Search results for "Terbium"
showing 10 items of 150 documents
Atomic transition probabilities for selected Yb II lines emitted from a ferroelectric plasma source
2010
The relative intensities of several hundred emission lines of Yb II between 200 nm and 900 nm were obtained with the use of ferroelectric plasma source. These relative intensities obtained for lines from 21 energy levels have been used to determine the line branching fractions, which have then been combined with accurate experimental radiative lifetime measurements to give absolute transition probabilities for 111 Yb II lines. The obtained values were compared with theoretical and experimental data taken from available literature.
Ytterbium-doped fiber laser as pulsed source of narrowband amplified spontaneous emission
2019
AbstractWe report random noise pulsed regime of an ytterbium-doped fiber laser arranged in common Fabry-Perot configuration. We show that the laser output obeys the photon statistics inherent to narrowband amplified spontaneous emission and that the noise pulsing is properly addressed in terms of probability density and autocorrelation functions. Our novel approach reveals, in particular, that the regime’s coherence time dramatically shortens, from few ns to tens ps, with increasing laser power.
Linear Coassembly of Upconversion and Perovskite Nanoparticles: Sensitized Upconversion Emission of Perovskites by Lanthanide‐Doped Nanoparticles
2020
Sensitized emission of lead halide perovskite nanoparticles (LHPNPs) can be achieved by near‐infrared (NIR) excitation of nearby lanthanide‐doped upconversion nanoparticles (UCNPs) by using a low‐cost diode laser. Here, the first preparation of linear assemblies of core and core–shell NPs, as well as linear coassemblies of LHPNPs and UCNPs, within an open peapod‐like lead sulfate shell are reported. UCNPs with a NaYF4 matrix doped with ytterbium and thulium or erbium, and with an inert shell of NaYF4 in the case of core‐shell, and all‐inorganic CsPbX3 NPs (X = halide) are chosen for these studies. Interestingly, the lead sulfate shell enhances the luminescence of the core/core– shell UCNPs …
On the development of a new approach to the design of lanthanide-based materials for solution-processed OLEDs
2019
The targeted design of lanthanide-based emitters for solution-processed organic light-emitting diodes (OLEDs) resulted in obtaining an NIR OLED with one of the highest efficiencies among ytterbium-based solution-processed OLEDs (30 μW W-1). The design was aimed at the combination of high luminescence efficiency with solubility and charge carrier mobility. The latter was achieved thanks to the introduction of the purposefully selected neutral ligands, which combine electron mobility and the ability to sensitize lanthanide luminescence. Besides, the HOMO and LUMO energies and charge carrier mobility of solution-processed thin films of coordination compounds were measured experimentally for th…
Chemistry of lanthanide–metal carbonyl systems: the ytterbium–chromium carbonyls interaction
2001
Abstract The interaction of the chromium carbonyl hydrides HCr2(CO)10− or HCr(CO)5− with Yb(acac)3·3H2O has been investigated, and the experimental conditions leading to the isolation of ytterbium–chromium carbonyl complex species are reported. Formulation of the coordination compounds produced by such interactions has been proposed on the basis of analytical data and IR spectroscopy.
Physicochemical Investigation of Nanostructures in Liquid Phases: Ytterbium Nitrate Ionic Clusters Confined in Ytterbium Bis(2-ethylhexyl) Sulfosucci…
2007
The confinement of finite amounts of ytterbium nitrate in the nanoscopic space of ytterbium bis(2-ethylhexyl)sulfosuccinate (Yb(DEHSS) 3 ) reversed micelles dispersed in n-heptane has been investigated by UV-vis-NIR, FT-IR, and SAXS. The analysis of the experimental data is consistent with the hypothesis that Yb(NO 3 ) 3 is distributed among reversed micelles as small size ionic clusters surrounded by the Yb 3+ surfactant counterions and anionic heads while the surfactant alkyl chains point toward the solvent medium. As a consequence of confinement and interfacial effects, the ionic clusters display photophysical properties different from those in the bulk state or isolated species. Moreove…
On erbium lattice location in ion implanted Si0.75Ge0.25 alloy
2003
A high crystalline quality Si0.75Ge0.25 alloy layer grown by chemical vapor deposition was implanted with 70 keV Er+ ions to a fluence of 1015 cm−2 at temperature of 550 °C. The implantation was found to result in an Er depth distribution with 1 at. % maximum concentration 30 nm beneath the surface. The location of the erbium atoms in the host matrix lattice is derived through computer simulation of experimental axial channeling angular scans measured by in situ Rutherford backscattering/channeling spectrometry. Using computer code FLUX 7.7 it is shown that 60% of the implanted erbium atoms are located at ytterbium sites, 10% at tetrahedral sites, and the remainder are associated with rando…
Highly Efficient Holmium-Doped All-Fiber ∼2.07-μm Laser Pumped by Ytterbium-Doped Fiber Laser at ∼1.13 μm
2018
We report a 2.07-μm Holmium-doped all-fiber laser (HDFL) pumped by a 1.13-μm Ytterbium-doped fiber laser (YDFL). Home-made alumino–germano–silicate holmium-doped fiber (HDF) served here as an active medium, optimized in terms of chemical composition and co-dopants’ concentrations. Laser action at 2.07 μm was assessed in simple Fabry–Perot cavity, formed by a couple of home-made fiber Bragg gratings (FBGs), inscribed directly in the HDF; this allowed notable diminishing of intracavity loss of the 2.07-μm laser. HDF was in-core pumped by the 1.13-μm double-clad YDFL with a power of ∼12.5 W, in turn pumped in-clad by a laser diode (LD) operated at 0.97 μm with ∼24.5-W output. Using optimal len…
All polarization-maintaining passively modelocked ytterbium-doped fiber lasers, behavior under two different cavity configurations
2020
Fil: Cuadrado-Laborde, Christian. Universidad de Valencia. Departamento de Física Aplicada; España Fil: Cuadrado-Laborde, Christian. Consejo Nacional de Investigaciones Científicas. Instituto de Física Rosario; Argentina Fil: Cuadrado-Laborde, Christian. Pontificia Universidad Católica Argentina. Facultad de Química e Ingeniería del Rosario; Argentina Fil: Carrascosa, Antonio. Universidad de Valencia. Departamento de Física Aplicada; España Fil: Diez, Antonio. Universidad de Valencia. Departamento de Física Aplicada; España Fil: Cruz, J. L. Universidad de Valencia. Departamento de Física Aplicada; España Fil: Andrés, M. V. Universidad de Valencia. Departamento de Física Aplicada; España Abs…
The formal redox potential of the Yb(III,II) Couple at 0°C in 3.22 molal NaCl medium
2004
Following our previous investigations on aqueous solutions of hypooxidized and iperoxidized species, we managed, by lowering the temperature of the solutions to 0 degrees C, to obtain, by electrochemical methods, Yb(II) and Yb(III) mixtures, enough stable to determine by a potentiometric method the formal redox potential of the Yb(IlI, II) couple. Its value, in a large range of total Ytterbium concentration, is -1233 +/- 3 mV against the molal hydrogen electrode in the 3.22 m NaCl medium.