Search results for "Thermal ionization"

Isotope shifts and hyperfine structure in the $\mathsf{ 3d ^2D_J \rightarrow 4p ^2P_J}$ transitions in calcium II

1998

The isotope shift and hyperfine structure in the three \(\) - transitions in Ca II have been studied by fast ion beam collinear laser spectroscopy for all stable Ca isotopes. The metastable 3d states were populated within the surface ionization source of a mass separator with a probability of about 0.1%. After resonant excitation to the 4p levels with diode laser light around 850 nm the uv photons from the \(\) transitions to the ground state were used for detection. Hyperfine structure parameters A and B for the odd isotope 43Ca, as evaluated from the splittings observed, agree well with theoretical predictions from relativistic many-body perturbation theory. Field shift constants \(\) and…

Intense mass-separated beams of halogens and beta-delayed neutron emission from heavy bromine isotopes

1984

Improved production yields of short-lived halogens were obtained from a ThO2 target, irradiated with 600 MeV protons, in combination with a negative surface ionization source. Mass-separated samples were studied by decay spectroscopy. Production yields of radioactive isotopes of chlorine, bromine, iodine and astatine are presented. Half-lives and relative neutron emission probabilities were measured for the heavy bromine isotopes89−92Br. Normalizing to earlier publishedPn values for89Br, the results are:89Br (4.30±0.14s,P n =13.6±0.8%),90Br (1.92±0.06s,P n =24.8±1.5%),91Br (0.53 ±0.03 s,P n =30.1 ±2.1%), and92Br (0.31 ±0.02 s,P n =34.6±2.5%). Energy spectra ofβ-delayed neutrons were measure…

Precision experiments with time-resolved Schottky mass spectrometry

2004

Abstract A large area on the mass surface of neutron-deficient nuclides (36≤Z≤85) was measured with time-resolved Schottky mass spectrometry at the FRS-ESR facilities. The masses of 114 nuclides were obtained for the first time from which 43 were determined via known decay energies. The improved mass accuracy of 30 keV allowed to study the isospin dependence of nuclear pairing, to precisely locate the one-proton dripline for odd-Z isotopes from Tb to Pa and to make crucial tests of the predictive powers of modern mass models.

Atomic beam magnetic resonance apparatus for systematic measurement of hyperfine structure anomalies (Bohr-Weisskopf effect)

1993

Abstract An atomic beam magnetic resonance (ABMR) apparatus has been constructed at Orsay, and has been installed at the CERN PS Booster ISOLDE mass separator facility for “on-line” work with radioactive isotopes in a program to measure hyperfine structure anomalies (the Bohr-Weisskopf effect) over long isotopic chains. The hfs anomalies result from the effect of the spatial distribution of the nuclear magnetization on the atomic hfs interaction. Constructional details of the system are described: emphasis is placed on the measurement of nuclear g-factors by a triple resonance, laser state selected, ABMR method. A precision better than 10−4 for gI values has been obtained in stable atomic b…

First ionization potential of the heaviest actinide lawrencium, element 103

2016

The first ionization potential (IP1 ) of element 103, lawrencium (Lr), has been successfully determined for the first time by using a newly developed method based on a surface ionization process. The measured IP 1 value is 4.9630.08 0.07 eV. This value is the smallest among those of actinide elements and is in excellent agreement with the value of 4.963(15) eV predicted by state-of-the-art relativistic calculations also performed in this work. Our results strongly support that the Lr atom has an electronic configuration of [Rn]7s 2 5f 14 7p 1 1/2 , which is influenced by strong relativistic effects. The present work provides a reliable benchmark for theoretical calculations and also opens t…

Three-photon resonance ionization of atomic Mn in a hot-cavity laser ion source using Ti:sapphire lasers

2015

Three-photon resonance ionization of atomic manganese (Mn) in a hot-cavity ion source using Ti:sapphire lasers has been demonstrated. Three-step ionization schemes employing different intermediate levels and Rydberg or autoionizing (AI) states in the final ionization step are established. Strong AI resonances were observed via the 3d54s5s f 6S5/2 level at 49 415.35 cm−1, while Rydberg transitions were reached from the 3d54s4d e 6D9/2,7/2,5/2 levels at around 47 210 cm−1. Analyses of the strong Rydberg transitions associated with the 3d54s4d e 6D7/2 lower level indicate that they belong to the dipole-allowed 4d → nf 6F°9/2,7/2,5/2 series converging to the 3d54s 7S3 ground state of Mn II. Fro…

Collisional and thermal ionization of sodium Rydberg atoms III. Experiment and theory fornS andnD states withn= 8–20 in crossed atomic beams

2005

The results of experimental and theoretical studies of collisional ionization of Na Rydberg atoms in nS and nD(n = 8–20) states are presented. Molecular and atomic ions from associative ionization and photoionization by blackbody radiation were detected after pulsed laser excitation of Rydberg states in crossed Na atomic beams. An original method of determination of associative ionization rate constants based on the measurement of ratios of molecular and atomic ion signals was used, which did not require the determination of absolute number density of Rydberg atoms. The measured rate constants of associative ionization of Rydberg atoms in collisions with ground-state Na atoms are compared w…

Response to “Comment on ‘Comparison and uncertainty evaluation of different calibration protocols and ionization chambers for low-energy surface brac…

2016

Collisional and thermal ionization of sodium Rydberg atoms: II. Theory fornS,nP andnD states withn= 5–25

2005

A stochastic model of associative ionization in collisions of Rydberg atoms with ground-state atoms is presented. The conventional Duman–Shmatov–Mihajlov–Janev (DSMJ) model treats the ionization as excitation of Rydberg electron to the continuum by the electric-dipole field generated by exchange interaction within the quasi-molecular ion. The stochastic model essentially extends this treatment by taking into account redistribution of population over a range of Rydberg states prior to ionization, which is caused by non-adiabatic processes in overlapping multiple level crossings of quasi-molecular Rydberg states. The redistribution is modelled as diffusion of electrons in the Rydberg energy s…

RADIOISOTOPE MASS SPECTROMETRY

2003

Mass spectrometric methods are very sensitive and enable in many cases a multielement determination of trace and ultratrace elements combined with a good isotopic analysis ( Bacon et al. , 2001 ). Therefore, these techniques are also applied for the detection of long-lived radionuclides ( Becker and Dietze, 2000 ) mainly in environmental samples ( Adriaens et al. , 1992 ; Bailey et al. , 1993 ; Bibler et al. , 1998 ; Eroglu et al. , 1998 ; Edmonds et al. , 1998 ; Becker and Dietze, 1999 ; Wendt et al. , 1999 ), nuclear materials ( Betti, 1997 ; Chartier et al. , 1999 ), glass and ceramics ( Rohr et al. , 1994 ; Fukuda and Sayama, 1997 ), and in high-purity substances ( Beer and Heumann, 199…