Search results for "TRIM"

showing 10 items of 1942 documents

Cocrystal trimorphism as a consequence of the orthogonality of halogen- and hydrogen-bonds synthons.

2019

True trimorphic cocrystals, i.e. multi-component molecular crystals of identical composition that exhibit three polymorphic structures, are exceedingly rare and so far no halogen-bonded cocrystal system has been reported to exhibit trimorphism. Here we describe a unique example of a trimorphic cocrystal exhibiting both hydrogen and halogen bonds in which the differences between polymorphs reveal their orthogonality, evident by the apparently independent variation of well-defined hydrogen- and halogen-bonded motifs. peerReviewed

inorganic chemicalsHydrogenchemistry.chemical_element010402 general chemistry01 natural sciencesCocrystalCatalysiskemialliset sidoksetOrthogonalityTrimorphismMaterials Chemistrysupramolekulaarinen kemiavetysidokset010405 organic chemistryHydrogen bondSynthonMetals and Alloysorthogonality halogen bond hydrogen bond cocrystal trimorphismGeneral Chemistrykiteet0104 chemical sciences3. Good healthSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCrystallographychemistryHalogenCeramics and CompositesChemical communications (Cambridge, England)
researchProduct

Modeling of the N-terminal Section and the Lumenal Loop of Trimeric Light Harvesting Complex II (LHCII) by Using EPR

2015

The major light harvesting complex II (LHCII) of green plants plays a key role in the absorption of sunlight, the regulation of photosynthesis, and in preventing photodamage by excess light. The latter two functions are thought to involve the lumenal loop and the N-terminal domain. Their structure and mobility in an aqueous environment are only partially known. Electron paramagnetic resonance (EPR) has been used to measure the structure of these hydrophilic protein domains in detergent-solubilized LHCII. A new technique is introduced to prepare LHCII trimers in which only one monomer is spin-labeled. These heterogeneous trimers allow to measure intra-molecular distances within one LHCII mon…

inorganic chemicalsModels MolecularProtein ConformationProtein domainTrimerContext (language use)complex mixturesBiochemistrylaw.inventionchemistry.chemical_compoundBiopolymersProtein structurelawElectron paramagnetic resonanceMolecular BiologySuperhelixfungiElectron Spin Resonance SpectroscopyPhotosystem II Protein ComplexCell Biologyequipment and suppliesCrystallographyMonomerModels ChemicalchemistryThylakoidProtein Structure and FoldingbacteriaJournal of Biological Chemistry
researchProduct

The CdCl2 effects on synthetic DNAs encaged in the nanodomains of a cationic water-in-oil microemulsion

2011

The present work is dedicated to the study of the interactions of CdCl(2) with the synthetic polynucleotides polyAT and polyGC confined in the nanoscopic aqueous compartment of the water-in-oil microemulsion CTAB/pentanol/hexane/water, with the goal to mimic in vitro the situation met by the nucleic acids in vivo. In biological structures, in fact, very long strings of nucleic acids are segregated into very small compartments having a radius exceedingly smaller than the length of the encapsulated macromolecule. For comparison, the behaviour of polyGC was also studied in aqueous solutions of matched composition. The conformational and thermal stabilities of both polynucleotides enclosed in t…

inorganic chemicalsnanodomaincadmiumPolynucleotideswater-in-oil microemulsion; cadmium; model polynucleotidesGeneral Physics and AstronomyDissociation (chemistry)model polynucleotideschemistry.chemical_compoundCadmium ChlorideHexanesOrganic chemistryMicroemulsionPhysical and Theoretical ChemistryAqueous solutionconformational transitionCetrimoniumChemistryCationic polymerizationWaterDNAHexaneUV and CD spectroscopiesreverse micelleChemical engineeringwater-in-oil microemulsionPolynucleotideCetrimonium CompoundsNucleic acidCationic w/o microemulsionEmulsionssynthetic polynucleotideOilsMacromolecule
researchProduct

Il "trust antimafia" tra principi generali e interessi antagonisti

2012

interessi confliggentigaranzia patrimoniale.Settore IUS/01 - Diritto Privatotrustlegislazione antimafia
researchProduct

La sostenibilità della coppia mista fra familiare e sociale

2013

La ricerca analizza sia i processi macrosociali, riferiti alla comunità, sia i processi micro, propri della dinamica di coppia. Per i primi abbiamo esaminato la percezione di diversità che può scaturire dalle dinamiche intergruppali e l’identità di luogo (intesa come radicamento nel nuovo contesto di accoglienza); per le dinamiche di coppia si sono prese in esame l’impatto che la presenza dei figli genera sulla dinamica di coppia e gli stili educativi adottati. Coerentemente con il metodo d’indagine della ricerca qualitativa, sono state intervistate 22 coppie miste residenti in Sicilia. Il contenuto emerso è stato analizzato con l’ausilio del software Atlas.ti. Tra gli aspetti più salienti …

intermarriage mixed couple discrimination educational styles support network of family identity of placematrimonio interculturale coppie miste discriminazione stili educative rete di sostegno familiare identità di luogo.Settore M-PSI/07 - Psicologia Dinamica
researchProduct

Self-assembly mechanism based on charge density topological interaction energies

2017

The packing interactions have been evaluated in the context of the self-assembly mechanism of crystal growth and also for its impacts on the aromaticity of the trimesate anion. The structure of ethylammonium trimesate hydrate (1) measured at 100 K and a charge density model, derived in part from theoretical structures, is reported. Theoretical structure factors were obtained from the geometry-optimized periodic wave function. The trimesic acid portion of 1 is fully deprotonated and participates in a variety hydrogen bonding motifs. Topological analysis of the charge density model reveals the most significant packing interactions and is then compared to a complementary analysis performed by …

intermolecular interactions010405 organic chemistryChemistryHydrogen bondsupramolecular synthonsIntermolecular forceCharge densityAromaticityContext (language use)010402 general chemistryCondensed Matter PhysicsTopology01 natural sciences0104 chemical sciencestopological analysischemistry.chemical_compoundcharge densitySelf-assemblyTrimesic acidPhysical and Theoretical ChemistryHydrateStructural Chemistry
researchProduct

La cessazione dell'istanza (artt. 143-154)

2008

istanza processo matrimonio parte cessazione sospensioneSettore IUS/11 - Diritto Canonico E Diritto Ecclesiastico
researchProduct

2.3.4. Il processo di alienazione: Palazzo Barlotta di San Giuseppe e Palazzo Miano

2010

Il processo di alienazione del patrimonio costruito messo in atto dalle pubbliche amministrazioni impossibilitate a far fronte a costi di gestione e manutenzione dei beni in loro possesso ha posto la necessità di indirizzare e controllare i processi di trasformazione cui inevitabilmente i beni alienati saranno sottoposti. Ciò ha imposto che le pubbliche amministrazioni si dotino di nuove procedure e strumenti attraverso cui esercitare l’azione di indirizzo e di controllo sugli interventi previsti in modo da garantire funzioni compatibili e la permanenza dei valori espressi dai beni stessi. Nel contributo si riporta l’iter di alienazione seguito per alcuni immobili di proprietà comunale inse…

iter di alienazione patrimonio costruito cartolarizzazione beni demanialiSettore ICAR/12 - Tecnologia Dell'Architettura
researchProduct

Nāves metafora Ovidija Skumjajās elēģijās

2022

Bakalaura darbā pētīta un analizēta Ovidija darbā Skumjās elēģijas atainotā nāves metafora, tās funkcija tekstā un poētiskais potenciāls. Bakalaura darba mērķis ir, apzinot Ovidija biogrāfiju un darbu Skumjās elēģijas, atklāt un analizēt darbā izmantoto nāves metaforu. Pirmkārt, darbā apzināts teorētiskais materiāls, kas nepieciešams nāves metaforu analīzei. Otrkārt, atlasītas un klasificētas nāves metaforu iekļaujošas tekstvietas. Treškārt, analizēta to funkcionalitāte tekstā un poētiskais pienesums dzejas darbam kopumā. Bakalaura darbā apstiprināta izvirzītā hipotēze, ka nāves metaforas lietojuma biežums un daudzveidīgais izmantojums Ovidija darbā Skumjās elēģijas liecina par autora iecer…

izsūtīšana trimdāValodniecībaSkumjās elēģijasOvidijsvientulībanāves metafora
researchProduct

ESTUDIO DEL EFECTO INFORMATIVO DEL ANUNCIO DE BENEFICIOS TRIMESTRALES

2005

In this research we investigate whether quarterly earnings announcements are informative using awide sample of firms listed in the Spanish Stock Market (SIBE). We study the period comprised between thethird quarterly of 2002 and the fourth quarterly of 2003. We analyse whether abnormal returns are related tothe quarter in which the announcement is released, whether the announcement implies good or bad news forthe firm, the source of the information, the size of the firm and whether the firm is followed by analysts.Results show that quarterly earnings announcements are informative. We also obtain evidence of a possibleuse of insider information in the case of the announcements disclosed in t…

jel:G14jel:G19Anuncio de beneficios trimestrales rendimiento anormal información privilegiada Quarterly earnings announcements abnormal returns insider information.jel:G12
researchProduct