Search results for "Thermal"
showing 10 items of 3576 documents
Photoinduced Modifications of the Structure and Microhardness of Fullerite C60
2004
The wavelength dependence, temperature limits, time and depth evolution of the photoinduced hardening of C60 crystals in air have been investigated by microindentation and dislocation mobility methods. Two photopolymerized phases, which differ in the hardness and thermal stability, are found to appear. We suggest that formation of fullerene dimers (ie. C120) in pristine fullerite and growth of C120O phase in oxygenated fullerite via [2+2] photoaddition reaction is responsible for it. It has been found from depth distribution data of the hardness that the C120O phase is located in oxygen-contaminated subsurface layer of 0.8–1 μm and appears under illumination at 290–330 K.
<title>Luminescence of intrinsic defects in LiBaF<formula><inf><roman>3</roman></inf></formula></title&g…
2003
A wide emission band in the region of 425 nm is observed in all the examined crystals at photo and ionising irradiation. Maximum of the complex luminescence band is observed at 410 nm at 350 K and at 450 nm at 85 K. The shift of the peak of the band envelope towards shorter wavelengths as the temperature increases is related to thermal dependence of the intensity of elementary components of the luminescence band. The authors suggest that the complex luminescence band arises from electronic excitations at "antisite" defects, i.e., defects caused by stoichiometric deviations, when a portion of Li+ cations (cations of one type of the LiBaF3 crystal lattice) occupy sites of Ba2+ cations (cation…
Comparison of field emissivities with laboratory measurements and ASTER data
2008
Surface emissivity in the thermal infrared (TIR) region is an important parameter for determining the land surface temperature from remote sensing measurements. This work compares the emissivities measured by different field methods (the Box method and the Temperature and Emissivity Separation, TES, algorithm) as well as emissivity data from ASTER scenes and the spectra obtained from the ASTER Spectral Library. The study was performed with a field radiometer having TIR bands with central wavelengths at 11.3 μm, 10.6 μm, 9.1 μm, 8.7 μm and 8.4 μm, similar to the ASTER TIR bands. The measurements were made at two sites in southern New Mexico. The first was in the White Sands National Monument…
Slow pyrolysis of an LDPE/PP mixture: Kinetics and process performance
2021
Abstract High- and low-density polyethylene (HDPE and LDPE) and polypropylene (PP) are the most common polymers among plastic waste as they have multiple commercial applications. This study focused on thermal degradation characteristics and kinetic of a plastic mixture with a composition of 92.5 wt% LDPE and 7.5% PP. Thermal decomposition characteristics of the plastic mixture was analysed through thermo-gravimetric analysis (TGA). The overall kinetic of the process was studied using the modified Coats−Redfern method and the Ozawa-Flynn-Wall (OFW) method. The apparent activation energy (E) and pre-exponential factor (A) obtained were 316.0 kJ/mol; 8.09E+21 min−1 and 311.5 kJ/mol; 4.35E+21 m…
Optimization of conducting structures by using the homogenization method
2002
Approximation and numerical realization of a class of optimization problems with control variables represented by coefficients of linear elliptic state equations is considered. Convergence analysis of well-posed problems is performed by using one- and two-level approximation strategies. The latter is utilized in an optimization layout problem for two conductive constituents, for which the necessary steps to transfer the well-posed problem into a computational form are described and some numerical experiments are given.
Recurrent daily rainfall patterns over South Africa and associated dynamics during the core of the austral summer
2010
This paper investigates the influence of some modes of climate variability on the spatio-temporal rainfall variability over South Africa during the core of the rainy season, December to February (DJF). All analyses are based directly on the rainfall field instead of atmospheric processes and dynamics. An original agglomerative hierarchical clustering approach is used to classify daily rainfall patterns recorded at 5352 stations from DJF 1971 to DJF 1999. Five clusters are retained for analysis. Amongst them, one cluster looks most like the rainfall and circulation mean picture. Another one, representing 37% of the days, describes strong negative rainfall anomalies over South Africa resultin…
Interactions between aroma compounds and beta-lactoglobulin in the heat-induced molten globule state
2010
; he present study aims to elucidate the binding of small hydrophobic ligands onto the molten globule state of β-lactoglobulin (BLG). The conversion of the native BLG into a molten globule state was induced by heat treatment at acidic pH. The molten globule state was evidenced by far and near-UV circular dichroism spectra. β-Ionone and guaiacol exhibited a higher binding ability to BLG in the heat-induced molten globule state compared to unheated BLG, as assessed by protein surface hydrophobicity measurements, using 6-propionyl-2-(dimethylamino)naphthalene (PRODAN) fluorescent probe. The binding sites of the two aroma compounds were determined by 2D nuclear magnetic resonance (NMR) spectro…
Helios and Aeolus
2012
In summer it’s always hot in the Big Apple, but the summer of 2003 had been especially sweltering. Temperatures had been around 35oC during all the month, with humidity approaching one hundred percent. The higher the temperature, the lower the New Yorkers’ thermostats, up to the point where you needed a sweater at the office, while outside delivery men, mail carriers and peddlers had to suffer the heat, together with the tourists brave enough to venture through the smoldering avenues.
Optimizing the generation system in a microgrid with power, thermal energy and mobility demands
2021
Microgrids are widely known to be the future of generation and distribution systems. This paper presents a method to optimize the size of the main components in a microgrid to supply the demands for electricity, heating and hydrogen for mobility through an Energy Hub model. The electricity production from a wind turbine, a CHP and a fuel cell satisfies the local electricity demand. The green hydrogen produced in the hub from renewable power in off-peak hours is used to feed the fuel cell or to meet the mobility demand. The heating power from CHP and fuel cell is used to feed the local district heating network.
Modelling of thermal stresses in bearing steel structure generated by electrical current impulses
2018
This work is the study of one particular candidate for white etching crack (WEC) initiation mechanism in wind turbine gearbox bearings: discharge current impulses flowing through bearing steel with associated thermal stresses and material fatigue. Using data/results from previously published works, the authors develop a series of models that are utilized to simulate these processes under various conditions/local microstructure configurations, as well as to verify the results of the previous numerical studies. Presented models show that the resulting stresses are several orders of magnitude below the fatigue limit/yield strength for the parameters used herein. Results and analysis of models …