Search results for "Thermodynamics"

Hydration and dehydration kinetics of xylazine hydrochloride

2009

From the experiments where mixture of xylazine hydrochloride hydrate H and anhydrous X were held at constant conditions, the stable form of xylazine hydrochloride can be found out. To determine equilibrium relative humidity, the unstable form of xylazine hydrochloride was inserted in thermostated humidity chamber and its weight was recorded by weighing the sample outside the chamber. The kinetic model and the rate constant for each condition were determined. The rate constants give information regarding the speed of the process at every experimentally used relative humidity. Thus using the data in coordinates k – p for each temperature it is possible to determine the water vapor pressure of…

Thermodynamic and Kinetic Modeling of Co-utilization of Glucose and Xylose for 2,3-BDO Production by Zymomonas mobilis

2021

Prior engineering of the ethanologen Zymomonas mobilis has enabled it to metabolize xylose and to produce 2,3-butanediol (2,3-BDO) as a dominant fermentation product. When co-fermenting with xylose, glucose is preferentially utilized, even though xylose metabolism generates ATP more efficiently during 2,3-BDO production on a BDO-mol basis. To gain a deeper understanding of Z. mobilis metabolism, we first estimated the kinetic parameters of the glucose facilitator protein of Z. mobilis by fitting a kinetic uptake model, which shows that the maximum transport capacity of glucose is seven times higher than that of xylose, and glucose is six times more affinitive to the transporter than xylose.…

A phenomenological approach to the mechanical breakdown of anodic oxide films on zirconium

1986

Abstract A phenomenological theory of the mechanical breakdown of films growing on valve metals during galvanostatic oxidation is presented and discussed in detail for ZrO2 anodic films. It is shown that the mechanical breakdown voltage, Vmb, can be linearly related to the logarithm of the anodizing current density both in the case of constant and variable critical thickness, Lc, at which the breakdown occurs. It is also shown that the Amb and Bmb parameters of the relationship: Vmb = Amb + Bmb log i are strictly related to the kinetic parameters of growth of the films in the different solutions. The expressions of Amb and Bmb parameters are derived for films grown in the presence as well a…

An Interfacial Thermodynamic Model for the Oxidation Kinetics of a Metal: Epitaxial Stress Effects

2004

Mechanical Stresses: Inhibitor of Catalyst of High Temperature Oxidation?

2001

Oxidation of metals is a complex reaction in which mechanical and chemical phenomena occur. A dynamic and macroscopic model is developed in order to simulate oxidation kinetics of a metal. It includes the stress/diffusion coupling in the bulk and the interfacial phenomena at metal/oxide interface. Its application to the Zr/ZrO 2 system shows the important role of stress field distribution in oxide on kinetic behavior. According to the sign of stress gradient in the oxide scale, the oxidation rate can speed up or slow down. The calculated kinetic curves could he fitted using a k p .t 1/n law where n and kp vary all over the process, like for the experimental kinetic curves.

Conjugate and cut loci of a two-sphere of revolution with application to optimal control

2008

Abstract The objective of this article is to present a sharp result to determine when the cut locus for a class of metrics on a two-sphere of revolution is reduced to a single branch. This work is motivated by optimal control problems in space and quantum dynamics and gives global optimal results in orbital transfer and for Lindblad equations in quantum control.

On some Riemannian aspects of two and three-body controlled problems

2009

The flow of the Kepler problem (motion of two mutually attracting bodies) is known to be geodesic after the work of Moser [20], extended by Belbruno and Osipov [2, 21]: Trajectories are reparameterizations of minimum length curves for some Riemannian metric. This is not true anymore in the case of the three-body problem, and there are topological obstructions as observed by McCord et al. [19]. The controlled formulations of these two problems are considered so as to model the motion of a spacecraft within the influence of one or two planets. The averaged flow of the (energy minimum) controlled Kepler problem with two controls is shown to remain geodesic. The same holds true in the case of o…

A physical-based constitutive model for surface integrity prediction in machining of OFHC copper

2017

International audience; Due to the rising interest in predicting machined surface integrity and sustainability, various models for metal cutting simulation have been developed. However, their accuracy depends deeply on the physical description of the machining process. This study aims to develop an orthogonal cutting model for surface integrity prediction, which includes a physical-based constitutive model of Oxygen Free High Conductivity (OFHC) copper. This constitutive model incorporates the effects of the state of stress and microstructure on the work material behavior, as well as a dislocation density-based model for surface integrity prediction. The coefficients of the constitutive mod…

Influence of cutting process mechanics on surface integrity and electrochemical behavior of OFHC copper

2014

The authors gratefully acknowledge the support received from IC ARTS and CEA Valduc; International audience; Superfinishing machining has a particular impact on cutting mechanics, surface integrity and local electrochemical behavior. In fact, material removal during this process induces geometrical, mechanical and micro-structural modifications in the machined surface and sub-surface. However, a conventional 3D cutting process is still complex to study in terms of analytical/numerical modeling and experimental process monitoring. So, researchers are wondering if a less intricate configuration such as orthogonal cutting would be able to provide information about surface integrity as close as…

Orthogonal cutting simulation of OFHC copper using a new constitutive model considering the state of stress and the microstructure effects

2016

International audience; This work aims to develop an orthogonal cutting model for surface integrity prediction, which incorporates a new constitutive model of Oxygen Free High Conductivity (OFHC) copper. It accounts for the effects of the state of stress on the flow stress evolution up to fracture. Moreover, since surface integrity parameters are sensitive to the microstructure of the work material, this constitutive model highlights also the recrystallization effects on the flow stress. Orthogonal cutting model is validated using experimental designed cutting tests. More accurate predictions were obtained using this new constitutive model comparing to the classical Johnson-Cook model.