Search results for "Thermal diffusivity"

Diffusivity in force-free simulations of global magnetospheres

2021

Abstract: Assuming that the numerical diffusivity triggered by violations of the force-free electrodynamics constraints is a proxy for the physical resistivity, we examine its impact on the overall dynamics of force-free aligned pulsar magnetospheres endowed with an equatorial current sheet. We assess the constraint violations as a diffusivity source. The effects of modifications on electric fields used to restore force-free conditions are not confined to the equatorial current sheet, but modify the magnetospheric dynamics on timescales shorter than the pulsar rotational period. These corrections propagate especially via a channel that was unexplored, namely, changes induced to the electric…

Thermal Diffusion and Particle Separation in Ferrocolloids

1999

Results of experiments on thermal diffusion in ferrocolloids are discussed in the paper. The Soret coefficient is evaluated from measurements of particle separation in thermodiffusion column. To interpret the separation curves measured in the presence of a magnetic field, the column theory is modified taking into account for MHD effects of free convection. It is shown that the Hartmann effect in hydrocarbon based colloids as well in ionic magnetic fluids does not influence significantly the particle separation dynamics. From unsteady separation curves positive values of the Soret coefficient of surfacted particles in tetradecane based colloids are calculated. Such direction of particle tran…

1989

Heat of crystallization significantly slows down polymer cooling and thus pressure drop increase during mould filling with thermoplastic crystalline polymers. If a correction of thermal diffusivity can account for such a cooling slow down at least as far as the effect on pressure drop is concerned, the use of nonisothermal crystallization kinetics may be avoided in the simulation of mould filling. A procedure to identify such a correction is outlined in this work. Pressure drop values during cavity filling calculated by using a corrected thermal diffusivity in the model proposed by Lord and Williams favourably compare with literature data taken with polypropylene and polyethylene resins. Be…

Ab initio study of the F centers in CaF2: Calculations of the optical absorption, diffusion and binding energies

1998

Abstract The ground electronic state of the F center in CaF 2 crystal, its optical absorption energy, the activation energy of thermal diffusion and M center dissociation to pair of F centers are calculated using the Hartree-Fock embedded molecular cluster method. Different pseudopotentials, basis sets, boundary conditions and two computer codes, EMBED96 and Gaussian94, are employed and their results compared.

Oxygen diffusivity in tumor tissue (DS-Carcinosarcoma) under temperature conditions within the range of 20?40�C

1977

The O2 diffusion constants D and K of tumor tissue (DS-Carcinosarcoma in the rat kidney) were determined at temperatures of 20, 30, 37, and 40 degrees C. The following mean values were obtained for the conditions of 37 degrees C: D = 1.75-10(-5) cm2/s and K = 1.9-10(-5) mlO2/cm-min-atm. Within the range of 20-40 degrees C, temperature variations in tumor tissue cause changes in the O2 diffusion coefficient D of 2.0-2.5%/C and in the Krogh O2 diffusion constant K of 0.5-1.5%/C. The measured O2 diffusion constants for tumor tissue correspond to values of normal tissue with similar water content. This indicates that the insufficient O2 supply in DS-Carcinosarcoma is due not to unfavorable O2 d…

Analysis of small-angle scattering patterns from a commercial Al-Li alloy by means of a model incorporating a repulsive step potential

1992

Abstract Small-angle X-ray scattering measurements are reported for a commercial Al-8·49%Li-51% Cu (atomic composition) alloy solution treated at 520°C and thermally aged for several times at several temperatures. Data have been analysed by means of a model of ellipsoidal precipitate particles previously proposed by some of us and by a modification of this model where, in the interparticle interference term, allowance is made for interactions between the precipitate particles at longer range than previously. This was achieved by the introduction, in addition to the hard-sphere interaction potential, of a potential step. Our fits indicate that the precipitate particles interact through a rep…

Determination of the porosity, permeability and diffusivity of rock in the excavation-disturbed zone around full-scale deposition holes using the -PM…

1998

Abstract Three experimental holes the size of deposition holes in a KBS-3 type repository (depth 7.5 m and diameter 1.5 m) were bored in hard granitic rock in the Research Tunnel at Olkiluoto to study, among other things, the properties of the rock in the excavation-disturbed zone. In the analysis described in this report, the porosities, effective diffusivities and permeabilities of disturbed and intact rock were determined by using two novel methods: the 14 C -polymethylmethacrylate method and the He-gas method. In addition, the structure of the rock in the excavation-disturbed zone was assessed using both scanning electron and optical microscopy.

Kinetics of particle growth and particle composition of a commercial Al-Li alloy by means of small-angle scattering

1991

Abstract Extending previous work done on a similar alloy, small-angle X-ray scattering measurements are reported for a commercial Al-Cu-Li alloy (2–68% Cu and 1–88% Li by weight). Data have been analysed by means of an ellipsoidal model of precipitate particles using a method previously proposed by some of us which, incorporating interparticle interference effects, reproduces the fuli scattering intensities of the samples studied. Particie dimensions obtained from the fit indicate that the Lifshitz-Slyozov coarsening mechanism holds for ageing at higher temperatures and longer times. The activation energy for volume diffusivity obtained is similar to that of pure binary alloys. The scatteri…

Collective and self diffusion of PS microgels in solution as observed by thermal diffusion forced Rayleigh scattering

2007

Thermal diffusion in solutions of polystyrene micro-network spheres (microgels) in toluene has been studied by the holographic scattering technique of thermal diffusion forced Rayleigh scattering (TDFRS) and by photon correlation spectroscopy (PCS). Size distributions of microgels of different crosslink ratios are obtained from TDFRS measurements on dilute solutions at very low q-values around 4000cm−1. At low concentrations a single diffusive mode is observed and the diffusion coefficient increases with concentration. It is attributed to the collective diffusion of the microgels and the solvent. At high concentrations an additional slow mode appears whose diffusion coefficient decreases wi…

Si self-diffusion in cubic B20-structured FeSi

2008

Self-diffusion of implanted 31Si in the e-phase FeSi (cubic B20-structure) has been determined in the temperature range 660–810 °C using the modified radiotracer technique. With an activation enthalpy of 2.30 eV and a pre-exponential factor of 15×10−8 m2 s−1 the silicon diffusivity was found to be slightly slower than Ge impurity diffusion in FeSi. This difference is proposed to originate from attractive elastic interactions prevailing between the slightly oversized Ge atoms and the Si sublattice vacancies. The results confirm the argument that 71Ge radioisotopes may be used to substitute the short-lived 31Si radiotracers when estimating self-diffusion in silicides.