Search results for "Surfaces"
showing 10 items of 2837 documents
Biopolymer-Targeted Adsorption onto Halloysite Nanotubes in Aqueous Media.
2017
Studies on the adsorption of biopolymers onto halloysite nanotubes (HNTs) in water were conducted. Three polymers with different charges-anionic (pectin), neutral (hydroxypropyl cellulose), and cationic (chitosan)-were chosen. The thermodynamic parameters for the adsorption of polymers onto the HNT surface were determined by isothermal titration calorimetry (ITC). The experimental data were interpreted based on a Langmuir adsorption model. The standard variations in free energy, enthalpy, and entropy of the process were obtained and discussed. Turbidimetry was used to evaluate the stability of functionalized nanoparticles in water. The ζ-potential clarified the surface charge properties of …
Pulsed-laser switching in the bistability domain of a cooperative spin crossover compound: a critical study through calorimetry
2015
The photoswitching from the low spin (LS) to high spin (HS) state and the reverse process in the bistability domain of spin crossover (SCO) compounds is a promising function to be used in molecular electronic devices, and evidenced mainly through spectroscopy. The phenomenon, and in particular its mechanism, is however still under debate since some controversial experimental results have been reported. Here we present a calorimetric experimental study of the photoswitching of the [Fe(pyrazine)Pt(CN)4] SCO material by a nanosecond-pulsed green laser. Our results confirm that the single laser pulse of varying energies results in significant LS to HS transformations and show that calorimetry p…
An Investigation into the Stability of Graphitic C 3 N 4 as a Photocatalyst for CO 2 Reduction
2018
The increasing CO 2 concentration in the atmosphere exerts a significant influence on global warming and climate change. The capture and utilization of CO 2 by conversion to useful products is an area of active research. In this work, the photodriven reduction of CO 2 was investigated using graphitic carbon nitride (g-C 3 N 4 ) as a potential photocatalyst. The photocatalytic reduction of CO 2 was investigated with g-C 3 N 4 powder immobilized on a glass support in a batch gas-phase photoreactor. The experiments were carried out under UV-vis irradiation at 70 °C and an initial pressure of 2.5 bar. The only gas-phase product detected during the irradiation of the g-C 3 N 4 in the presence of…
Influence of calcium‐based fillers and vegetable oil on the processability and yield behavior of polyolefins
1997
The mixing of different polyolefins, several calcium-based fillers, and a type of vegetable oil was investigated. The effect of viscosity and type of polyolefin on Young's modulus, yield stress, and elongation at yield has been determined. Tensile and machine torque properties have been studied for both mixing at 180°C and at 250°C as a function of the content of several types of calcium carbonate or calcium hydroxide filler. The influence of the addition of a sunflower oil as a lubricant has also been characterized. SEM micrographs indicate some problems of the formation of agglomerates and the influence of particle size on matrix morphology and filler/matrix adhesion. Physical and chemica…
Visible photothermal deflection spectroscopy using microcantilevers
2012
International audience; Photothermal deflection spectroscopy based on bi-material cantilevers combines the sensitivity of miniature sensors and the selectivity of optical spectroscopy. In this paper, we report on the photothermal response of the microcantilevers functionalized with nanometer thin organic films in the visible region. Unlike responses in the infrared regime, in the optical region, light absorption by all the cantilever constituents must be considered for extraction of the physical parameters of the organic layer. A model of photothermal deflection for the optical region has been developed for two absorbing layers consisting of a thick metal (>200 nm) and a thin organic film. …
Activation process of reversible Pd thin film hydrogen sensors
2013
Abstract Microcantilever-based thin film palladium hydrogen sensors have high selectivity and sensitivity. Reproducibility and accuracy of the sensor performance depend on the activation process of the polycrystalline palladium film deposited on the cantilever. When the hydrogen is in solid solution ( α -phase), the cantilever bending is mostly governed by the residual film stress induced by the swelling at the grain boundaries in the film. When the palladium hydride ( β -phase) starts to be formed, the cantilever undergoes a large deflection due to hydrogen absorption-induced film swelling (10% change in volume). Differences in the phase diagrams of the palladium hydride for two film thick…
Sensing of the Molecular Spin in Spin-Crossover Nanoparticles with Micromechanical Resonators
2019
In the past years, the use of highly sensitive silicon microelectromechanical cantilevers has been proposed as a tool to characterize the spin-crossover phenomenon by employing fast optical readout of the motion. In this work, Fe II -based spin-crossover nanoparticles of the well-known [Fe(Htrz) 2 (trz)](BF 4 ) complex wrapped with thin silica shells of different sizes will be studied by means of silicon microresonators. The silica shell will enhance its chemical stability, whereas the low thickness will allow a proper mechanical coupling between the cantilever and the spin-crossover core. To maximize the sensing of the spin-crossover phenomena, different cantilever geometries and flexural…
Solvent features of cluster single-wall C, BC2N and BN nanotubes, cones and horns
2013
Graphical abstractDisplay Omitted Highlights? It is discussed single-wall carbon, BC2N and BN nanocones in organic solvents in cluster form. ? Theory is developed based on a cluster bundlet model describing distribution function by size. ? There is explanation in which (BC2N/BN-)SWNC free energy is combined from two components. ? Bundlet model enables describing the distribution function of (BC2N/BN-)SWNC clusters by size. ? From purely geometrical differences, bundlet and droplet models predict different behaviours. It is discussed the existence of single-wall carbon nanocones (SWNCs), especially nanohorns (SWNHs), and BC2N/boron nitride (BN) analogues in organic solvents in cluster form; …
Effect of alloying elements on the electronic properties of thin passive films formed on carbon steel, ferritic and austenitic stainless steels in a …
2014
The influence of alloying elements on the electrochemical and semiconducting properties of thin passive films formed on several steels (carbon steel, ferritic and austenitic stainless steels) has been studied in a highly concentrated lithium bromide (LiBr) solution at 25 °C, by means of potentiodynamic tests and Mott Schottky analysis. The addition of Cr to carbon steel promoted the formation of a p-type semiconducting region in the passive film. A high Ni contentmodified the electronic behaviour of highly alloyed austenitic stainless steels.Mo did notmodify the electronic structure of the passive films, but reduced the concentration of defects.
Friction and wear testing of multilayer coatings on carbide substrates for dry machining applications
2002
Abstract The principle aim of this paper is to investigate three wear-protective coatings with multilayer structures, which are frequently used in the cutting tool industry and to assess their frictional behaviour under the test conditions equivalent to those for the cutting of medium carbon steel. A modified pin-on-disc tester was used to conduct experiments in which both the friction coefficient and the linear wear of the tribo-pair were recorded vs. sliding distance. The volumetric wear rate was proposed as a parameter for quantitative comparison of the wear resistance of the tribo-pairs tested. It was found that the principle stage of the specimen wear takes place during the first 200–2…