Search results for "Surfaces"
showing 10 items of 2837 documents
Water Adsorption in Flexible Gallium-Based MIL-53 Metal–Organic Framework
2014
Understanding the adsorption of water in metal–organic frameworks (MOF), and particularly in soft porous crystals, is a crucial prerequisite before considering MOFs for industrial applications. We report here a joint experimental and theoretical study on the behavior of a gallium-based breathing MOF, Ga-MIL-53, upon water adsorption. By looking at the energetics and thermodynamics of Ga-MIL-53, we demonstrate why it behaves differently from its sibling Al-MIL-53, showing a different phase at room temperature (a nonporous phase) and the presence of a hydrated narrow-pore structure at gas saturation pressure. Moreover, we present a complete water vapor pressure vs temperature phase diagram of…
UV Index experimental values on vertical surfaces
2011
UV erythemal irradiance (UVER) has been studied on a horizontal plane and on vertical surfaces with different orientations in Valencia, Spain. The evolution of the solar noon value and the maximum daily value over a year has been analysed from the instantaneous UVER taken every five minutes on the horizontal plane and on vertical surfaces with north, south, east and west orientations. The annual evolution of these values shows a sinusoidal form for all planes except for the vertical south plane with maxima in spring and autumn. The UV Index (UVI) on these planes was also determined. The percentage of coincidence of the UVI at solar noon and of the maximum daily UVER values, considering diff…
Evaluation of models for estimating solar irradiation on vertical surfaces at Valencia, Spain
1991
Abstract Hourly irradiation data recorded on vertical surfaces at north, east, south, and west orientations during the winter period going from December 1989 to March 1990 in Valencia, Spain, have been compared with estimated solar irradiation from several tilted-surface models. The isotropic-, Temps' and Coulson's-, Klucher's-, Hay's-, Skartveit's and Olseth's-, Gueymard's- and Perez' (simplified) models have been considered for this comparison. Root-mean-square-difference (RMSD), mean-bias-difference (MBD) and mean-absolute-difference (MAD) estimators have been used to measure the departure of models from experimental data. Modeled values are evaluated with the original coefficients propo…
The optimisation of the angle of inclination of a solar collector to maximise the incident solar radiation
1999
Abstract Irradiation data, recorded on vertical surfaces facing north, south, east and west and on a horizontal surface every ten minutes during daylight hours from January–December 1992 in Valencia, Spain, have been compared with estimated solar irradiation from inclined-surface models. Results show that Hays model most accurately reproduces the variation in irradiation on all vertical surfaces. Hays model has been used to find the hourly variation in the optimum tilt angle for a South-facing solar collector in Valencia, Spain, and also to calculate the yearly average of this angle. This method has been compared with the results provided by another model that uses average monthly values of…
Thiopeptide-Supported Lipid Layers on Solid Substrates
1997
The sequential layer-by-layer formation of peptide-supported bimolecular lipid membranes at solid supports is described. In the first step, thiol-derivatized peptide sequences of 5 and 7 amino acids are assembled on a Au substrate. After activation of their COOH-terminus phospholipid molecules (DMPE) are covalently attached via an amid bond to form a tethered monolayer on the Au electrode. The different preparation steps are analyzed by Fourier transform IR, X-ray reflectometry, and surface plasmon spectroscopy. The latter technique is then also used to on-line monitor at the solid/solution interface the formation of a bilayer by fusion of vesicles prepared from a fluid lipid mixture with a…
Interprétation tribologique de la perception tactile de surfaces texturées
2018
International audience; Ces dernières années, l’industrie a porté un intérêt grandissant à la qualité sensorielle de leurs produits, et notamment à la sensation tactile qu’ils procurent. Selon Hollins et al, l’ensemble des surfaces matérielles peuvent être définies selon quatre dimensions psycho-perceptives tactiles : « glissant/collant », « lisse/rugueux », « chaud/froid » et « dur/mou » [1]. La texturation de surface est un moyen de parvenir à la réalisation d’une variété de surfaces appartenant, du point de vue de la perception tactile, aux deux premières dimensions susnommées. Néanmoins, les liens entre les paramètres topographiques des textures et la sensation ressentie lors du toucher…
One-sensor electronic olfactometer for rapid sorting of fresh fruit juices
2001
Abstract A low-cost electronic olfactometer was developed, based on virtual sensors array (an array of signals from a single metal oxide sensor) and on our proprietary semi-automated sampling system. This concept enables us to drastically improve the sensitivity and selectivity of the entire olfactometer to make it suited to food products analysis. Each step of the prototype was checked separately in earlier work, and finally the system performance was evaluated first on pure chemicals, and then at-line for grape juice during grape-harvesting in Champagne. It is shown that over a 3-week vintage period, the drift of the unique-sensor was quite low (absolute baseline value: avg., 2152; std., …
Time-resolving Analysis of Cryotropic Gelation of Water/Poly(Vinyl Alcohol) Solutions via Small Angle Neutron Scattering
2007
The structural transformations occurring in initially homogeneous aqueous solutions of poly(vinyl alcohol) (PVA) through application of freezing (-13 degrees C) and thawing (20 degrees C) cycles is investigated by time resolving small-angle neutron scattering (SANS). These measurements indicate that formation of gels of complex hierarchical structure arises from occurrence of different elementary processes, involving different length and time scales. The fastest process that could be detected by our measurements during the first cryotropic treatment consists of the crystallization of the solvent. However, solvent crystallization is incomplete, and an unfrozen liquid microphase more concentr…
Mesoscopic and Microscopic Investigation on Poly(vinyl alcohol) Hydrogels in the Presence of Sodium Decylsulfate
2007
The structure of poly(vinyl alcohol) (PVA) hydrogels formed as a result of freeze/thaw treatments of aqueous solutions of the polymer (11 wt % PVA) in the freshly prepared state is analyzed through the combined use of small (SANS) and ultrasmall (USANS) angle neutron scattering techniques. The structure of these hydrogels may be described in terms of polymer rich regions, with dimensions of the order of 1-2 microm, dispersed in a water rich phase, forming two bicontinuous phases. The PVA chains in the polymer rich phase form a network where the cross-linking points are mainly crystalline aggregates of PVA having average dimensions of approximately 45 A. The structural organization of freeze…
Resist-based silver nanocomposites synthesized by lithographic methods
2010
In this work, the formation of silver metal nanoparticles inside a negative-tone resist based on poly(vinyl alcohol) is achieved by electron beam lithography. The chemistry of this sensitive resist allows the production of nanoparticles as well as the polymer crosslinking by the electron radiation. Due to the presence of the silver nanoparticles, the final composite exhibits a plasmonic behavior, which was characterized by measuring the absorbance. The lithographic properties of the resist have been characterized. The technique has also been exported to UV lithography, where silver nanoparticles are obtained inside the polymeric patterns after optical lithography.