Search results for "Surfaces"
showing 10 items of 2837 documents
Positron Studies of Subsurface Zone in Titanium Created in Sliding Wear
2014
Positron annihilation studies of the subsurface zone constituted during dry sliding in pure titanium are reported. A new type of defect depth profile in this zone, which is not an exponential decay usually reported for other metals and alloys, is observed. Two layers in the subsurface zone are present in this metal. In the layer adjacent to the worn surface, the characteristic plateau of the mean positron lifetime that extends to a depth of 60–70 μm was observed. Small vacancy clusters and dislocations were recognized in this layer. At deeper zone, the mean positron lifetime decreased exponentially in the manner typical for the other metals. In this zone, vacancy clusters increase in size a…
Pullout Force and Inlet Oscillation in Telescopic Carbon Nanotubes: A Quantum Study
2021
The noncovalent interaction energy as a function of the core extension in double-walled carbon nanotubes (DWCNT) was accurately calculated in the frame of density functional theory, considering dis...
From Dupin cyclides to scaled cyclides
2003
Dupin cyclides are algebraic surfaces introduced for the first time in 1822 by the French mathematician Pierre-Charles Dupin. They have a low algebraic degree and have been proposed as a solution to a variety of geometric modeling problems. The circular curvature line’s property facilitates the construction of the cyclide (or the portion of a cyclide) that blends two circular quadric primitives. In this context of blending, the only drawback of cyclides is that they are not suitable for the blending of elliptic quadric primitives. This problem requires the use of non circular curvature blending surfaces. In this paper, we present another formulation of cyclides: Scaled cyclides. A scaled cy…
Enhancing values of roofs albedo for lowering cities’ air temperature and electric demand of buildings: a simple economic evaluation
2019
Abstract In cities vegetated roofs are becoming more popular because they can mitigate Urban Heat Island phenomena by decreasing the outdoor air temperature in summer. This decrease reduces the electric energy demand for climatization of buildings, which, in front of a milder climate, will recur less to mechanical tools for guaranteeing thermal comfort conditions to occupants. Cities can registered another indirect positive effect: the reduced cooling energy demand, limits the heat released by the climatization systems’ external unities toward the urban open spaces, thus lowering the outdoor air temperature. Therefore, the outdoor surface temperature of green, as well as cool roofs, can be …
Integral geometry from Buffon to geometers of today
2016
La géométrie intégrale, aussi appelée théorie des probabilités géométriques, a accompagné pendant plus de deux siècles le développement des probabilités, de la théorie de la mesure et de la géométrie. Elle commence pour nous en 1777, date de la publication du « traité d'arithmétique morale » de Buffon. Ce n'est que presque un siècle plus tard que Crofton explicitera ce que veut dire mettre une mesure sur un ensemble continu comme l'ensemble des droites. Le sens de la formule de Cauchy-Crofton « la longueur d'une courbe plane est proportionnelle à la mesure pondérée de l'ensemble des droites qui la coupent », est maintenant clair. Au début du vingtième siècle, la géométrie intégrale commence…
Very strong −N–X+⋯−O–N+ halogen bonds
2016
A new (-)N-X(+)(-)O-N(+) paradigm for halogen bonding is established by using an oxygen atom as an unusual halogen bond acceptor. The strategy yielded extremely strong halogen bonded complexes with very high association constants characterized in either CDCl3 or acetone-d6 solution by (1)H NMR titrations and in the solid-state by single crystal X-ray analysis. The obtained halogen bond interactions, RXB, in the solid-state are found to be in the order of strong hydrogen bonds, viz. RXB ≈ RHB.
A Computational Study of Adsorption of CO2, SO2, and H2CO on Free-Standing and Molybdenum-Supported CaO Films
2018
Oxide films play a significant role in a wide range of fields from catalysis to solar cell materials. CaO films are promising sorbents for many environmentally harmful molecules. Here, we report a systematic investigation of adsorption of CO2, SO2, and H2CO on bulk and Mo-supported CaO(100) films using density functional theory. Significant effects on adsorption energy, charge transfer to the molecules, and degree of the C–O bond activation were demonstrated on Mo-supported CaO films by changing the film thickness, composition, and the strength and direction of an applied external electric field. These findings are relevant for interpreting results from scanning tunneling microscopy of smal…
Active lighting applied to three dimensional reconstruction of specular metallic surfaces by polarization imaging
2005
This thesis deals with a new automated tridimensional inspection system for specular metallic surfaces, based on polarization analysis. We first present an extension of the ‘Shape from Polarization' method for dielectric to metallic surfaces. After being reflected, an unpolarized light wave becomes partially linearly polarized, depending on the surface normal and on the refractive index of the media it impinges on. Hence, by measuring the polarization parameters of the reflected light, the surface normals are computed. The ambiguity concerning the normals orientation is solved here with a new active lighting system. Then, we describe and compare numerical methods for reconstructing the trid…
Asymmetric [N–I–N]+halonium complexes in solution?
2020
Assessment of the solution equilibria of [bis(pyridine)iodine(I)]+ complexes by ESI-MS and NMR reveals the preference of iodine(I) to form complexes with a more basic pyridine. Mixtures of symmetric [bis(pyridine)iodine(I)]+ complexes undergo statistical ligand exchange, with a predominant entropic driving force favoring asymmetric systems. The influence of ligand basicity, concentration, temperature, and ligand composition is evaluated. Our findings are expected to facilitate the investigations, and the supramolecular and synthetic applications of halonium ions’ halogen bonds. peerReviewed
Potent affinity material for tracing acetone and related analytes based on molecular recognition by halogen bonds.
2014
Affinity materials based on halogen bonds turned out to be a powerful tool for the molecular recognition of acetone or related carbonyl compounds in the presence of ubiquitous protic molecules. The superior selectivity and sensitivity were found by the gravimetric detection of volatile organic compounds by quartz crystal microbalances.