88] . The aim of the work is to assess the adequacy of different methods for predicting Njs and, more generally, to contribute to a viable CFD-based str…

Settore ING-IND/26 - Teoria Dello Sviluppo Dei Processi ChimiciWork (thermodynamics)Engineeringbusiness.industrySettore ING-IND/25 - Impianti ChimiciGeneral Chemical EngineeringMixing (process engineering)Mechanical engineeringGeneral ChemistryMechanicsStirred tank Multi-fluid model Computational fluid dynamics Solid–liquid two-phase flow Complete suspension speed Sufficient suspension speed Unsuspended solids criterionComputational fluid dynamicsIndustrial and Manufacturing EngineeringControl volumeImpellerEnvironmental ChemistrySuspension (vehicle)Reynolds-averaged Navier–Stokes equationsbusinessContactorChemical Engineering Journal
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CFD simulations of early- to fully-turbulent conditions in unbaffled and baffled vessels stirred by a Rushton turbine

2021

Abstract Laboratory scale unbaffled tanks provided with a top cover and a baffled tank both stirred by a Rushton turbine were simulated by carrying out RANS simulations. Three different turbulence models were adopted (k- ω SST, k- e and the SSG Reynolds stress model) to predict the flow field and the relevant performance parameters (power and pumping numbers) of the tank operated from early to fully turbulent conditions. CFD results were compared with literature experimental data and DNS simulation results to validate and properly compare the models. In the range of Reynolds numbers investigated, results showed that, for the unbaffled tank, the SSG model based on Reynolds stresses is a bett…

Settore ING-IND/26 - Teoria Dello Sviluppo Dei Processi Chimicibusiness.industryTurbulenceGeneral Chemical EngineeringSettore ING-IND/25 - Impianti ChimiciReynolds number02 engineering and technologyGeneral ChemistryReynolds stressMechanicsComputational fluid dynamicsLaboratory scale021001 nanoscience & nanotechnologyFlow fieldRushton turbinesymbols.namesake020401 chemical engineeringCFD SSG Stirred tank Turbulence model Unbaffled vesselsymbols0204 chemical engineering0210 nano-technologybusinessReynolds-averaged Navier–Stokes equationsSettore ING-IND/19 - Impianti NucleariMathematics
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MR3085505 Reviewed Boonpogkrong, Varayu Stokes' theorem on manifolds: a Kurzweil-Henstock approach. Taiwanese J. Math. 17 (2013), no. 4, 1183–1196

2013

Settore MAT/05 - Analisi MatematicaStokes Theorem manifold Kurzweil-Henstock
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Radio polarization maps of shell-type SNRs II. Sedov models with evolution of turbulent magnetic field

2017

Polarized radio emission has been mapped with great detail in several Galactic supernova remnants (SNRs), but has not yet been exploited to the extent it deserves. We have developed a method to model maps of the Stokes parameters for shell-like SNRs during their Sedov evolution phase. At first, 3-dimensional structure of a SNR has been computed, by modeling the distribution of the magnetohydrodynamic parameters and of the accelerated particles. The generation and dissipation of the turbulent component of magnetic field everywhere in SNR are also considered taking into account its interaction with accelerated particles. Then, in order to model the emission, we have used a generalization of t…

Shock waveRadiation mechanisms: non-thermalAstrophysics::High Energy Astrophysical PhenomenaFOS: Physical sciencesCosmic rayAstrophysics01 natural sciencessymbols.namesake0103 physical sciencesFaraday effectStokes parameters010306 general physics010303 astronomy & astrophysicsISM: supernova remnantAstrophysics::Galaxy AstrophysicsPhysicsHigh Energy Astrophysical Phenomena (astro-ph.HE)Astronomy and AstrophysicsAstronomy and AstrophysicDissipationAcceleration of particlePolarization (waves)Cosmic rayMagnetic fieldSupernovaShock waveSpace and Planetary SciencesymbolsAstrophysics - High Energy Astrophysical Phenomena
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