Search results for "TEMPERATURE"
showing 10 items of 3798 documents
The photochemistry of mono- and dinuclear cyclometalated bis(tridentate)ruthenium(ii) complexes: dual excited state deactivation and dual emission
2016
The synthesis and characterization of a series of weakly emissive mononuclear cyclometalated [Ru(dpb-R)(tpy)](+) complexes with functional groups R of varying electron-donating characters at the dpb ligand are described (dpbH = 1,3-di(2-pyridyl)benzene, tpy = 2,2';6',2''-terpyridine, 1(+): R = NHCOMe, 2(+): R = NH2, 3(+): R = COOEt, 4(+): R = COOH). Steady-state emission spectroscopy in the temperature range between 298 K and 77 K revealed a previously unrecognized excited state deactivation pathway via low-lying triplet ligand-to-ligand ((3)LL'CT) charge transfer states in addition to the well-known pathway via(3)MC states. Thermal activation barriers for depopulation of the emissive metal…
On the magneto-structural role of the coordinating anion in oxamato-bridged copper(ii) derivatives
2019
We herein present the synthesis, spectroscopic analysis, description of the crystal structures and magnetic properties of four new complexes of the formula [{Cu(opba)(H2O)1.2}{Cu(dmphen)(SCN)}2]·dmf (1), [{Cu(opba)}2{Cu(dmphen)Cl}4]·1.5dmf·2.5dmso (2), [{Cu(opba)}2{Cu(dmphen)Br}4]·dmf·2.3dmso (3) and [{Cu(opba)}{Cu(dmphen)(dca)}2]n (4) [H4opba = N,N′-1,2-phenylenebis(oxamic acid), dmphen = 2,9-dimethyl-1,10-phenanthroline and dca = dicyanamide anion]. 1 is a neutral tricopper(II) complex where an inner [Cu(opba)]2− fragment adopts a bis-bidentate coordination mode towards two outer [Cu(dmphen)(NCS)]+ units. 2 and 3 are bis-trinuclear species where two oxamato-bridged [Cu(opba){Cu(dmphen)X}2…
The [Pd(bipy)]2+ “merry-go-round”: Insights into the lability of the Pd–N bond
2009
Abstract Two tripods (1 and 2) featuring pyrimidinyl pendant arms have been synthesized from 5-(1H-pyrazol-3-yl)-pyrimidine (5) and 1,3,5-tribromomethylbenzene derivatives. Reaction with three equivalents of [Pd(bipy)](NO3)2 to form a macrotricycle closed by palladium coordination unexpectedly afforded the mononuclear species [Pd(1)(bipy)]2+ and [Pd(2)(bipy)]2+. These complexes show fluxional behavior on the 1H NMR timescale, the [Pd(bipy)]2+ fragment hopping between the pyrimidinyl coordinating moieties. The ΔGc‡’s estimated by the coalescence method are temperature independent, which means that ΔSc‡ = 0. This indicates that the “merry-go-round” process of [Pd(bipy)]2+ occurs intramolecula…
Long-term changes of the ice regime of rivers in Latvia
2016
The ice regime of rivers is considered a sensitive indicator of climate change. This paper summarises the results of research on the long-term changes in the ice regime parameters under changing climate conditions and their regional peculiarities in Latvia from 1945 to 2012. The ice cover duration on Latvian rivers has decreased during recent decades. The research results demonstrated that there is a positive trend as regards the formation of the ice cover and in 31.8% of the cases the trend is statistically significant at p < 0.05. As regards the breaking up of ice, there is a statistically significant negative trend in 93.2% of the cases at p < 0.05. This indicates an earlie…
The WISE 2000 and 2001 Field Experiments in Support of the SMOS Mission:Sea Surface L-Band Brightness Temperature Observations and Their Application …
2004
Camps, Adriano ... et al.-- 20 pages, 16 figures, 3 tables
Two-year global simulation of L-band brightness temperatures over land
2003
International audience; This letter presents a synthetic L-band (1.4 GHz) multiangular brightness temperature dataset over land surfaces that was simulated at a half-degree resolution and at the global scale. The microwave emission of various land-covers (herbaceous and woody vegetation, frozen and unfrozen bare soil, snow, etc.) was computed using a simple model [L-band Microwave Emission of the Biosphere (L-MEB)] based on radiative transfer equations. The soil and vegetation characteristics needed to initialize the L-MEB model were derived from existing land-cover maps. Continuous simulations from a land-surface scheme for 1987 and 1988 provided time series of the main variables driving t…
X-ray emission from young brown dwarfs in the Orion Nebula Cluster
2005
We use the sensitive X-ray data from the Chandra Orion Ultradeep Project (COUP) to study the X-ray properties of 34 spectroscopically-identified brown dwarfs with near-infrared spectral types between M6 and M9 in the core of the Orion Nebula Cluster. Nine of the 34 objects are clearly detected as X-ray sources. The apparently low detection rate is in many cases related to the substantial extinction of these brown dwarfs; considering only the BDs with $A_V \leq 5$ mag, nearly half of the objects (7 out of 16) are detected in X-rays. Our 10-day long X-ray lightcurves of these objects exhibit strong variability, including numerous flares. While one of the objects was only detected during a sho…
Deep XMM-Newton Observations Reveal the Origin of Recombining Plasma in the Supernova Remnant W44
2019
Recent X-ray studies revealed over-ionized recombining plasmas (RPs) in a dozen mixed-morphology (MM) supernova remnants (SNRs). However, the physical process of the over-ionization has not been fully understood yet. Here we report on spatially resolved spectroscopy of X-ray emission from W44, one of the over-ionized MM-SNRs, using XMM-Newton data from deep observations, aiming to clarify the physical origin of the over-ionization. We find that combination of low electron temperature and low recombination timescale is achieved in the region interacting with dense molecular clouds. Moreover, a clear anti-correlation between the electron temperature and the recombining timescale is obtained f…
Smap-based retrieval of vegetation opacity and albedo
2020
Over land the vegetation canopy affects the microwave brightness temperature by emission, scattering and attenuation of surface soil emission. The questions addressed in this study are: 1) what is the transparency of the vegetation canopy for different biomes around the Globe at the low-frequency L-band?, 2) what is the seasonal amplitude of vegetation microwave optical depth for different biomes?, 3) what is the effective scattering at this frequency for different vegetation types?, 4) what is the impact of imprecise characterization of vegetation microwave properties on retrieval of soil surface conditions? These questions are addressed based on the recently completed one full annual cycl…
Spatio-temporal patterns of thermal anomalies and drought over tropical forests driven by recent extreme climatic anomalies
2018
The recent 2015–2016 El Niño (EN) event was considered as strong as the EN in 1997–1998. Given such magnitude, it was expected to result in extreme warming and moisture anomalies in tropical areas. Here we characterize the spatial patterns of temperature anomalies and drought over tropical forests, including tropical South America (Amazonia), Africa and Asia/Indonesia during the 2015–2016 EN event. These spatial patterns of warming and drought are compared with those observed in previous strong EN events (1982–1983 and 1997–1998) and other moderate to strong EN events (e.g. 2004–2005 and 2009–2010). The link between the spatial patterns of drought and sea surface temperature anomalies in th…