Search results for "TUNNEL"
showing 10 items of 576 documents
Tuning the Kondo resonance in two-dimensional lattices of cerium molecular complexes
2018
International audience; Cerium intermetallics have raised a lot of interest for the past forty years thanks to their very unusual and interesting electronic and magnetic properties. This can be explained by the peculiar electronic configuration of Ce (4f1) that allows different oxidation states leading to singular behavior such as quantum phase transitions, heavy-fermion behavior and the Kondo effect. In this work, we used a mixed-valence molecular analogue to study the Kondo effect down to the atomic scale by means of scanning tunneling microscopy/spectroscopy (STM/STS) for which new many-body effects are expected to emerge due to reduced dimensionality and specific chemical environment of…
Intermolecular potential and rovibrational states of the H2O–D2 complex
2012
International audience; A five-dimensional intermolecular potential for H2O-D-2 was obtained from the full nine-dimensional ab initio potential surface of Valiron et al. [P. Valiron, M. Wernli, A. Faure, L. Wiesenfeld, C. Rist, S. Kedzuch, J. Noga, J. Chem. Phys. 129 (2008) 134306] by averaging over the ground state vibrational wave functions of H2O and D-2. On this five-dimensional potential with a well depth D-e of 232.12 cm (1) we calculated the bound rovibrational levels of H2O-D-2 for total angular momentum J = 0-3. The method used to compute the rovibrational levels is similar to a scattering approach-it involves a basis of coupled free rotor wave functions for the hindered internal r…
Self-trapped holes and recombination luminescence in LiBaF3 crystals
2001
Abstract We investigated electron paramagnetic resonance (EPR) angular dependencies, recombination afterglow and thermostimulated luminescence of undoped LiBaF3 crystals, X-irradiated at low temperatures. EPR parameters of the F2− molecule oriented along the [1 1 0] direction have been obtained. Based on the value of the g-shift Δg=g⊥−gII=0.02, characteristic for the VK-centres in similar perovskites, we propose that we indeed observed the VK-centres, not the H-centres. X-irradiation below 170 K results in creation of a long-time temperature-independent afterglow due to the tunnelling recombination between close electron and hole centres. The F-type electron centres and the VK as well as pr…
Spectral Measurement of Photon Emission from Individual Gold Nanoparticles Using Scanning Tunneling Microscopy
2016
The light emission spectra of individual Au nanoparticles induced by a scanning tunneling microscope (STM) have been investigated. Two-dimensional ensembles of tunnel-coupled Au particles were prepared by thermal evaporation onto a native oxide silicon wafer in ultrahigh vacuum (10 – 9 mbar). Our STM measurements show a single peak at photon energy 1.6 eV in the tunneling mode and two peaks at 2.2 eV (connected with the Mie plasmon) and 1.45 eV (a new peak which was not discussed in literature before) in the field emission mode.
Localised transitions in luminescence of AlN ceramics
2014
Abstract The photoluminescence (PL) and thermoluminescence (TL) properties of AlN ceramics revealed under UV irradiation are determined mainly by oxygen-related centres, giving rise to the UV (around 3.18 eV) and the Blue (2.58 eV) bands. It was found that the UV irradiation-generated donor–acceptor pairs (DAPs), responsible for the UV emission band, are randomly distributed with regard to separation distance. Luminescence properties of AlN are interpreted basing on the model of localised recombination involving electron tunnel transitions from the excited state of D to the ground state of A, proposed by Jain et al. (2012) . The observed features of PL, afterglow and TL of AlN ceramics are …
Trap spectroscopy and tunnelling luminescence in feldspars
1998
Abstract Comparative studies of tunnel luminescence, thermally stimulated luminescence (TSL), and trap energy spectra by the fractional glow technique (FGT) have been made both with sanidine and microcline feldspars. After X-irradiation at LNT these feldspars show intense tunnelling afterglow. As the temperature is raised, several TSL glow peaks may be observed, starting at 135 K. An intense peak at 250 K is common to all four investigated microclines. In samples of sanidine, tunnelling afterglow overcomes TSL up to 250–260 K. With sanidine and microcline samples, the distributions of trap activation energies vs temperature obtained by the FGT are continuous and quasi-linear. Maxima in the …
Electronic transport in intermediate sized carbon nanotubes
2009
We have studied systematically basic transport properties of multiwalled carbon nanotubes in a relatively unexplored diameter range, corresponding to tubes just slightly larger than single- or double-walled tubes to tubes up to 17 nm in diameter. We find in all the smaller tubes a gap in the transport data which increases with decreasing tube diameter. Within the gap region of several tubes, negative differential resistance was observed at small or moderate biases and at bias values that scaled inversely with the tube diameter. For this latter type of behavior of the conductance, we tentatively propose interlayer resonant tunneling as the cause.
Structures de déformation induites par surpressions de fluide dans les environnements sous-glaciaires et marin profonds : implications paléoenvironne…
2014
Soft-sediment deformation structures (SSDs) occur in unconsolidated sediments, during or shortly after deposition. SSDs are abundant in subglacial and deep-marine environments because of the development of fluid overpressure. Case studies of these two sedimentary environments were used (1) to reconstruct palaeoenvironments from SSDS, and (2) to define the impacts of SSDS on glacial morphologies and (3) petrophysical properties.(1) Analyses of strain regimes, deformation mechanisms, and chronologies in SSDs served to improve palaeoenvironmental reconstructions. These structures were used as proxys to estimate variations of ice flow velocities, ice thickness, meltwater production, and positio…
Preparation and structural analysis of Fe2+xTi1−x thin films in the C14 Laves phase stability range
2002
Abstract We report the epitaxial growth of single phase (0 0 1)-oriented thin films of Fe2+xTi1−x in the C14 Laves phase stability range using molecular beam epitaxy (MBE). The growth was studied by reflection high-energy electron diffraction (RHEED) and X-ray diffraction (XRD). The onset temperature for epitaxial growth and the temperature range for improved crystalline coherence were identified. From X-ray reflectometry analysis the rms roughness was estimated to 0.5 nm for typical film thicknesses of 22 nm. As revealed by scanning tunneling microscopy (STM), this roughness is discrete and due to step edges corresponding to the full c-axis length of Fe2Ti. The epitaxial growth implies an …
Morphology and magnetoresistance of Co2Cr0.6Fe0.4Al-based tunnelling junctions
2009
Some ferromagnetic Heusler compounds are theoretically predicted to be half metallic materials, i.e. to be characterized by a huge spin polarization at the Fermi energy. We investigate the correlations between junction preparation conditions, morphology and transport properties of planar MgO/Co2Cr0.6Fe0.4Al/AlOx/Co/CoOx/Pt tunnelling junctions. Epitaxial Co2Cr0.6Fe0.4Al thin films were deposited by dc and rf magnetron sputtering on different buffer layers (Cr, Fe, MgO) on MgO(1 0 0) substrates. By RHEED, LEED and in situ STM investigations different surface morphologies were observed. Atomically flat surfaces with Co2Cr0.6Fe0.4Al unit cell sized steps (B2 structure) were obtained by rf sput…