Search results for "Thermodynamics"
showing 10 items of 2774 documents
Determination of the apparent activation energy of dielectric relaxation phenomena by means of the representation of ε” as a function of T at constan…
1984
Abstract The main purpose of this work is to justify the use of the positions of the maxima of e” versus T curves when calculating the apparent activation energy in secondary dielectric relaxations or in the relaxation associated with the glass transition. To exemplify this, phenomenological models as well as experimental results for methacrylic polymers are discussed.
Linear versus Three-Arm Star Polybutadiene: Effects of Polymer Architecture on the Thermodynamic Solution Behavior
2012
The interaction of linear and of three-arm star polybutadiene (PB) with THF was studied in the temperature range between 25 and 55 °C. Information for dilute solution rests on light scattering experiments; Flory–Huggins interaction parameter χ stem from vapor pressure measurements as a function of φ, the volume fraction of polymer. Despite the minute divergence in the architecture, the second osmotic virial coefficients of the two PBs differ noticeably. The present work demonstrates that these disparities become much more pronounced as φ increases and that they depend strongly on temperature. These findings are interpreted on the basis of an approach accounting for the effects of chain conn…
Experimental and numerical study of composite T-joints for marine application
2010
Abstract The aim of this work was to study the behaviour of composite T-joints used in marine applications. The effect of several parameters was investigated. In particular, three configurations were studied; i.e. with adhesive and with two different over-laminations. Moreover, the joined sections were made of different materials. These joints were subjected to a tensile load in the plane of the sheet. To quantify the effect of different designs on the strength, a variance analysis was performed. Finally, a numerical model was developed using a commercial finite element code (Ansys).
A Promising New Method to Estimate Drug-Polymer Solubility at Room Temperature
2016
The established methods to predict drug-polymer solubility at room temperature either rely on extrapolation over a long temperature range or are limited by the availability of a liquid analogue of the polymer. To overcome these issues, this work investigated a new methodology where the drug-polymer solubility is estimated from the solubility of the drug in a solution of the polymer at room temperature using the shake-flask method. Thus, the new polymer in solution method does not rely on temperature extrapolations and only requires the polymer and a solvent, in which the polymer is soluble, that does not affect the molecular structure of the drug and polymer relative to that in the solid st…
Investigations on the linear friction welding process through numerical simulations and experiments
2012
Abstract Linear Friction Welding (LFW) is a solid-state joining process applied to non-axisymmetric components. LFW involves joining of materials through the relative motion of two components undergoing an axial force. In such process the heat source is given by the frictional forces work decaying into heat determining a local softening of the material and eventually bonding conditions. In the paper the authors present a designed and assembled laboratory fixture for LFW operations and the results of an experimental and numerical campaign aimed to weld steel parts. The dedicated fixture permitted to highlight the effect of the most important process parameters. Process conditions allowing ef…
Friction Based Solid State Welding Processes
2012
In the last decade the industrial use of solid state welding processes based on frictional forces work decaying into heat is continuously increasing due to their strong advantages with respect to traditional fusion techniques. Several advances have been proposed by the scientific community regarding process mechanics, material flow and also the computer aided engineering of the operation with the aim to maximize the mechanical performances of the welded joints. In the paper Friction Stir Welding (FSW) and Linear Friction Welding (LFW) operations are considered and a review of the most relevant research issues and results is provided.
Outlining the Limits of Friction Stir Consolidation as Used as an Aluminum Alloys Recycling Approach
2021
Friction stir consolidation (FSC) is a solid-state process that recycles metal scraps economically and eco-friendly compared to the conventional melting method. The process parameters especially processing time and rotational speed, have a crucial role in achieving a sound disc during FSC. The current study answers the research question of how far these process parameters can be effective when the mass of chips to be recycled increases. In specific, an experimental setup was analyzed that was previously identified as challenging for recycling 20 g chips of aluminum alloy AA 2024-O. Rotational speed was set doubled, and processing time was increased up to 1.5 times of their initial values. T…
Impedance analysis of perovskite solar cells: a case study
2019
Metal halide perovskites are mixed electronic-ionic semiconductors with an extraordinary rich optoelectronic behavior and the capability to function very efficiently as active layers in solar cells, with a record efficiency surpassing 23% nowadays. In this work, we carry out an impedance spectroscopy analysis of two perovskite solar cells with quite distinct optical and electrical characteristics, i.e. MAPbI3 and CsPbBr3-based devices. The main aim of the analysis is to establish how, regardless the inherent complexity of the impedance spectrum due to ionic effects, information like ideality factors, recombination losses and the collection efficiency can be qualitative and quantitatively as…
Manipulation of nanoparticles of different shapes inside a scanning electron microscope
2014
In this work polyhedron-like gold and sphere-like silver nanoparticles (NPs) were manipulated on an oxidized Si substrate to study the dependence of the static friction and the contact area on the particle geometry. Measurements were performed inside a scanning electron microscope (SEM) that was equipped with a high-precision XYZ-nanomanipulator. To register the occurring forces a quartz tuning fork (QTF) with a glued sharp probe was used. Contact areas and static friction forces were calculated by using different models and compared with the experimentally measured force. The effect of NP morphology on the nanoscale friction is discussed.
Complex tribomechanical characterization of ZnO nanowires: nanomanipulations supported by FEM simulations
2016
In the present work, we demonstrate a novel approach to nanotribological measurements based on the bending manipulation of hexagonal ZnO nanowires (NWs) in an adjustable half-suspended configuration inside a scanning electron microscope. A pick-and-place manipulation technique was used to control the length of the adhered part of each suspended NW. Static and kinetic friction were found by a 'self-sensing' approach based on the strain profile of the elastically bent NW during manipulation and its Young's modulus, which was separately measured in a three-point bending test with an atomic force microscope. The calculation of static friction from the most bent state was completely reconsidered…