Search results for "TEP"
showing 10 items of 712 documents
Controlling the position of anions relative to a pentafluorophenyl groupw
2012
The position of an anion above an electron-deficient arene can be controlled by the geometry of appended directing groups. Here a series of ammonium substituted pentafluorophenyl derivatives is investigated. The presented results are one step on the way to find the ideal structural features for an effective and superior receptor for anion–π studies.
Synthesis of Tripyreno[2,3,4-abc: 2,3,4-ghi: 2,3,4-mno][18]annulenes
2000
The title compounds were prepared in a multi-step synthesis in which primarily the pyrene building blocks were formed (1,2 11a,b). The final reaction step 11a,b 12a,b consisted of a threefold trans selective cyclocondensation process that generated the central 18-membered ring. Hexyloxy or dodecyloxy sidechains attached on the periphery led to the formation of liquid crystalline phases.
CIGS THIN FILM BY ONE-STEP ELECTRODEPOSITION FOR SOLAR CELLS
2013
In this work, we present a cost-effective technique to produce CIGS thin films for solar cells by means of a single-step electrodeposition. In fact, electrodeposition is known as an easy technique for building low cost materials for photovoltaic device processing. Morphological, structural and optical characterization of these films has been performed.
La heterodoxia en la poesía visual española del siglo XXI
2014
Resumen: Toda vanguardia esconde un malestar y una rebeldia contra la realidad que aflige al individuo y que se vuelve objeto de critica en las obras. En este sentido, tras aclarar a que nos referimos cuando hablamos de poesia visual, analizaremos algunas obras que han aparecido por primera vez en 2014, interpretandolas como reaccion contra la perdida de valores de la sociedad postmoderna. La finalidad sera demostrar que la poesia visual espanola del siglo XXI no ha renunciado a su heterodoxia, puesto que elige justamente este universo donde todo es rapido, fluido, superficial, complejo e inasible para seguir denunciando desde su interior la incomunicacion y la alienacion a la que nos han l…
El procedimiento monitorio en el anteproyecto de código procesal chileno : Algunas consideraciones a partir de la experiencia en derecho español
2009
Se estudian las características del proceso monitorio en el anteproyecto de código procesal civil chileno. En este análisis se realiza primero un estudio sistemático del ACPC, y enseguida se analiza críticamente el anteproyecto dejándose en evidencia sus vacíos e imperfecciones. Con ello, y sobre todo al especificarlas, contribuye precisa y claramente a mejorarlo. The author deals witch the characteristics of the admonitory proceedings in the Chilean civil procedural code draft bill. He first does a systematic study of this draft bill, and then critically analyzes in finding loopholes and imperfections. By doing this, and because he specifies them, he contributes clearly and precisely to im…
Multiple catenanes based on tetraloop derivatives of calix[4]arenes
2009
Abstract Four novel tetraarylurea calix[4]arenes ( 4a – d ) have been synthesized, substituted by ω-alkenyloxy residues in 3,5-positions of the arylurea residues. The eight alkenyl groups were pairwise connected by olefin metathesis and subsequent hydrogenation. The ring-closure reaction was carried out with heterodimers exclusively formed by 4 with a tetratosylurea calix[4]arene 1 , which serves as a template in this reaction step. The potential trans-cavity bridging is entirely suppressed in this way. Bis- and tetraloop calix[4]arenes cannot form dimers due to overlapping loops. However, they readily form heterodimers with open-chain tetraureas, as long as their urea residues can pass thr…
The Variability of the Photosynthetic Unit in Chlorella Fusca
1984
The concept of the photosynthetic unit (PSIT) was introduced by Gaffron and Wohl (1936) on the basis of Emerson and Arnold’s flash light experiments (1932). The PSU was defined as the minimum of chlorophyll molecules required for the evolution of one O2. Later on, the PSU was considered to be the complex of one reaction center and its appropriate antenna of light harvesting chlorophyll molecules. Assuming that there is an equal number of the PS I and PS II reaction centers the PSU was mostly expressed as Chl/P-700. However, recently it could be shown that the ratio of PS II/PS I is variable depending on the light conditions during growth (Kawamura et al., 1979; Myers, Graham, 1982). Further…
Using Y-chromosome capture enrichment to resolve haplogroup H2 shows new evidence for a two-path Neolithic expansion to Western Europe
2021
Uniparentally-inherited markers on mitochondrial DNA (mtDNA) and the non-recombining regions of the Y chromosome (NRY), have been used for the past 30 years to investigate the history of humans from a maternal and paternal perspective. Researchers have preferred mtDNA due to its abundance in the cells, and comparatively high substitution rate. Conversely, the NRY is less susceptible to back mutations and saturation, and is potentially more informative than mtDNA owing to its longer sequence length. However, due to comparatively poor NRY coverage via shotgun sequencing, and the relatively low and biased representation of Y-chromosome variants on capture assays such as the 1240 k, ancient DNA…
The 15 March 2007 explosive crisis at Stromboli Volcano, Italy: assessing physical parameters through a multidisciplinary approach
2011
Basaltic volcanoes are dominated by lava emission and mild explosive activity. Nevertheless, many basaltic systems exhibit, from time to time, poorly documented and little-understood violent explosions. A short-lived, multiblast explosive crisis (paroxysmal explosion) occurred on 15 March 2007 during an effusive eruptive crisis at Stromboli (Italy). The explosive crisis, which started at 20:38:14 UT, had a total duration of ∼5 min. The combined use of multiparametric data collected by the permanent instrumental networks (seismic, acoustic, and thermal records) and a field survey carried out immediately after the event enabled us to constrain the eruptive dynamics and quantify physical param…
Etude numérique d'équations aux dérivées partielles non linéaires et dispersives
2011
Numerical analysis becomes a powerful resource in the study of partial differential equations (PDEs), allowing to illustrate existing theorems and find conjectures. By using sophisticated methods, questions which seem inaccessible before, like rapid oscillations or blow-up of solutions can be addressed in an approached way. Rapid oscillations in solutions are observed in dispersive PDEs without dissipation where solutions of the corresponding PDEs without dispersion present shocks. To solve numerically these oscillations, the use of efficient methods without using artificial numerical dissipation is necessary, in particular in the study of PDEs in some dimensions, done in this work. As stud…