Search results for "Thermal"

showing 10 items of 3576 documents

Steady state and transient thermal-hydraulic characterization of full-scale ITER divertor plasma facing components

2008

Abstract In the frame of the activities related to ITER divertor R&D, ENEA CR Brasimone was in charge by EFDA (European Fusion Development Agreement) to investigate the thermal-hydraulic behaviour of the full-scale divertor plasma facing components, i.e. the outer vertical target, the inner vertical target and the dome-liner, both in steady state and during draining and drying transient. The investigation was performed by means of both experimental test campaigns performed at ENEA CR Brasimone and theoretical simulation developed in RELAP5 Mod.3.3 environment at the Department of Nuclear Engineering of the University of Palermo (DIN). This paper presents the achieved experimental results fo…

Materials scienceSteady stateITER Divertor Plasma facing components Thermal-hydraulicsMechanical EngineeringNuclear engineeringDivertorFull scalePlasmaThermal hydraulicsNuclear Energy and EngineeringFUSIONE NUCLEARE ITER DIVERTORE TERMOIDRAULICAGeneral Materials ScienceTransient (oscillation)Settore ING-IND/19 - Impianti NucleariCivil and Structural EngineeringFusion Engineering and Design
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On the theoretical–numerical study of the ITER Upper Port Plug structure hydraulic behaviour under steady state and draining and drying transient con…

2011

Abstract The ITER diagnostic Upper Port Plug (UPP) is a water-cooled stainless steel structure aimed to integrate within vacuum vessel the plasma diagnostic systems, shielding them from neutron and photon irradiation. Due to the very intense heat loads expected, a proper cooling circuit has been designed to ensure an adequate UPP cooling with an acceptable thermal rise and an unduly high pumping power and to perform its draining and drying procedure by injection of pressurized nitrogen. A theoretical research activity has been launched at the Department of Nuclear Engineering of the University of Palermo aiming to investigate the hydraulic behaviour of the UPP Trapezoid Section cooling circ…

Materials scienceSteady stateMechanical EngineeringMass flowFlow (psychology)Port (circuit theory)Mechanicslaw.inventionCoolantThermal hydraulicsNuclear Energy and EngineeringlawITER Upper Port Plug Thermal–hydraulic Draining and dryingGeneral Materials ScienceTransient (oscillation)Spark plugSettore ING-IND/19 - Impianti NucleariCivil and Structural EngineeringFusion Engineering and Design
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Strain-dependent electrical resistance of epoxy/MWCNT composite after hydrothermal aging

2015

Abstract The electrical resistance of epoxy/multi-wall carbon nanotube (MWCNT) composites was studied under the effect of hygro- and hydrothermal aging. Tensile tests were conducted and the responses in the electrical resistance were measured during the tests for samples with different prehistory of environmental exposure. The overall pattern of the electrical resistance change versus strain for the samples tested consists of linear and nonlinear regions with a broad peak that precedes the ultimate strength of the sample and occurs at the onset of evident plastic deformation in the stress–strain curve. The composite with lower content of MWCNTs exhibits a more pronounced nonlinear behavior …

Materials scienceStrain (chemistry)Composite numberGeneral EngineeringEpoxyEnvironmental exposureHydrothermal circulationElectrical resistance and conductancevisual_artUltimate tensile strengthCeramics and Compositesvisual_art.visual_art_mediumComposite materialElectrical conductorComposites Science and Technology
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Thermodiffusion of sodium polystyrene sulfonate in a supporting electrolyte

2019

Thermodiffusion, or the Soret phenomenon, is well understood in simple systems, but in multicomponent and polyvalent electrolyte systems the process becomes more complicated due to the coupling of fluxes. We experimentally investigate the time evolution of a concentration gradient generated by thermodiffusion of a polyelectrolyte (poly(sodium 4-styrene sulfonate), NaPSS) in a 1:1 supporting electrolyte. We also derive and solve the transport equations that are used to extract the Soret coefficient from the experimental observations. It is shown that NaPSS thermodiffusion in NaCl is strongly dependent on concentration, with almost 100% thermal separation in concentrations below 15 nmol L−1. …

Materials scienceSupporting electrolyteGeneral Chemical EngineeringSodiumThermodynamicschemistry.chemical_elementNon-isothermal processSoret effect02 engineering and technologyElectrolyteThermodiffusion010402 general chemistry01 natural scienceschemistry.chemical_compoundFlux (metallurgy)Electrochemistryta116Time evolutionPolyelectrolyte021001 nanoscience & nanotechnologyPolyelectrolyte0104 chemical sciencesSulfonatechemistry0210 nano-technologySodium Polystyrene SulfonateElectrochimica Acta
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Low temperature synthesis of monodisperse nanoscaled ZrO2with a large specific surface area

2012

Thermal decomposition of Zr(C(2)O(4))(2)·4H(2)O within an autoclave or in a conventional tube furnace at temperatures below 380 °C resulted in nano- and micron-sized ZrO(2), respectively. Reactions under autogenic pressure yielded monodisperse monoclinic (m) and tetragonal (t) ZrO(2) nanoparticles with an average diameter of ~8 nm and interconnected t-ZrO(2) nanoparticles with diameters of ~4 nm, depending on the synthesis temperature. Samples were characterised by X-ray diffraction (XRD), small angle X-ray scattering (SAXS), scanning electron microscopy (SEM), transmission electron microscopy (TEM) associated with energy dispersive X-ray spectroscopy (EDS), Raman microspectroscopy and phot…

Materials scienceSurface PropertiesScanning electron microscopeSmall-angle X-ray scatteringSpectrum AnalysisThermal decompositionTemperatureNanoparticleNanotechnologyChemistry Techniques SyntheticNanostructuresInorganic ChemistryChemical engineeringTransmission electron microscopySpecific surface areaThermogravimetryZirconiumParticle sizeMonoclinic crystal systemDalton Trans.
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Morphological Control of Hydrothermal Ni(OH)2 in the Presence of Polymers and Surfactants: Nanocrystals, Mesocrystals, and Superstructures

2008

International audience; Polymers with different hydrophilic groups [polyvinylpyrrolidone (PVP), ammonium polyacrylate (APA), and hydroxypropylmethyl cellulose (HPMC)] and surfactants [cetyltrimethylammonium bromide (CTAB) and sodium dodecylbenzensulfonate (SDBS)] were used as additives to modify the crystallization of β-Ni(OH)2 in hydrothermal conditions. Marked morphological changes in the β-Ni(OH)2 particles were observed depending on the additive concentration and on the duration of the hydrothermal treatment. The final morphology is the result of a complex, time-dependent self-assembly and growth process. Well-defined particles with sizes from submicrometer range to a few micrometers co…

Materials scienceSurfactantsNanotechnologyPrecipitation02 engineering and technology010402 general chemistry01 natural sciencesHydrothermal circulationlaw.inventionlawmedicineHydrothermal synthesisGeneral Materials ScienceCrystallizationMesocrystalschemistry.chemical_classificationAcicularPolyvinylpyrrolidoneGeneral ChemistryPolymer021001 nanoscience & nanotechnologyCondensed Matter Physics0104 chemical sciencesChemical engineeringchemistry[PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci]Self-assemblyParticle sizeParticle morphology0210 nano-technologymedicine.drugCrystal Growth & Design
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Room temperature vacuum-deposition of CsPbI2Br perovskite films from multiple-sources and mixed halide precursors

2020

Fully inorganic cesium lead halide perovskites, such as CsPbI2Br, show enhanced thermal stability compared to hybrid ones and are being widely investigated as wide bandgap absorbers for tandem applications. Despite their simple stoichiometry, the preparation of highly crystalline and stable cesium lead halide thin films is not trivial. In general, high-efficiency solar cells based on solution-processed CsPbI2Br thin films are prepared by hightemperature annealing or the use of chemical additives. In this work, we use solvent-free synthesis to investigate the formation of CsPbI2Br in bulk or in thin films via mechanochemical synthesis and multiple-source vacuum deposition, respectively. We d…

Materials scienceTandemBand gapGeneral Chemical EngineeringHalidechemistry.chemical_element02 engineering and technologyGeneral Chemistry010402 general chemistry021001 nanoscience & nanotechnology7. Clean energy01 natural sciences0104 chemical sciencesVacuum depositionChemical engineeringchemistryCaesiumMaterials ChemistryThermal stability0210 nano-technologyMaterialsCèl·lules fotoelèctriquesPerovskite (structure)Chemistry of Materials
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Highly Efficient Thermally Co-evaporated Perovskite Solar Cells and Mini-modules

2020

The rapid improvement in the power conversion efficiency (PCE) of perovskite solar cells (PSCs) has prompted interest in bringing the technology toward commercialization. Capitalizing on existing industrial processes facilitates the transition from laboratory to production lines. In this work, we prove the scalability of thermally co-evaporated MAPbI3 layers in PSCs and mini-modules. With a combined strategy of active layer engineering, interfacial optimization, surface treatments, and light management, we demonstrate PSCs (0.16 cm2 active area) and mini-modules (21 cm2 active area) achieving record PCEs of 20.28% and 18.13%, respectively. Un-encapsulated PSCs retained ∼90% of their initial…

Materials scienceTandembusiness.industryEnergy conversion efficiencyPhotovoltaic system02 engineering and technology010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesThermal Evaporation0104 chemical sciencesActive layerGeneral Energy:Physics [Science]PhotovoltaicsLight managementOptoelectronicsEnergiaPerovskite Solar Cells0210 nano-technologybusinessCèl·lules fotoelèctriques
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FORMATION OF FRACTAL MICRO- AND NANO-STRUCTURES IN CERAMIC TANTALUM PENTOXIDE UNDER CONCENTRATED FLUX OF LIGHT AND THEIR EFFECT ON THERMAL EXPANSION

2009

ABSTRACT Oxides of weak thermal expansion are the basis for stable ceramics and artefacts resistant to sharp cyclic variations of temperature. For technical applications is a wide interest in high-temperature materials of low or negative thermal expansion and, particularly, in studies of the micromechanisms in Ta2O5. Thermal expansion of ceramic pentoxides of tantalum is affected by conditions under which they are formed. After treatment by concentrated light flows anomalous segments of zero and even negative thermal expansion appear in ceramics of Ta2O5. The effect of treatment by concentrated light flux on formation of fractal nano-structures and thermal expansion of ceramic tantalum pent…

Materials scienceTantalumchemistry.chemical_elementCondensed Matter PhysicsThermal expansionElectronic Optical and Magnetic MaterialsCondensed Matter::Materials Sciencechemistry.chemical_compoundFlux (metallurgy)FractalchemistryNegative thermal expansionControl and Systems Engineeringvisual_artNano-Tantalum pentoxideMaterials ChemistryCeramics and Compositesvisual_art.visual_art_mediumCeramicElectrical and Electronic EngineeringComposite materialIntegrated Ferroelectrics
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Unstable behaviour of normally-off GaN E-HEMT under short-circuit

2018

The short-circuit capability of power switching devices plays an important role in fault detection and the protection of power circuits. In this work, an experimental study on the short-circuit (SC) capability of commercial 600 V Gallium Nitride enhancement-mode high-electron-mobility transistors (E-HEMT) is presented. A different failure mechanism has been identified for commercial p-doped GaN gate (p-GaN) HEMT and metal-insulator-semiconductor (MIS) HEMT. In addition to the well known thermal breakdown, a premature breakdown is shown on both GaN HEMTs, triggered by hot electron trapping at the surface, which demonstrates that current commercial GaN HEMTs has requirements for improving the…

Materials scienceThermal breakdownGallium nitrideFailure mechanism02 engineering and technologyHigh-electron-mobility transistor01 natural sciencesFault detection and isolationlaw.inventionchemistry.chemical_compoundlaw0103 physical sciencesMaterials ChemistryElectrical and Electronic Engineering010302 applied physicsbusiness.industryTransistorNormally off021001 nanoscience & nanotechnologyCondensed Matter PhysicsElectronic Optical and Magnetic MaterialschemistryOptoelectronics0210 nano-technologybusinessShort circuitSemiconductor Science and Technology
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