Search results for "Thermal"
showing 10 items of 3576 documents
Series expansion for the effective conductivity of a periodic dilute composite with thermal resistance at the two-phase interface
2019
We study the asymptotic behavior of the effective thermal conductivity of a periodic two-phase dilute composite obtained by introducing into an infinite homogeneous matrix a periodic set of inclusions of a different material, each of them of size proportional to a positive parameter ?. We assume that the normal component of the heat flux is continuous at the two-phase interface, while we impose that the temperature field displays a jump proportional to the normal heat flux. For ? small, we prove that the effective conductivity can be represented as a convergent power series in ? and we determine the coefficients in terms of the solutions of explicit systems of integral equations.
Structural Stability of Hafnia-Based Materials at Ultra-High Temperature
2018
This study assesses the structural stability at ultra-high temperature of the following selected compositions: 6.5 and 14 mol. % of RE2O3 (RE = Dy, Y, Er, Yb, and Lu) doped HfO2. Under thermal cycling and thermal shock, the structural stability was evaluated at 2400°C with water vapor flux using a specific test bench with a 3 kW CO2 laser. The cubic phase stability, which is theoretically important in the broad temperature range from 25 to 2800°C, was determined by a quantitative analysis of the X-ray diffractograms. Fully and partially stabilized HfO2, obtained respectively with 14 mol. % and 6.5 mol. % of dopants, showed different behaviors to thermal damage. Thermal expansion was measure…
Kinetic Parameters for Thermal Degradation of Green Asparagus Texture by Unsteady-state Method
1998
An unsteady-state method was developed for estimating texture degradation during heating-cooling of green asparagus spears. The method used a mathematical model of heat transmission for time-temperature history estimation, and a nonlinear regression of texture measurements of asparagus spears to estimate kinetic parameters. The specific heat, conductivity and convective coefficient of green asparagus were determined experimentally and used In the mathematical model for temperature estimation. Values obtained were Ea = 76.19±0.13 kJ/mol and k 1158°C = 0.00528±0.00005 s -1 . Good agreement was found between predicted and observed texture values. The method was compared with the classical stea…
Wall assemblies U-value calculation in test buildings using constant power heating
2018
Abstract Building envelopes under various climates behave differently, in this paper the actual thermal transmittance or U-value of five different wall assemblies are evaluated and compared with values, calculated using standard EN ISO 6946. The experiment is carried out in five test buildings with equal spatial orientation, the same ceiling and floor assemblies as well as the same windows and doors mounted in each building. The thermal transmittances for these partitions are assumed to be well known and therefore, by knowing temperature difference and heat sources inside the building, the thermal transmittance of wall assembly can be calculated. It is shown that for small buildings the cor…
From Wood and Hemp Biomass Wastes to Sustainable Nanocellulose Foams
2021
Abstract Transition to the circular economy requires the implementation of recycling and reuse routes for waste products. This research addresses one of the leading emerging areas, i.e., the development of sustainable materials and natural waste processing, namely wood and hemp byproducts. The cellulosic nanomaterials derived from these under-utilized waste residues and byproducts also serve as promising natural precursors for advanced applications, e.g., biomedical, pollution filtering, and thermal insulation. The wood and hemp fibrils were prepared by microfluidic processing of 0.2 – 1.0 wt% cellulose water suspensions. After freeze-drying, the resulting foam materials were characterized …
<title>Photo-induced structural changes in near-surface layers of chalcogenide semiconductors</title>
1997
Photoinduced structural changes in near-surface layers of amorphous As-Se and As-S films have been investigated using the microhardness method. Microhardness via indentation depth data for as-deposited, illuminated and aged in ambient atmosphere films is presented. The results obtained show that photoinduced increase in microhardness of surface layers up to approximately 1 - 1.5 micrometer are more pronounced in comparison with deeper layers. Increase in microhardness of the investigated films under exposure to atmosphere was also observed. Atmosphere-induced effect was more pronounced in the case of As-S films. Photo- and atmosphere-induced effects in the near-surface layers were found to …
Using crystallographic shear to reduce lattice thermal conductivity: high temperature thermoelectric characterization of the spark plasma sintered Ma…
2013
Engineering of nanoscale structures is a requisite for controlling the electrical and thermal transport in solids, in particular for thermoelectric applications that require a conflicting combination of low thermal conductivity and low electrical resistivity. We report the thermoelectric properties of spark plasma sintered Magnéli phases WO2.90 and WO2.722. The crystallographic shear planes, which are a typical feature of the crystal structures of Magnéli-type metal oxides, lead to a remarkably low thermal conductivity for WO2.90. The figures of merit (ZT = 0.13 at 1100 K for WO2.90 and 0.07 at 1100 K for WO2.722) are relatively high for tungsten-oxygen compounds and metal oxides in general…
Improving the Long‐Term Stability of Doped Spiro‐Type Hole‐Transporting Materials in Planar Perovskite Solar Cells
2021
The improvement of the long-term stability of perovskite-based solar cells (PSCs) toward commercialization is closely linked to the development of cutting-edge charge-transporting materials. The progress on the design and the synthesis of new hole-transporting materials (HTMs) is synergistically attaining both top efficiencies and promising stability. Herein, the synthesis and characterization of two doped-HTMs based on electron-rich spiranic cores, namely, 9H-quinolinophenoxazine (spiro-POZ) and 9H-quinolinophenothiazine (spiro-PTZ), are presented. The novel HTMs exhibit excellent solubility, optimal highest occupied molecular orbital energy, and excellent thermal stability with glass tran…
Thermal expansion, normalized thermo-optic coefficients, and condition for second harmonic generation of a Nd:YAG laser with wide temperature bandwid…
2011
Interferometric determination of thermal expansion and of normalized thermo-optic coefficients of RbTiOPO4 at four laser wavelengths are performed as a function of temperature. A suitable vectorial formalism applied to obtained data allows the establishment of the temperature dependence of refractive indices, and subsequent theoretical analysis enables one to predict that an extremum in the evolution of the phase-matching direction in the (X,Y) plane should occur near 100 °C for type II second harmonic generation of Nd:YAG lasers, with a temperature bandwidth that can be as large as 117 °C for a crystal of 10 mm in length. Such unusual behavior is observed experimentally by recording the co…
Numerical Procedure For Residual Stresses Prediction In Friction Stir Welding
2011
The prediction of residual stresses is a relevant and, under many points of view, still open issue for a proper welding process design. In the present paper a 3D FE model, with general validity for different joint configurations, was used to simulate the Friction Stir Welding (FSW) process of butt joints through a single block approach. The model is able to predict the residual stresses by considering thermal actions only, thanks to a new time efficient approach. A good agreement between calculated and experimentally measured data was found; the effectiveness of the presented numerical procedure was evaluated by comparing the calculation times of the proposed method with the ones of already…