Search results for "Thermoelectric effect"
showing 10 items of 147 documents
Growth mechanisms and related thermoelectric properties of innovative hybrid networks fabricated by direct deposition of Bi2Se3 and Sb2Te3 on multiwa…
2020
Abstract Flexible thermoelectric generators are an emerging trend in the field of waste heat conversion, as well as wearable and autonomous devices. However, the energy conversion efficiency of the state-of-the-art flexible thermoelectric devices is too low for their wide application and commercialization. In this work, n- and p-type multiwalled carbon nanotube (MWCNT)-thermoelectric material hybrid networks that may become a promising building block for the fabrication of flexible thermoelectric devices are presented. The hybrid networks were fabricated by direct deposition of thermoelectric material (Bi2Se3, Sb2Te3) on the MWCNT networks using physical vapor deposition technique. Growth m…
High Thermoelectric Power Factor Organic Thin Films through Combination of Nanotube Multilayer Assembly and Electrochemical Polymerization
2017
In an effort to produce effective thermoelectric nanocomposites with multiwalled carbon nanotubes (MWCNT), layer-by-layer assembly was combined with electrochemical polymerization to create synergy that would produce a high power factor. Nanolayers of MWCNT stabilized with poly(diallyldimethylammonium chloride) or sodium deoxycholate were alternately deposited from water. Poly(3,4-ethylene dioxythiophene) [PEDOT] was then synthesized electrochemically by using this MWCNT-based multilayer thin film as the working electrode. Microscopic images show a homogeneous distribution of PEDOT around the MWCNT. The electrical resistance, conductivity (σ) and Seebeck coefficient (S) were measured before…
Changes in the thermoelectric response of vitreous carbon due to the irradiation by γ-rays
2014
In order to study variations in the thermoelectric properties, some commercial glassy carbon samples were subjected to a sequence of steps consisting of a combination of irradiation with γ-rays produced by radioisotopes 60Co, and hydrogen adsorption when the samples were put in an over pressured atmosphere of this gas. With this procedure it was possible to observe that the irradiation decreases the electrical conductivity of glassy carbon samples and the hydrogenation changes the sign of Seebeck coefficient. The material initially is an n-type semiconductor, but with hydrogenation changes to p-type semiconductor. X-ray diffraction analysis showed that the hydrogenated vitreous carbon is mo…
Unprecedented pressure-driven metallization and topological charge transport in an anion radical salt
2021
Abstract The hybrid inorganic/organic closed π -stacking and soft lattice of a copper anion radial (Copper-7,7,8,8-tetracyanoquinodimethane) renders its electrical conductivity and structural modifications, which are susceptible to temperature and pressure. The geometry of its metal-ligand construction contemplates the concept of topology with a charge-transfer instability. A pressure-induced ionic-neutral phase transition occurs and accompanies an anomalously large electrical conductivity, carries topological charges, and possesses a low energy gap smaller than the Coulomb gap. X-ray absorption spectroscopy of the metal establishes the high electrical conduction by the topological charges.…
Thermoelectric Transport in Cu7PSe6 with High Copper Ionic Mobility
2014
Building on the good thermoelectric performances of binary superionic compounds like Cu2Se, Ag2Se and Cu2S, a better and more detailed understanding of phonon-liquid electron-crystal (PLEC) thermoelectric materials is desirable. In this work we present the thermoelectric transport properties of the compound Cu7PSe6 as the first representative of the class of argyrodite-type ion conducting thermoelectrics. With a huge variety of possible compositions and high ionic conductivity even at room temperature, the argyrodites represent a very good model system to study structure-property relationships for PLEC thermoelectric materials. We particularly highlight the extraordinary low thermal conduct…
Thermoelectric radiation detector based on a superconductor-ferromagnet junction : Calorimetric regime
2018
We study the use of a thermoelectric junction as a thermal radiation detector in the calorimetric regime, where single radiation bursts can be separated in time domain. We focus especially on the case of a large thermoelectric figure of merit $ZT$ affecting significantly for example the relevant thermal time scales. This work is motivated by the use of hybrid superconductor/ferromagnet systems in creating an unprecedentedly high low-temperature $ZT$ even exceeding unity. Besides constructing a very general noise model which takes into account cross correlations between charge and heat noise, we show how the detector signal can be efficiently multiplexed by the use of resonant LC circuits gi…
Spin caloric effects in antiferromagnets assisted by an external spin current
2018
Searching for novel spin caloric effects in antiferromagnets we study the properties of thermally activated magnons in the presence of an external spin current and temperature gradient. We predict the spin Peltier effect -- generation of a heat flux by spin accumulation -- in an antiferromagnetic insulator with cubic or uniaxial magnetic symmetry. This effect is related with spin-current induced splitting of the relaxation times of the magnons with opposite spin direction. We show that the Peltier effect can trigger antiferromagnetic domain wall motion with a force whose value grows with the temperature of a sample. At a temperature, larger than the energy of the low-frequency magnons, this…
Nonlinear thermovoltage and thermocurrent in quantum dots
2013
Quantum dots are model systems for quantum thermoelectric behavior because of their ability to control and measure the effects of electron-energy filtering and quantum confinement on thermoelectric properties. Interestingly, nonlinear thermoelectric properties of such small systems can modify the efficiency of thermoelectric power conversion. Using quantum dots embedded in semiconductor nanowires, we measure thermovoltage and thermocurrent that are strongly nonlinear in the applied thermal bias. We show that most of the observed nonlinear effects can be understood in terms of a renormalization of the quantum-dot energy levels as a function of applied thermal bias and provide a theoretical m…
Thermoelectric Effects: Semiclassical and Quantum Approaches from the Boltzmann Transport Equation
2013
The thermoelectric efficiency of a material depends on its electronic and phononic properties. It is normally given in terms of the dimensionless figure of merit Z T = σ S 2 T ∕ κ. The parameters involved in Z T are the electrical conductivity σ, the Seebeck coefficient S, and the thermal conductivity κ. The thermal conductivity has two contributions, κ = κ e + κ L , the electron thermal conductivity κ e and the lattice thermal conductivity κ L . In this chapter all these parameters will be deduced for metals and semiconductors, starting from the Boltzmann transport equation (BTE). The electrical conductivity, the Seebeck coefficient, and the electronic thermal conductivity will be obtained…
Complex Terahertz and Direct Current Inverse Spin Hall Effect in YIG/Cu1-xIrx Bilayers Across a Wide Concentration Range
2018
We measure the inverse spin Hall effect of Cu1-xIrx thin films on yttrium iron garnet over a wide range of Ir concentrations (0.05 ⩽ x ⩽ 0.7). Spin currents are triggered through the spin Seebeck effect, either by a continuous (dc) temperature gradient or by ultrafast optical heating of the metal layer. The spin Hall current is detected by electrical contacts or measurement of the emitted terahertz radiation. With both approaches, we reveal the same Ir concentration dependence that follows a novel complex, nonmonotonous behavior as compared to previous studies. For small Ir concentrations a signal minimum is observed, whereas a pronounced maximum appears near the equiatomic composition. We …