Search results for "Tetramethylammonium"

showing 9 items of 109 documents

CCDC 275029: Experimental Crystal Structure Determination

2006

Related Article: H.Mansikkamaki, M.Nissinen, K.Rissanen|2005|CrystEngComm|7|519|doi:10.1039/b508191b

bis(281420-Tetramethyl-46101216182224-octahydroxycalix(4)arene) tetramethylammonium clathrate chloride ethanol solvate trihydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1480930: Experimental Crystal Structure Determination

2016

Related Article: Marta Mon, Thais Grancha, Michel Verdaguer, Cyrille Train, Donatella Armentano and Emilio Pardo|2016|Inorg.Chem.|55|6845|doi:10.1021/acs.inorgchem.6b01256

catena-[hexakis(Tetramethylammonium) dodecakis(mu-oxalato)-tetra-chromium(iii)-tri-manganese(ii) methanol solvate]Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

Enantioselective self-assembly of antiferromagnetic hexacopper(ii) wheels with chiral amino acid oxamates

2013

The Cu(2+)-mediated self-assembly of oxamato-based ligands derived from either the (S)- or (R)-enantiomers of the amino acid valine leads to the formation of two antiferromagnetically coupled homochiral anionic hexacopper(II) wheels in the presence of templating tetramethylammonium countercations.

chemistry.chemical_classificationTetramethylammoniumStereochemistryMagnetic PhenomenaMetals and AlloysEnantioselective synthesisStereoisomerismValineGeneral ChemistryLigandsCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsAmino acidchemistry.chemical_compoundchemistryCoordination ComplexesValineMaterials ChemistryCeramics and CompositesAntiferromagnetismSelf-assemblyCopperChemical Communications
researchProduct

Studien zum Vorgang der Wasserstoffübertragung 36 [1] Einfluß von Art und Struktur einiger Leitsalze auf die elektrochemische Spaltung von Diarylsulf…

1975

Tensammetrische Messungen bestatigen, das Tetraalkylammoniumsalze in Methanol mit steigender Kettenlange der Alkylreste und wachsender Konzentration zunehmend starker an der Quecksilberoberflache adsorbiert werden. Polarographie und Zyklovoltammetrie der Diarylsulfone 1–8 in Methanol lassen folgende Schlusse zu: 1 Unabhangig von der Alkylkettenlange der Tetraalkylammoniumsalze werden die Diarylsulfone 1–6 nach einem ECE-Mechanismus gespalten. Bei Verwendung von Alkalileitsalzen sind die genannten Sulfone polarographisch inaktiv. 2 Beim 4-Cyano-diphenylsulfon wird mit Tetramethylammoniumchlorid zyklovoltammetrisch keine Reversibilitat des ersten Elektronen ubergangs beobachtet, wohl aber mit…

chemistry.chemical_compoundAmmonium bromidechemistryDiphenyl sulfoneGeneral Chemical EngineeringPolymer chemistryTetramethylammonium chlorideLithium chlorideAmmoniumAmmonium chlorideSodium perchlorateElectrochemistryBerichte der Bunsengesellschaft für physikalische Chemie
researchProduct

CCDC 883545: Experimental Crystal Structure Determination

2012

Related Article: J.Vallejo, J.Cano, I.Castro, M.Julve, F.Lloret, O.Fabelo, L.Canadillas-Delgado, E.Pardo|2012|Chem.Commun.|48|7726|doi:10.1039/c2cc33674j

hexakis(Tetramethylammonium) (mu~4~-carbonato)-bis(mu~3~-23-quinoxalinediolato)-tetrakis(mu~2~-23-quinoxalinediolato)-tetraaqua-di-gadolinium-di-potassium heptahydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

Hypoosmolar conditions reduce extracellular volume fraction and enhance epileptiform activity in the CA3 region of the immature rat hippocampus

2006

The osmolarity of the extracellular space (ECS) compartment is an important factor determining the excitability of neuronal tissue. In the adult hippocampus an important role of osmolarity and ECS diffusion parameters on the susceptibility to epileptic events is well established, but the influence of hypo- and hyperosmolar conditions on the immature hippocampus remains elusive. To investigate the influence of osmolarity on epileptiform activity, extracellular field potentials were recorded in the CA3 region of hippocampal slices of immature (postnatal days 4-7) Wistar rats. The ECS diffusion parameters were determined by the real-time tetramethylammonium (TMA+) iontophoretic method with ion…

medicine.medical_specialtyHippocampusAlpha (ethology)In Vitro TechniquesHippocampal formationHippocampusCellular and Molecular Neurosciencechemistry.chemical_compoundInternal medicinePotassium Channel BlockersmedicineExtracellularAnimalsMagnesium4-AminopyridineRats WistarNeuronsOsmoleTetramethylammoniumEpilepsyDose-Response Relationship DrugOsmotic concentrationIontophoresisOsmolar ConcentrationRatsQuaternary Ammonium CompoundsEndocrinologyAnimals NewbornHypotonic SolutionschemistryExtracellular SpaceNeuroscienceJournal of Neuroscience Research
researchProduct

Crystal structure and Hirshfeld surface analysis of [N(CH3)4][2,2′-Fe(1,7-closo-C2B9H11)2]

2017

Abstract This work investigates the meta -ferrabis(dicarbollide) anion that was isolated as salt of tetramethylammonium. The structure of the obtained crystal consisted of discrete [2,2′-Fe(1,7- closo -C 2 B 9 H 11 ) 2 ] − anions and disordered [N(CH 3 ) 4 ] + cations. The anion had a considerable chemical stability ensured by ionic and Van der Waals interactions. Thus, Hirshfeld surfaces and fingerprint plot were used to visualize, explore, and quantify intermolecular interactions in the crystal lattice of the title compound. This investigation proved that close contacts were dominated by H⋯H interactions.

structures: crystalsIonic bondingCrystal structure010402 general chemistrychemistry01 natural sciencesBiochemistryIonInorganic ChemistryCrystalchemistry.chemical_compoundsymbols.namesakeComputational chemistrymeta-carboraneMaterials ChemistryPhysical and Theoretical Chemistryta116x-ray crystallographyTetramethylammoniummetallabis(dicarbollide)010405 organic chemistryOrganic ChemistryIntermolecular forcex-ray technology0104 chemical sciencesCrystallographydihydrogen bondschemistrysymbolsChemical stabilityvan der Waals forceHirshfeld studyJournal of Organometallic Chemistry
researchProduct

CCDC 157094: Experimental Crystal Structure Determination

2001

Related Article: M.Bujak, J.Zaleski|2000|J.Mol.Struct.|555|179|doi:10.1016/S0022-2860(00)00600-1

tetrakis(Tetramethylammonium) tetrakis(mu~4~-chloro)-bis(mu~3~-chloro)-tetrakis(mu~2~-chloro)-octadecachloro-octa-antimonate(iii)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 659301: Experimental Crystal Structure Determination

2008

Related Article: E.J.Juarez-Perez, C.Vinas, A.Gonzalez-Campo, F.Teixidor, R.Sillanpaa, R.Kivekas, R.Nunez|2008|Chem.-Eur.J.|14|4924|doi:10.1002/chem.200702013

tetramethylammonium 1-(dimethylsilyl)-33'-commo-bis(3-cobalta-12-dicarba-closo-dodecaborate)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct