Search results for "Titan"
showing 10 items of 1109 documents
Preparation in mild conditions of photocatalytically active nanostructured TiO2 rutile
2006
Abstract Nano structured TiO 2 rutile samples were prepared in mild conditions by hydrolysis of TiCl 4 in different solutions. The powders revealed a fair photoactivity for the photoeatalytic degradation of 4-nitrophenol. The influence of preparation procedure, pH and presence of Cl − and N 3 − anions on the physicochemical features and photocatalytic activity of the powders was investigated.
ChemInform Abstract: Enhanced Surface Area in Thermally Stable Pure Mesoporous TiO2.
2001
Abstract We describe here for the first time the surfactant-assisted synthesis of thermally stable mesoporous pure TiO 2 having a high surface area. Our synthetic approach to the chemistry of this system is based on the equilibrium between the hydrolysis and condensation reactions of the inorganic species and the organic–inorganic self-assembling processes. The use of titanatrane complexes helps to retard the hydrolysis and condensation reactions, thus allowing us to overcome the difficulties in preparing titanium dioxide mesoporous materials starting from highly reactive Ti-alkoxides. The mesoporous material has been characterized by TEM, XRD and N 2 adsorption–desorption isotherms and dis…
Rebuttal to “Comment on “Evidence of electrical activity on Titan drawn from the Schumann resonances sent by Huygens probe” by J.A. Morente, J.A. Por…
2009
Abstract Hamelin et al. criticize some conclusions of our paper [Morente, J.A., Porti, J.A., Salinas, A., Navarro, E.A., 2008. Icarus 195, 802–811]. This rebuttal is our response to their criticism. In our view, their comments are contradictory and not based on scientific argument. Our paper presents a comprehensible methodology for extracting weak resonances from the late-time response of systems with high losses and our conclusions are derived from and supported by this methodology, which was first checked using an analytical function and later with the data from a numerical simulation of Titan’s atmosphere. Conversely, the Comment of Hamelin et al. does not contain any mathematical proof…
Defect detection in additively manufactured titanium prosthesis by flying laser scanning thermography
2018
Abstract Metal additive manufacturing is nowadays a well-established technology for cutting edge applications in the automotive, aerospace, defense and medical sectors. Since additive metal deposition is basically a welding method, which creates parts by successively adding layers of material, there is a chance for defects like pores, cracks, inclusions and lack of fusion to develop. As a matter of fact, interlayer and intralayer defects are often observed in additive manufactured components. However, if one considers the typical end applications along with the high costs involved in metal additive manufactured components, a “zero defect” target is close to mandatory for this technology. Pl…
Synthesis and study of new fluorescent probes for optical imaging, Cherenkov imaging and multimodal imaging
2015
The goal of this work was to prepare and study new fluorescent probes, which could give rise to novel optical or Cherenkov imaging agents. The first section of this work describes the synthesis of fluorescent subphthalocyanines and phthalocyanines probes, which possess relevant chemicals groups suitable for optical imaging applications. The optical and physico-chemical properties of the new probes were carefully examined to ensure they comply with the specification of the fluorophores for the desired application. The second part focused on the subsequent development of a few selected probes into real imaging agents. The biovectorisation of subphtalocyanines was achieved upon conjugation of …
Vertical Osteoconductive Characteristics of Titanium Implants with Calcium-Phosphate-Coated Surfaces - A Pilot Study in Rabbits
2014
Introduction: Osteoconductive characteristics of different implant surface coatings are in the focus of current interest. The aim of the present study was to compare the vertical osteoconductivity at the implant shoulder of supracrestal inserted calcium-phosphate coated implants (SLA-CaP) with conventional sand-blasted/acid-etched (SLA) implants in a rabbit model. Materials and Methods: SLA-CaP and SLA implants were inserted bilaterally in the mandible of four rabbits in a split-mouth design. The implants were placed 2 mm supracrestal. After 3 weeks, at the left and right implant shoulder, the percentage of linear bone fill (PLF) as well as bone-implant contact (BIC-D) were determined. Resu…
Zirconium dioxide implants as an alternative to titanium: A systematic review
2020
Background: This systematic review evaluates the available scientific literature to demonstrate the aesthetic and clinical benefits and to determine the survival and the success of zirconium dioxide implants concerning titanium implants. Material and Methods: The electronic databases were searched until January 2020. Outcome measures were pink aesthetic score (PAS), white aesthetic score (WAS), bleeding on probing (BOP) and probing depth (PD). The addressed PICO question was: In partially edentulous patients in the upper-anterior sector, do zirconium dioxide implants provide aesthetic benefits over conventional titanium implants? Results: In the 15 articles included after the screening were…
Effect of bone loss on the fracture resistance of narrow dental implants after implantoplasty. An in vitro study
2021
Background Implantoplasty (IP) involves polishing of the exposed surface of implants affected by peri-implantitis (PI). A study was made to determine whether the degree of bone loss influences the fracture resistance of implants with or without IP. Material and Methods An in vitro study was carried out on 32 narrow (3.5 mm) dental implants with a rough surface and external hexagonal connection. Implantoplasty was performed in half of the implants of the sample. Both the IP and control implants were divided into two subgroups according to the amount of bone loss (3 mm or 7.5 mm). Standardized radiographic assessment of implant width was performed using specific software. The main outcome var…
Electrocaloric Effect in (1−x)(0.8Na0.5Bi0.5TiO3-0.2BaTiO3)−xCaTiO3 Solid Solutions at High Electric Fields
2022
This research was funded by the Latvian Science Council Fund, grant number lzp-2020/2-0080. The Institute of Solid State Physics, University of Latvia as the Center of Excellence has received funding from the European Union’s Horizon 2020 Framework Programme, grant number 739508.
Synthesis and structural characterization of novel tetranuclear organotitanoxane derivatives.
2011
Synthesis of the novel titanoxane compounds, [(TiCl)(TiOH){(Ti)[μ-(η(5)-C(5)Me(4)SiMe(2)O-κO)](2)(μ-O)}(2)(μ-O)] (4) and [{Ti[μ-(η(5)-C(5)Me(4)SiMe(2)O-κO)](μ-O)}(4)] (5) by controlled reaction of the dinuclear titanium oxo complex [{Ti{μ-(η(5)-C(5)Me(4)SiMe(2)O-κO)}Cl](2)(μ-O)] (1) with 2 equiv of LiOH is reported. Complex 4 is innovative and remarkable. It is one of the rare known examples of tetranuclear stable terminal hydroxo titanium complexes, with an open-chained structure, which coincides with the transient metal monohydroxo proposed in the stepwise pathway employed to justify the formation of the hexanuclear complex [{Ti[μ-(η(5)-C(5)Me(4)SiMe(2)O-κO)](μ-O)}(6)] (3) from 1. (1)H DO…