Search results for "Terbium"
showing 10 items of 150 documents
2,3-Dihydro-1,2,6-thiadiazine 1-Oxides by Biginelli-Type Reactions with Sulfonimidamides under Mechanochemical Conditions.
2021
Biginelli-type multicomponent reactions (MCRs) with NH-free sulfonimidamides provide 2,3-dihydro-1,2,6-thiadiazine 1-oxides in high yields. The couplings are performed in a planetary ball mill under solvent-free mechanochemical conditions. Acetic acid or ytterbium triflate are used as catalysts. A representative product was characterized by X-ray single crystal structure analysis revealing molecular details of the highly functionalized three-dimensional heterocycle. Further product modifications lead to additional structural scaffolds.
Sulfur Dioxide Oxidation Catalyzed by Photosensitized Ytterbium Diphthalocyanine
2008
Oxidation of SO2 into SO3 was found effectively catalyzed by photosensitized ytterbium diphthalocyanine, YbPc2 (Pc = phthalocyanine ligand, C32H16N8) when performed in air-saturated dimethylformamide (DMF) solution at 20 °C. The process follows according to a multi-step complex mechanism involving chemical induction as its driving force. Excitation energy of the sandwich molecular system in YbPc2 is used to promote the reaction by creating a reactive intermediate form of the ytterbium complex hosting up to eight SO2 molecules. The conversion of SO2 proved complete.
Luminescence properties of zirconia nanocrystals prepared by solar physical vapor deposition
2014
Abstract Zirconia nanocrystals have attracted considerable interest as biolabels, which can be used as probes for medical imaging and biosensor applications. However, zirconia particle agglomeration forms a major limitation to its use for biolabeling. In this backdrop, for the first time, well-separated zirconia nanocrystals were obtained in a Heliotron reactor (PROMES CNRS, France) via the solar physical vapor deposition (SPVD) method. As the raw material target for solar evaporation, zirconia nanopowders obtained via the sol–gel process were used. The luminescence and upconversion luminescence properties of the Sol Gel nanopowders were compared with those of the SPVD nanocrystals. Erbium …
ZnO – Yb2O3 composite optical ceramics: Synthesis, structure and spectral-luminescent properties
2022
International audience; Zinc oxide optical ceramics containing 0 – 2 wt% ytterbium are prepared byuniaxial hot pressing of commercial oxides at 1150 and 1180 °C. The ceramics have themain crystalline phase of hexagonal wurtzite-type ZnO. Ytterbium ions do not enter theZnO crystals but form a cubic sesquioxide phase of Yb2O3 located at the ZnO grainboundaries. Yb acts as an inhibitor for the ZnO grain growth. The ceramics exhibittransmittance up to 60% in the visible. Their transmission in the infrared is determinedby the free charge carrier absorption. The Yb3+ ions are found in C2 and C3i sites in Yb2O3crystals. Under X-ray excitation, the ceramics exhibit intense luminescence bands in the…
NIR‐NIR‐Aufkonvertierung in molekularen Chrom‐Ytterbium‐Salzen
2020
Photonen-Aufkonvertierung in hetero-oligonuklearen, Metallkomplex-Architekturen mit organischen Liganden ist ein interessantes, aber bisher selten beobachtetes Phanomen, trotz des grosen Potentials sowohl aus Sicht der Grundlagenforschung als auch aus der Anwendungsperspektive. Nun wurde ein neues photonisches Material aus molekularen Chrom(III)- und Ytterbium(III)-Komplexionen entwickelt. Dieses zeigt im Festkorper bei Raumtemperatur abhangig von der Anregungsleistungsdichte nach Anregung des 2F7/2! 2F5/2-3berganges des Ytterbiums bei ca. 980 nm eine kooperative Sensibilisierung der Chrom(III)-zentrierten 2E/2T1-Phosphoreszenz bei ca. 775 nm. Der Aufkonvertierungsprozess ist unempfindlich …
Efficient and Mild Ytterbium(III)-Catalyzed Tosylation of Alcohols.
2004
Ytterbium(III) trifluoromethanesulfonate efficiently catalyzes the reaction of primary and secondary alcohols with toluenesulfonic acid anhydride to yield the alkyl tosylates in high yields. The reactions were carried outunder neutral and mild conditions and product purification was easily achieved by means of short column chromatography.
All polarization-maintaining passively mode-locked fiber-ring ytterbium-doped laser; from net-normal to net-anomalous dispersion
2020
We investigated the behavior of a fiber-ring polarization-maintaining passively modelocked ytterbium-doped laser in a broad range of dispersion values; i.e., from highly net-normal to net-anomalous, with a special emphasis near the zero of chromatic dispersion. Different lengths of an ad hoc polarization-maintaining photonic crystal fiber were used as intracavity dispersion compensator to shift the operation of this laser from net-normal to the net-anomalous regime. The laser generated the shortest light pulses around the zero of dispersion: 6 ps / 7ps for −0.023 ps2 / 0.045 ps2 ; in both cases, pulses were not transform-limited, being theoretically possible an out-of-cavity recompression d…
Coexistence of quasi-CW and SBS-boosted selfQ-switched pulsing in ytterbium-doped fiber laser with low Q-factor cavity
2020
We report the results of an experimental study of an ytterbium-doped fiber laser with low Q-factor cavity. We demonstrate that the laser operates in two randomly alternating sub-regimes, quasi-CW (QCW) and self-Q-switching (SQS), the latter ignited by stimulated Brillouin scattering (SBS). We show that probability of each sub-regime depends on pump power: QCW dominates slightly above the laser threshold while SQS pulsing prevails at higher pump powers. We also discuss the featuring details of QCW sub-regime and its role in instabilities (jittering) of SBS-boosted SQS pulsing as well as the statistical properties of the latter.
Self-focusing in Terbium Gallium Garnet using Z-scan
1998
International audience; When illuminated near its resonance with an Ar ion laser beam (lambda=488 nm), laser induced thermal self-focusing is observed in Terbium Gallium Garnet. The crystal exhibits a strong intensity dependent refractive index change Dn. The Z-scan technique is used to study the beam waist change due to Dn. The refractive index is found to be well described by a quadratic spatial distribution model. Both the sign and the distribution coefficient of Dn are determined.
Pulse timing effects in bulk Er/Yb codoped diode-pumped eyesafe lasers
2007
In this work, diode-pumping with appropriately modulated pulses is used to expose subtle input / output pulse-timing characteristics of Er3+ /Yb3+ systems, study their relation to laser efficiency and demonstrate some unique laser-pulse timing behavior. Er+3/Yb+3 codoped glass and YAG laser-host materials with similar concentrations (optimized for eyesafe emission in the 1.6-mum region) were studied in the same diode-pumped setup, in similar resonator configurations and analogous operating conditions.