Search results for "THERMAL"
showing 10 items of 3576 documents
Mixed Grotthuss and Vehicle Transport Mechanism in Proton Conducting Polymers from Ab initio Molecular Dynamics Simulations
2011
We elucidate the microscopic mechanism of long-range proton conduction in poly[vinyl phosphonic acid] (PVPA), a highly promising proton conducting polymer. Using a steered ab initio molecular dynamics approach, we characterize the charge transport functionality of acid groups interacting with nonbulk water molecules intercalated in the polymer. Our results show that in PVPA, unlike in Nafion, water has a local vehicle/carrier function for excess protons. This function must however be combined with the Grotthuss-type conduction mechanism that is supplied by the acid groups in order to yield long-range charge transport. As an additional aspect, we find that contrary to common intuition, syste…
In Situ Synthesis of Conducting Polymers: A Novel Approach toward Polymer Thermoelectrics
2020
The efficient conversion of thermal energy into electricity by means of durable and scalable solid-state thermoelectric devices has been a well stablished aim. Electrically conducting polymers have...
Thermal sensor based on a polymer nanofilm
2016
In this work, we have developed a thermal sensor based on poly(3,4 ethylenedioxythiophene) (PEDOT) nanofilms as thermoelectric material. The PEDOT nanofilms have been synthesized by the electrochemical polymerization method. The thicknesses of the films were around 120 nm. The doping level of PEDOT was controlled by chemical reduction using hydrazine. The achieved Seebeck coeficient is 40 uV/K. A PEDOT nanofilm was integrated into an electronic circuit that amplifies the voltage originated from the Seebeck effect. The temperature increment produced by a fingerprint touching the film is enough to switch on a light emitting diode. Peer Reviewed
Protonic ceramic fuel cell : elaboration and characterization. Investigation of the BaZr0.8Y0.2O3-d electrolyte by electrochemical impedance spectros…
2021
One of the current global challenges is to find novel, clean and efficient techniques for the energy production. The use of electrochemical cells and hydrogen is one of the solutions. These cells convert the excess energy produced by conventional systems into hydrogen by steam electrolysis. The hydrogen can be stored and transformed into electricity when needed in the fuel cell mode. Among the different electrochemical cells, protonic ceramic electrochemical cells have attracted much attention due to their high efficiency at intermediate temperature (400 – 600 °C). In addition, these systems offer the advantage of not diluting the fuel in electrolysis mode. This thesis work focuses on the e…
Synthesis and characterization of novel organic–inorganic hybrid block copolymers
2004
Novel organic–inorganic hybrid block copolymers based on poly(methylsilsesquioxanes) (PMSSQs) have been synthesized. Two routes to functionalized PMSSQs are presented and from both atom transfer radical polymerization of methylmethacrylate could be performed. Copolymers with different block ratios have been polymerized and were characterized. In particular, thermal properties were investigated by TGA and the promising thermal decomposition behaviour makes the copolymers potential candidates as pore generators in future nanoporous materials. Additionally, these copolymers were analysed as surface coatings of regular PMMA. Contact angle measurements proved the dramatic effect on the surface p…
Real-time simulation and control system for the continuous casting process
2005
In this paper we present a real-time system which is used to simulate the unsteady-state continuous casting process and to control the secondary cooling water sprays. The aim of the control system is to keep the surface temperature of the slab constant with respect to time in spite of casting speed variations, and in this way minimize the formation of cracks in the final product. The simulator calculates the temperature distribution using a mathematical model based on a heat conduction formula with phase changes. The optimal spray water flow rates for each spray cooling zone will be calculated by minimizing the deviation between the target surface temperature and the calculated actual surfa…
FE-Modelling of Continuous Casting Problem
1986
A mathematical model for simulating the heat transfer during solidification in continuous casting of steel is presented. The heat transfer coefficients along and across the strand are optimized. The evolution and location of thermal stresses are computed. Numerical examples are included.
Preliminary CAD implementation of EU-DEMO primary heat transfer systems for HCPB breeding blanket option
2019
Abstract This paper focuses on the 3D CAD implementation of the pipework and the main equipment of the Primary Heat Transfer System of EU-DEMO fusion power plant. In particular, the systems related to the Helium-Cooled Pebble Bed Breeding Blanket option are considered here. During the pulse operation, the breeding blanket modules will be the main thermal power source; Divertor and the Vacuum Vessel will contribute in the definition of the total reactor power. All the In-Vessel generated power is rejected to the Power Conversion System through a molten salt Intermediate Heat Transport System. The latter is equipped with an Energy Storage System to allow for continuous operation also during t…
Solitary Waves for the Assessment of Thermal Stress and Neutral Temperature in Slender Structures
2015
Slender columns and continuous welded rails subjected to compressive stress are common in many civil structures. The rapid in-situ measurement of this stress may be of interest to prevent structural anomalies such as buckling. In this article, the authors describe the coupling mechanism between highly nonlinear solitary waves (HNSWs) propagating along an L-shaped granular system and a beam in contact with the granular medium. The aim is the evaluation of HNSWs as a tool to measure stress in thermally loaded structures and to estimate the neutral temperature, i.e. the temperature at which this stress is null. The authors investigated numerically and experimentally one chain of spherical part…
Investigation on a Bio-Composite Material as Acoustic Absorber and Thermal Insulation
2020
In order to limit the anthropic emissions of CO2, research is currently investigating new materials for the building sector. The main purpose is the reduction in the embodied energy consumption, especially in the residential sector, and consequently the limitation of the direct and indirect utilization of fossil fuels, for the indoor heating, cooling, and ventilation services. Indeed, the residential sector is affected by a high energy demand, thus the choice of improved materials is fundamental to improve the sustainability. All phases: construction, building life, and dismantling are impacting in terms of resource and energy consumption, both associated with the emissions of pollutants in…