Search results for "TAM"
showing 10 items of 11664 documents
Unexpected Scholl Reaction of 6,7,13,14-Tetraarylbenzo[k]tetraphene: Selective Formation of Five-Membered Rings in Polycyclic Aromatic Hydrocarbons
2016
Cyclodehydrogenation is a versatile reaction that has enabled the syntheses of numerous polycyclic aromatic hydrocarbons (PAHs). We now describe a unique Scholl reaction of 6,7,13,14-tetraarylbenzo[k]tetraphene, which "unexpectedly" forms five-membered rings accompanying highly selective 1,2-shift of aryl groups. The geometric and optoelectronic nature of the resulting bistetracene analogue with five-membered rings is comprehensively investigated by single-crystal X-ray, NMR, UV-vis absorption, and cyclic voltammetry analyses. Furthermore, a possible mechanism is proposed to account for the selective five-membered-ring formation with the rearrangement of the aryl groups, which can be ration…
Catalytic activity of biscobalt porphyrin-corrole dyads toward the reduction of dioxygen
2009
A series of biscobalt cofacial porphyrin-corrole dyads bearing mesityl substituents at the meso positions of the corrole ring were investigated as to their electrochemistry, spectroelectrochemistry, and CO binding properties in nonaqueous media and then applied to the surface of a graphite electrode and tested as electrocatalysts for the reduction of dioxygen to water or hydrogen peroxide in air-saturated aqueous solutions containing 1 M HClO(4). The catalytic reduction of O(2) with the same dyads was also investigated in the homogeneous phase using 1,1'-dimethylferrocene as a reductant in PhCN containing HClO(4). The examined compounds are represented as (PMes(2)CY)Co(2), where P = a porph…
A reinvestigation of compound CpMo(PMe3)2(CH3)2: Alkylation by single electron transfer and radical addition?
2001
International audience; The synthesis of the half-sandwich molybdenum(III) diphosphine dimethyl complex CpMo(PMe3)2(CH3)2 has been reinvestigated. The compound was obtained from the corresponding dichloro complex CpMo(PMe3)2Cl2 and methyllithium at low temperatures and isolated as a crystalline product by conducting all operations at temperatures lower than −10 °C. The complex is thermally unstable at room temperature but has been fully characterised by EPR spectroscopy, cyclic voltammetry and X-ray diffraction. The formation reaction is retarded by excess phosphine. On the basis of this and other related observations, a mechanism involving phosphine pre-dissociation followed by single elec…
Pharmaceuticals and other urban contaminants threaten Amazonian freshwater ecosystems
2021
Abstract Urban areas in the Brazilian Amazon have grown at an unprecedented rate during the last years. About 90% of the wastewater produced by these urban areas are discharged untreated into Amazonian freshwater ecosystems, constituting a potential environmental pathway for pharmaceuticals and other chemicals consumed by modern societies (e.g. psychostimulants, personal-care products, hormones). The distribution of these chemicals into the Amazon River and their potential risks for freshwater biodiversity have not been evaluated so far. Here, we show the results of the largest chemical monitoring campaign conducted in the Amazon region. We assessed exposure patterns for 43 pharmaceuticals …
Non‐subduction origin for 3.2 Ga high‐pressure metamorphic rocks in the Barberton granitoid‐greenstone terrane, South Africa
2019
The occurrence of high-pressure (HP) garnet-bearing metamorphic rocks in the southern Barberton granitoid-greenstone terrane (BGGT), South Africa, has been proposed as a key indicator of the onset of modern plate tectonics at ca. 3.2 Ga. Here, we report new zircon/titanite U-Pb ages of garnet-bearing HP metamorphic rocks and associated granitoids in the BGGT that argue against such an interpretation. The results show that HP metamorphism occurred synchronously with granitoid magmatism in the Stolzburg domain, the supposed subducted plate, during two episodes at 3.4 and 3.2 Ga, and that these two episodes of magmatism occurred on both sides of the assumed suture zone, a feature that cannot e…
Subduction or sagduction? Ambiguity in constraining the origin of ultramafic–mafic bodies in the Archean crust of NW Scotland
2016
Abstract The Lewisian Complex of NW Scotland is a fragment of the North Atlantic Craton. It comprises mostly Archean tonalite–trondhjemite–granodiorite (TTG) orthogneisses that were variably metamorphosed and reworked in the late Neoarchean to Paleoproterozoic. Within the granulite facies central region of the mainland Lewisian Complex, discontinuous belts composed of ultramafic–mafic rocks and structurally overlying garnet–biotite gneiss (brown gneiss) are spatially associated with steeply-inclined amphibolite facies shear zones that have been interpreted as terrane boundaries. Interpretation of the primary chemical composition of these rocks is complicated by partial melting and melt loss…
Exposure to mercury among 9-year-old Spanish children: Associated factors and trend throughout childhood
2019
Mercury is considered a neurotoxicant and human exposure occurs mainly from the consumption of marine species. We aimed to describe total mercury concentrations (THg) and associated factors in 9-year old children, as well as to explore the trend in THg from 4 to 9 years of age. The study population consisted of 9-year-old children participating in the INMA (Environment and Childhood) birth cohort study in Valencia, Spain (n = 405, 2013–2014). THg in hair samples was measured by atomic absorption spectrometry at the age of 4 and 9 years. Sociodemographic and dietary data was obtained through questionnaires. Multiple linear regression was used to explore the association between THg and covari…
Early Neoproterozoic crustal growth and microcontinent formation of the north–central Central Asian Orogenic Belt: New geological, geochronological, …
2021
Abstract In this study, new geological, geochronological, geochemical, and Nd–Hf isotopic data are presented for the Melange Zone within the Zavkhan terrane, Mongolia, and the terrane structure, early Neoproterozoic continental crust growth, and microcontinent formation in the north–central part of the Central Asian Orogenic Belt (CAOB) are discussed. The Melange Zone separates high-grade complexes of the northwestern part of the Zavkhan terrane and unmetamorphosed Neoproterozoic Zavkhan Formation covered by Cryogenian–Cambrian shelf deposits of the southwestern part. Zone consist of a lower-grade association of basalts, basaltic andesites, rarely felsic volcanic rocks, trondhjemites of the…
Zircon and muscovite ages, geochemistry, and Nd-Hf isotopes for the Aktyuz metamorphic terrane: Evidence for an Early Ordovician collisional belt in …
2011
International audience; The Aktyuz metamorphic terrane in the Kyrgyz northern Tianshan consists of granitoid gneisses and migmatites with subordinate paragneisses, greenschists, presumed meta-ophiolites, and garnet amphibolite dykes that contain HP eclogite relicts. The gneisses and migmatites were previously considered to be Archaean and Palaeoproterozoic in age on the basis of α-Pb and U-Pb multigrain zircon dating. Zircons from a post-tectonic granite were previously dated at 692 ± 15 Ma, constraining the time of main deformation and metamorphism in the Aktyuz terrane to the Precambrian. The chemical characteristics of most granitoid samples are consistent with melting of chemically evol…
Kinematics, deformation partitioning and late Variscan magmatism in the Agly massif, Eastern Pyrenees, France
2020
International audience; In order to constrain the finite deformation pattern of the Variscan basement of the Agly massif, a detailed structural analysis over the whole Agly massif was performed. Our investigation combined geological mapping, reappraisal of published and unpublished data completed with our own structural work. Results are provided in the form of new tectonic maps and series of regional cross-sections through the Agly massif. At variance from previous studies, we identified three deformation fabrics named D1, D2 and D3. The D1 deformation is only relictual and characterized by a broadly northwest-southeast striking and eastward dipping foliation without any clear mineral and …