Search results for "TERBIUM"
showing 10 items of 150 documents
CCDC 1904524: Experimental Crystal Structure Determination
2019
Related Article: Diogo Galico, Riccardo Marin, Gabriel Brunet, Dylan Errulat, Eva Hemmer, Fernando Sigoli, Jani Moilanen, Muralee Murugesu|2019|Chem.-Eur.J.|25|14625|doi:10.1002/chem.201902837
Laser-induced anisotropy in terbium-gallium garnet
1998
Ga5O12 crystal when illuminated at the terbium ion resonance, becomes optically uniaxial. The optical axis is found to be along the beam-propagation axis. The origin of this symmetry breakdown is a thermal effect. Our observation of a conoscopic pattern is accounted for by a quadratic stress and refractive index distribution model. By spatial integration of the conoscopic pattern, the laser-induced stress birefringence variation as a function of the incident beam power is determined.
Theoretical and experimental study of the structural stability ofTbPO4at high pressures
2010
We have performed a theoretical and experimental study of the structural stability of terbium phosphate at high pressures. Theoretical ab initio total-energy and lattice-dynamics calculations together with x-ray diffraction experiments have allowed us to completely characterize a phase transition at {approx}9.8 GPa from the zircon to the monazite structure. Furthermore, total-energy calculations have been performed to check the relative stability of 17 candidate structures at different pressures and allow us to propose the zircon {yields} monazite {yields} scheelite {yields} SrUO{sub 4}-type sequence of stable structures with increasing pressure. In this sequence, sixfold P coordination is …
Precision Measurement of the First Ionization Potential of Nobelium
2018
One of the most important atomic properties governing an element's chemical behavior is the energy required to remove its least-bound electron, referred to as the first ionization potential. For the heaviest elements, this fundamental quantity is strongly influenced by relativistic effects which lead to unique chemical properties. Laser spectroscopy on an atom-at-a-time scale was developed and applied to probe the optical spectrum of neutral nobelium near the ionization threshold. The first ionization potential of nobelium is determined here with a very high precision from the convergence of measured Rydberg series to be 6.626 21±0.000 05 eV. This work provides a stringent benchmark for st…
Combined omics approaches reveal distinct responses between light and heavy rare earth elements in Saccharomyces cerevisiae
2022
International audience; The rapid development of green energy sources and new medical technologies contributes to the increased exploitation of rare earth elements (REEs). They can be subdivided into light (LREEs) and heavy (HREEs) REEs. Mining, industrial processing, and end-use practices of REEs has led to elevated environmental concentrations and raises concerns about their toxicity to organisms and their impact on ecosystems. REE toxicity has been reported, but its precise underlying molecular effects have not been well described. Here, transcriptomic and proteomic approaches were combined to decipher the molecular responses of the model organism Saccharomyces cerevisiae to La (LREE) an…
self-assembly and intra-cluster reaction of erbium and ytterbium bis(2-ethylhexyl)sulfosuccinate reverse micelle in gas phase
2014
Electronic structure of the ytterbium monohydroxide molecule to search for axionlike particles
2021
Recently, the YbOH molecule has been suggested as a candidate to search for the electron electric dipole moment (eEDM), which violates spatial parity ($P$) and time-reversal ($T$) symmetries [I. Kozyryev and N. R. Hutzler, Phys. Rev. Lett. 119, 133002 (2017)]. In the present paper, we show that the same system can be used to measure coupling constants of the interaction of electrons and nucleus mediated by axionlike particles. The electron-nucleus interaction produced by the axion exchange can contribute to a $T,P$-violating EDM of the whole molecular system. We express the corresponding $T,P$-violating energy shift produced by this effect in terms of the axion mass and product of the axion…
Dimeric Hydrido Complexes of Rare-Earth Metals Containing a Linked Amido−Cyclopentadienyl Ligand: Synthesis, Characterization, and Monomer−Dimer Equ…
2000
Dimeric hydrido complexes of lutetium, ytterbium, and yttrium containing a linked amido−cyclopentadienyl ligand, [Ln(η5:η1-C5Me4SiMe2NCMe2R)(L)(μ-H)]2 (Ln = Lu, Yb, Y; R = Me, Et; L = THF, PMe3), w...
Metal–Organic Frameworks as Playgrounds for Reticulate Single-Molecule Magnets
2019
Achieving an accurate control on the final structure of Metal-Organic Frameworks (MOFs) is mandatory to obtain target physical properties. Here we describe how the combination of a metalloligand design strategy and a post-synthetic method is a versatile and powerful approach to success on this extremely difficult task. In a first stage, a novel oxamato-based tetranuclear cobalt(III) complex with a tetrahedron-shape geometry is used, for the first time, as metalloligand toward cal-cium(II) cations to lead a diamagnetic Ca(II)-Co(III) three-dimensional (3D) MOF (1). In a second stage, in a single-crystal to single-crystal manner the calcium(II) ions are replaced by terbium (III), dysprosium(I…
Europium(III), Terbium(III), and Gadolinium(III) Oxamato-Based Coordination Polymers: Visible Luminescence and Slow Magnetic Relaxation
2021
The reaction of aqueous solutions of EuIII, TbIII, and GdIII ions with Na2Hpcpa [H3pcpa = N-(4-carboxyphenyl)oxamic acid] afforded three new isostructural oxamate-containing lanthanide(III) coordination polymers of general formula {LnIII2(Hpcpa)3(H2O)5·H2O}n [Ln = Eu (1),Tb (2), and Gd(3)]. Their structure is made up of neutral zigzag chains running parallel to the [101] direction where double syn-syn carboxylate(oxamate)-bridged dilanthanide(III) pairs (Ln1 and Ln2) are linked by three Hpcpa2- ligands, one of them with the μ-κ2O,O':κO″ coordination mode and the other two with the μ3-κ2O,O':κO″:κO'''. Additionally, two of those chains are interlinked through hydrogen bonding and π-π type in…