Search results for "Thermal"
showing 10 items of 3576 documents
Thermal stability of Au–TiO2 nanocomposite films prepared by direct liquid injection CVD
2015
Abstract Nanocomposite films composed of gold nanoparticles (AuNPs) embedded in a TiO 2 matrix have been prepared by direct liquid injection chemical vapor deposition process, using preformed nanoparticles and titanium isopropoxide as precursors. The spherical AuNPs about 4.1 nm in diameter were synthesized by using gold (III) chloride trihydrate and stabilized by thiol ligands. The depositions were carried out by performing at first oxide deposition, then gold nanoparticle one and capping with oxide. The morphology, structure; the chemical state and optical properties of nanocomposite films were characterized by scanning electron microscopy, Raman, X-ray photoelectron and UV–Vis absorption…
Effect of surface impurities on downconversion luminescence of Pr3+, Yb3+ activated SrF2 nanoparticles
2020
Abstract Pr3+,Yb3+ activated SrF2 nanoparticles synthesized by low-temperature hydrothermal method were studied. The composition and size of nanoparticles were intentionally changed by controlling synthesis conditions. After structural and morphological characterization, the spectroscopic properties of the nanoparticles were analyzed in the visible and near infrared spectra ranges. The results show correlation between the gradual change of the amount of carboxylate and hydroxyl moieties on the nanoparticle surface, varied by the size nanoparticles and the quenching of the luminescence. The size-related amount of surface quenchers is strongly connected to the decrease of the downconversion e…
Effects of Thermal Treatment on the Structure of Eu:YAG Nanopowder
2007
Eu:YAG nanopowder precursors were obtained by co-precipitation of aluminium, yttrium and europium nitrates solution with ammonia. The hydroxides precursors were calcined at different temperatures from 900 to 1200°C as a function of holding time (1, 2 and 6 hours). The presence of Eu3+ ions in the matrix was confirmed by Energy Dispersive X-rays analysis. X-Ray Diffraction investigation by the Rietveld method shows that the sample treated at 900°C for 1 hour is essentially the garnet phase with the minor presence of hexagonal and monoclinic metastable phases. The Eu3+ ions are incorporated into the garnet phase, as is suggested by the lattice parameter value being larger than that in literat…
Mechanical Activation as a New Method for SHS
2006
The use of mechanical activation (the elemental powder mixture is milled for a short time at given frequency and impact energy) as a precursor to self-propagating high-temperature synthesis (SHS) results in the formation of nanostructured porous materials. The mechanical activation step was found necessary (i) to modify the thermal parameters of the combustion front (i.e. combustion front velocity, thermal heating rate…) in the cases of Mo-Si, Fe-Al, Ni-Si (ii) to initiate a combustion front in the case of systems having a low exothermicity. Nevertheless, the control of the mechanically activated mixture characteristics and, the understanding of the mechanical activation role on the SHS par…
Synthesis of Titanate Nanotubes Directly Coated with USPIO in Hydrothermal Conditions: A New Detectable Nanocarrier
2011
International audience; Abstract: For the first time, titanate nanotubes (TiONts) coated with USPIO (ultrasmall superparamagnetic iron oxide) without polymer functionalization and directly obtained during TiONts formation is reported. The coating of these tubes was performed directly during the TiONts hydrothermal synthesis. After this treatment, in strongly basic conditions, USPIO particles kept their structure and magnetic properties while their size distribution slightly increased. By coupling zeta-potential measurements and TEM observations at different pH it appeared that interactions between nanotubes and USPIO were not electrostatic. This study presents the new design of a titanate n…
Nanowires: A route to efficient thermoelectric devices
2019
Miniaturization of electronic devices aims at manufacturing ever smaller products, from mesoscopic to nanoscopic sizes. This trend is challenging because the increased levels of dissipated power demands a better understanding of heat transport in small volumes. A significant amount of the consumed energy in electronics is transformed into heat and dissipated to the environment. Thermoelectric materials offer the possibility to harness dissipated energy and make devices less energy-demanding. Heat-to-electricity conversion requires materials with a strongly suppressed thermal conductivity but still high electronic conduction. Nanowires can meet nicely these two requirements because enhanced …
On the Use of L-shaped Granular Chains for the Assessment of Thermal Stress in Slender Structures
2014
Slender beams subjected to compressive load are common in civil engineering. The rapid in-situ measurement of this stress may help preventing structural anomalies. In this article, we describe the coupling mechanism between highly nonlinear solitary waves (HNSWs) propagating along an L- shaped granular system and a beam in contact with the gran- ular medium. We evaluate the use of these waves to measure stress in thermally loaded structures and to estimate the neutral temperature, i.e. the temperature at which the stress is null. We investigate numerically and experimentally one and two L- shaped chains of spherical particles in contact with a prismatic beam subjected to heat. We find that …
Detection and characterisation of disbonds on Fibre Metal Laminate hybrid composites by flying laser spot thermography
2017
Abstract In this work a novel data collection and processing is proposed for the Infrared Non-Destructive Testing (IR-NDT) of interlaminar disbonds on Fibre Metal Laminate (FML) hybrid composites. The adopted active IR-NDT scheme uses a pointwise laser heat source that is moved along a raster scanning trajectory over the object surface. A Focal Plane Array IR camera is employed to acquire the thermal field generated by the moving heat source. Disbonds defect signatures are then searched by analysing the perturbations of the temperature distribution over a reference area following the heat source. The proposed methodology has been implemented on a GLARE sample, since this class of FMLs has g…
A Numerical Study on Interlaminar Defects Characterization in Fibre Metal Laminates with Flying Laser Spot Thermography
2018
This work describes a numerical study on non-destructive evaluation of interlayer disbond defects in aerospace grade Fibre Metal Laminate sheets (FMLs). A recently proposed infrared non-destructive testing setup is considered, where a continuous laser is moved over the material surface, while the thermal footprint of the moving heat source is acquired, e.g. by an infrared thermal camera. Interlayer disbonds are then detected by analysing the features of the acquired thermograms. The experimental feasibility of this approach has been recently proved. The present work proposes a numerical simulation of the NDT approach, where the material thermal response is analysed and correlated to defects…
On the thermal-hydraulic performances of the DEMO divertor cassette body cooling circuit equipped with a liner
2020
Abstract In the framework of the Work Package DIV 1 - “Divertor Cassette Design and Integration” of the EUROfusion action, a research campaign has been jointly carried out by University of Palermo and ENEA to investigate the steady-state thermal-hydraulic performances of the DEMO divertor cassette cooling system. The research activity has been focussed onto the most recent design of the Cassette Body (CB) cooling circuit, consistent with the DEMO baseline 2017 and equipped with a liner, whose main function is to protect the underlying vacuum pump CB opening from plasma radiation. The research campaign has been carried out following a theoretical-computational approach based on the finite vo…