Search results for "Surfaces"
showing 10 items of 2837 documents
Magnetic circular and linear dichroism in VUV-photoemission from thin iron films on W(110)
1996
Abstract We report on two different photoemission techniques for ferromagnetic surfaces: the phenomena of magnetic circular and linear dichroism in the angular distribution of photoelectrons MCDAD and MLDAD. MCDAD had already been studied in detail for different systems. Now we are able to compare our MCDAD results from thin iron films on W(110) to new data from magnetic linear dichroism MLDAD. Both effects (MCDAD and MLDAD) have been studied in the identical photon energy region (up to hv = 36 eV). The results will be discussed with respect to a bandstructure calculation.
MAGNETIC COUPLING OF ALKALI AND RARE-GAS FILMS ADSORBED ON A FERROMAGNETIC SURFACE
2002
The observation of magnetic circular dichroism in the angular distribution of photoelectrons (MCDAD) from alkali and rare-gas films adsorbed on a thin remanently magnetized Co layer is reported. The observation of an antisymmetric MCDAD near normal emission for Co(0001)–Cs 5p semi core level is shown. The reversed magnetization leads to a mirror-image-like distribution. The second system under investigation, physisorbed Co(0001)–Xe 5p, does not give such an but shows significant differences in the MCDAD signal for both directions of magnetization, in particular in the |mj| substates of the p3/2 level. A magnetic coupling between Xe and Co is evident when we take results of spin-resolved ph…
Magnetic interface formation at Fe/Cr/Fe(100)
1997
Photoemission magnetic dichroism of Fe and Cr 3p core levels was employed to investigate the magnetic order at the Fe/Cr/Fe(100) interface. For submonolayer and monolayer Fe coverages on Cr(100) the interface system appears magnetically frustrated, with no net magnetization along the parallel (antiparallel) direction of the substrate magnetization. The analysis of the Fe 3p photoemission dichroism allows to conclude that, at these low coverages, Fe is magnetically ordered but along an axis lying at 90° from the substrate Fe(100) magnetization, favoring the interpretation of biquadratic coupling between the ultrathin iron overlayer and the bulk iron substrate, across the Cr interlayer.
Magnetism and Molecular Nonlinear Optical Second-Order Response Meet in a Spin Crossover Complex
2012
International audience; The quadratic hyperpolarizability of two inorganic Schiff base metal complexes which differ from each other by the nature of the central metal ion (FeII or ZnII) is estimated using hyper-Rayleigh light-scattering (HRS) measurements. The investigated FeII microcrystals exhibit a thermal spin-crossover (SCO) from a diamagnetic to a paramagnetic state centered at T1/2 = 233 K that can be reproduced by the HRS signal whose modest intensity is mainly due to their centrosymmetric packing structure. Diamagnetic ZnII microcrystals even lead to much weaker (∼400 times) HRS intensities which are in addition temperature-independent. These observations allow us to ascribe the ch…
Surface Chemistry Controls Magnetism in Cobalt Nanoclusters
2016
Magnetic properties of Co13 and Co55 nanoclusters, passivated by surface ligand shells that exhibit varying electronic interactions with the metal, are studied using density functional theory. The calculations show that the chemical nature of the bond between the ligand and the metal core (X-type or L-type) impacts the total magnetic moment of Co nanoclusters dramatically. Furthermore, the chemical identity of the ligand within each binding motif then provides a fine handle on the exhibited magnetic moment of the cluster. Thus, ligand shell chemistry is predicted to not only stabilize Co nanoclusters, but provide a powerful approach to control their magnetic properties, which combined enabl…
Impact of local order and stoichiometry on the ultrafast magnetization dynamics of Heusler compounds
2015
Nowadays, a wealth of information on ultrafast magnetization dynamics of thin ferromagnetic films exists in the literature. Information is, however, scarce on bulk single crystals, which may be especially important for the case of multi-sublattice systems. In Heusler compounds, representing prominent examples for such multi-sublattice systems, off-stoichiometry and degree of order can significantly change the magnetic properties of thin films, while bulk single crystals may be generally produced with a much more well-defined stoichiometry and a higher degree of ordering. A careful characterization of the local structure of thin films versus bulk single crystals combined with ultrafast demag…
Quantum Tunneling of Magnetization under Pressure in the High-Spin Mn12 Molecular System
2004
Experimental and theoretical investigations of quantum tunneling magnetization in the high-spin cluster [Mn 1 2 O 1 2 (CH 3 COO) 1 6 (H 2 O) 4 ].2CH 3 COOH.4H 2 O under pressure have been performed. The main observation is that the blocking temperature and hysteresis width decrease under the effect of pressure. However, the position of the steps in the magnetization versus field curve does not change noticeably as pressure increases. A theoretical examination of the pressure influence on the relaxation rate and magnetization has been carried out taking into consideration the quantum tunneling effects. The qualitative agreement between theory and experiment has been achieved both at atmosphe…
Interface magnetization of ultrathin epitaxial Co2FeSi(110)/Al2O3films
2007
Element-specific magnetic properties of ultrathin epitaxial Co2FeSi(110) films were measured using x-ray magnetic circular dichroism (XMCD). The epitaxial Heusler films were grown by RF magnetron sputtering on substrates. The magnetization of thicker films as determined by XMCD is smaller than expected for a half-metallic material. In addition, the magnetization decreases considerably for films thinner than 10 nm. The thickness dependence of the magnetic moment can be described by introducing a certain number of dead layers representing a deficiency of magnetization at the interfaces. Quantitative evaluation results in a dead layer thickness of 0.8 nm at room temperature, consisting of a te…
Fragmentation dynamics within shear bands--a model for aging tectonic faults?
2001
A numerical model for packing of fragmenting blocks in a shear band is introduced, and its dynamics is compared with that of a tectonic fault. The shear band undergoes a slow aging process in which the blocks are being grinded by the shear motion and the compression. The dynamics of the model have the same statistical characteristics as the seismic activity in faults. The characteristic magnitude distribution of earthquakes appears to result from frictional slips at small and medium magnitudes, and from fragmentation of blocks at the largest magnitudes. Aftershocks to large-magnitude earthquakes are local recombinations of the fragments before they reach a new quasi-static equilibrium. The …
Prevention of pressure injuries in critically ill children: A preliminary evaluation
2020
Abstract Aims To evaluate a prevention strategy implemented to reduce incidence and severity of positioning related pressure injuries affecting pediatric patients in a pediatric critical care unit. Secondary objective was to evaluate compliance with preventive recommendations. Background The skin in infants or children has important physiological and anatomical differences compared with adults. Further, factors such as the immaturity of the skin and limited activity and mobility in pediatric critical care unit, along with the pressure exerted by medical devices, increases the risk of pressure ulcers in infants and children. The most effective preventive measures specific to this intensive c…