Search results for "Thermodynamics"

Theoretical study on hydrogen storage capacity of expanded h-BN systems

2017

In this work, the hydrogen storage capacity of the expanded hexagonal Boron Nitride (eh-BN) systems has been presented. We have employed a new equation of state (EOS) for hydrogen gas to figure out the hydrogen density distribution profiles in the eh-BN systems. In this regard, the environmental conditions (i.e., temperature and pressure) are considered in the prediction procedure using DFT single point calculations. The eh-BN systems with different layer spacings are studied by PBE method with consideration of the long range dispersion corrections. On account of the in-plane polar bonds, a series of adsorption positions are considered. Additionally, the adsorption energy and hydrogen densi…

ECT of ethanol and hexane mixtures in the spinning disk system

2007

The paper presents the research results of electrostatic charging tendency (ECT) of ethanol and hexane mixtures, a liquid of a simple chemical structure and high purity (pro analysis). The research work was carried out in a spinning disk system, where the factors influencing the value of the electrification current registered were the composition of the mixture and the rotational speed of the disk. The research results showed that the biggest ECT changes occur in the range of up to 10% of ethanol content in hexane and the electrification current characteristic has a visible maximum for the mixture, the contents of which constitute 95% of hexane volume and 5% of ethanol by volume. In the nex…

Protection concepts from optical radiation used in places of danger from explosion of gases, vapour or cloud of particles

2005

Use of optical systems in hazardous locations can result in ignition of surrounding explosive atmosphere. The conducted research work allowed to propose three protection concepts. The primary protection concept - inherently safe optical radiation - consists in use of optical radiation with power, energy or irradiance incapable of causing ignition of surrounding explosive atmosphere. However, the arbitrary determination of values of these parameters is considered as excessively rigorous. The work presents the proposed protection concepts in relation to zone classification. The author describes his own method to determine safe values based on probability mathematics that can be used not only …

2017

The volume of ordinary materials decreases in response to a pressure increase exerted by a surrounding gas or liquid, i.e., the material volume compressibility is positive. Recently, poroelastic metamaterial architectures have been suggested theoretically that allow for an unusual negative effective static volume compressibility—which appears to be forbidden for reasons of energy conservation at first sight. The challenge in the three-dimensional (3D) fabrication of these blueprints lies in the necessary many hollow 3D crosses sealed by thin membranes, which we realize in this work by using 3D laser microlithography combined with a serendipitous mechanism. By using optical-microscopy cross-…

Investigation on Metal–Oxide Graphene Field-Effect Transistors With Clamped Geometries

2019

In this work, we report on the design, fabrication and characterization of Metal-Oxide Graphene Field-effect Transistors (MOGFETs) exploiting novel clamped gate geometries aimed at enhancing the device transconductance. The fabricated devices employ clamped metal contacts also for source and drain, as well as an optimized graphene meandered pattern for source contacting, in order to reduce parasitic resistance. Our experimental results demonstrate that MOGFETs with the proposed structure show improved high frequency performance, in terms of maximum available gain and transition frequency values, as a consequence of the higher equivalent transconductance obtained.

Interfacial Modification for High-Efficiency Vapor-Phase-Deposited Perovskite Solar Cells Based on a Metal Oxide Buffer Layer.

2018

Vacuum deposition is one of the most technologically relevant techniques for the fabrication of perovskite solar cells. The most efficient vacuum-based devices rely on doped organic contacts, compromising the long-term stability of the system. Here, we introduce an inorganic electron-transporting material to obtain power conversion efficiencies matching the best performing vacuum-deposited devices, with open-circuit potential close to the thermodynamic limit. We analyze the leakage current reduction and the interfacial recombination improvement upon use of a thin (<10 nm) interlayer of C60, as well as a more favorable band alignment after a bias/ultraviolet light activation process. This wo…

Kinetics of zinc anodic dissolution from the EIS characteristic points

2003

A possible faradaic impedance function for the complex mechanism of metals electrodissolution across two consecutive electrotransferences has been developed in this work. The analysis of this function provides some characteristics points from which it is possible to calculate kinetic parameters of these processes. The dependence of these parameters on the potential has been studied in the case of Zn. These ones have been interpreted in terms of changes in the controlling stages of the overall rate of reaction. Keywords: EIS simulation, Zinc anodic dissolution, Kinetic constants and electron transfer

Magnetorheology for suspensions of solid particles dispersed in ferrofluids

2006

In this work, the magnetorheological properties of suspensions of micron-sized iron particles dispersed in magnetite ferrofluids were studied. With this aim, the flow properties of the suspensions in the steady-state regime were investigated using a commercial magnetorheometer with a parallel-plate measuring cell. The effect of both magnetite and iron concentration on the magnitude of the yield stress was studied for a broad range of magnetic fields. In addition, the experimental values of the yield stress were compared with the predictions from the chain model. With this purpose the values of the yield stress were obtained by means of finite element calculations. Interestingly, it was foun…

R-Curve Modelling of Mode I Delamination in Multidirectional Carbon/Epoxy Composite Laminates

2014

In the present work, the mode I delamination behaviour of a quasi-isotropic quasi-homogeneous carbon/epoxy composite laminate with adjacent plies of 0o//45o is studied numerically. To describe the R-curve behaviour observed during crack propagation, a linear-exponential traction-separation law is proposed, where the fracture toughness and the increment in the fracture energy could be considered separately in the model. This model is then implemented in the finite element simulation of the delamination process in the composite laminate. Numerical results indicate that with the incorporation of the fibre bridging effect leads to a well-predicted force-displacement response of the composite la…

Simplified Modeling of Radiant Fields in Heterogeneous Photoreactors. 2. Limiting “Two-Flux” Model for the Case of Reflectance Greater Than Zero

1997

In the first part of this work a simple model for the description of the radiant field in heterogeneous photoreactors was developed, based on the assumption of zero reflectance of the particles. In this second part of the investigation a limiting model is developed in which the above hypothesis is removed. In this last model, scattering phenomena are dealt with in a very simple “two-flux” way, so that analytical solutions are obtained again. The case here developed is the same as in part 1, namely slab geometry with orthogonal parallel irradiation, giving special reference to the important case of semi-infinite reactor thickness. Both cases of solid catalysts with single particle size and w…