Search results for "Thermal"
showing 10 items of 3576 documents
Syntheses, structures and physical characterization of two new three-dimensional mixed-valence hexadecavanadate derivatives
2007
Abstract Two new hexadecavanadate derivatives, (bpy)[Zn(4,4′-bpy)2]2[H4ClV16O38]·6H2O 1 and (bpy)[Co(4,4′-bpy)2]2[H4ClV16O38]·6H2O 2 (bpy = 4,4′-bipyridine), were synthesized under the hydrothermal conditions and structurally characterized by IR, XPS and EPR spectroscopy, redox titration and single-crystal X-ray diffraction. The two compounds are isostructural and crystallize in the tetragonal non-centrosymmetric space group P-4n2 (No. 118) with a = 17.124(2), b = 17.124(2), c = 14.724(3) A, V = 4317.5(12) A3 and Z = 1 for the compound 1, and a = 17.038(2), b = 17.038(2), c = 14.754(3) A, V = 4282.9(12) A3 and Z = 1 for the compound 2. Compounds 1 and 2 were constructed from 4-connected {H4…
Photomagnetic effect in a cyanide-bridged mixed-valence {FeII2FeIII2} molecular square
2012
The self-assembly of [Fe(III)(Tp)(CN)(3)](-) and [Fe(II)(bik)(2)(S)(2)](2+) affords the cyanide-bridged mixed valence {Fe(III)(2)Fe(II)(2)}(2+) molecular square, which exhibits a photomagnetic effect under laser light irradiation at low temperature and also shows thermal spin-state conversion near ambient temperature.
Intermediate valencies of vanadium cations appearing during oxidation of vanadium–iron spinels
2000
Abstract The oxidation state of vanadium cations in nanosized vanadium–iron spinels at stoichiometry and at oxidative nonstoichiometry has been investigated by associating X-ray diffraction, thermal analysis (DSC), infrared and X-ray photoelectron spectroscopies. It has been established that, during oxidation, the V3+ cations present several intermediate valencies before to realize the final oxidation state +5. A comparison was made with the oxidation of V2O3.
Climatic change and thermal comfort. Effects on the tourism industry in the region of Valencia
2020
El cambio climático comienza a manifestar efectos en las actividades económicas de la Comunidad Valenciana. El turismo es una parte fundamental de su economía, puesto que representa el 15% de su PIB regional. La modalidad de “sol y playa” es la principal actividad turística en el territorio valenciano, de ahí la importancia del análisis de las alteraciones que están experimentando los elementos climáticos debido a su efecto en el recurso turístico y en las preferencias de la demanda. La pérdida del “confort climático”, el aumento de las noches “tropicales” (Tª > 20ºC), el incremento de la temperatura del agua de mar Mediterráneo y la adaptación a los extremos atmosféricos (olas de calor, ll…
Comparing indoor performances of a building equipped with four different roof configurations in 65 Italian sites
2020
Abstract—Despite the increasing concern of institutions and technical organizations toward the improvement of the building energy (and, therefore, environmental) efficiency, the main goal of technicians should be also devoted toward the levels of internal thermal comfort that buildings are able to realize. As that, the relationships between energy performances and comfort conditions provided by the enclosures are of paramount importance in guiding designers in their work. In this paper, the influence of diverse roof construction typologies on energy and indoor performance of buildings has been investigated, in different Italian sites during heating and cooling seasons. In addition, it must …
Gas–solid chromatographic separation of hydrogen isotopes: a comparison between two palladium bearing materials – alumina and kieselguhr
1998
The separation of hydrogen isotopes (H, D, T) is performed by displacement gas chromatography on palladium. A large isotopic effect is associated with the reversible adsorption of hydrogen by palladium. Two Pd support materials have been compared: alpha-alumina and kieselguhr. The study includes a physicochemical characterization and a set of functional tests. The Van Deemter model gives a fairly good analysis of the process but to get more information, thermoregulated separations are needed. For both supports, palladium is impregnated as small dispersed particles in the 0.1 to 0.3 μm range diameter. For the same palladium loading, alumina is more efficient than kieselguhr.
(Vapour + liquid) equilibria of (water + dimethylformamide): application of the headspace-gas chromatography for the determination of thermodynamic i…
1998
Abstract Isothermal measurements of the partial vapour pressures have been carried out on {water + dimethylformamide (DMF)} at temperatures betweenT=305.15 K andT=323.15 K using an apparatus composed of a headspace sampler and a normal gas chromatograph. These data were simultaneously evaluated in one step with respect to the (composition dependent, integral) Flory-Huggins interaction parametergby means of a new method which minimizes the Gibbs energy of mixing and does not require chemical potentials. The expression forggiven by Koningsveld and Kleintjens, originally designed for polymer solutions, describes the present results best.
Control Strategy for Induction Motor Drives Based on Decoupling Techniques
1989
Abstract In this work a new closed loop, synchronous microprocessor-based controller is proposed for field oriented controlled induction motor drives, using a PWM voltage source inverter. This controller is based on a non linear state feedback compensator which gives decoupling of both rotor current and rotor flux, and direct and inquadrature components of the stator current vector. The compensator has a linearizing effect on the synchronous model of the electromagnetic circuit of the motor. It follows that the control laws can be obtained using optimal control techniques for linear systems. The controller in question gives directly the conduction sequences of the inverter supplying the ind…
The vegetation for mitigating the microclimate and designing livable and healthy public spaces in Palermo City Centre
2018
Urban morphology and increasing building density play a key role in the overall heat and energy balance of our cities. The urban environment and CO2 emissions resulting from human activities cause a local increase of temperature, a phenomenon known as Urban Heat Island (UHI). This is also due to the reduction of vegetation in urban areas. The benefits that green spaces have in urban planning have been widely acknowledged. In particular, in temperate and hot contexts, plants help to reduce the extreme summer temperatures, improving people’s outdoor and indoor thermal comfort and, at the same time, reducing the buildings’ energy demand for cooling. The way plants affect urban climates is gene…
Natural ventilative cooling in school buildings in Sicily
2016
The paper shows analysis of the impact on thermal comfort of natural ventilation in a nonresidential Mediterranean case-study. Results are based on the EN 15251 approach on adaptive comfort. Different scenarios are proposed, granting an improvement of up to 10% in the number of summer comfort hours.