Search results for "Toe"
showing 10 items of 3824 documents
Molecular semiconductor-doped insulator (MSDI) heterojunctions: Oligothiophene/bisphtalocyanine (LuPc2) and perylene/bisphthalocyanine as new structu…
2010
Abstract The combination of a sexithiophene and a perylene diimide derivatives, as p-type and n-type materials, respectively, used as sub-layers, to an intrinsic semiconductor, namely the lutetium bisphthalocyanine, allows to obtain a new transducer for gas sensing. These transducers were called molecular semiconductor-doped insulator (MSDI) heterojunctions, were recently designed and reported, but with only phthalocyanines as active materials. p-Type material leads to MSDIs that exhibit a positive response to ozone and a negative response to ammonia, whereas MSDIs prepared from n-type material exhibit a positive response to ammonia and negative response to ozone. The remarkable point is th…
Phosphites as precursors in atomic layer deposition thin film synthesis
2021
We here demonstrate a new route for deposition of phosphorous based materials by atomic layer deposition (ALD) using the phosphites Me3PO3 or Et3PO3 as precursors. These contain phosphorous in the oxidation state (III) and are open for deposition of reduced phases by ALD. We have investigated their applicability for the synthesis of LiPO and AlPO materials and characterized their growth by means of in situ quartz crystal microbalance. Phosphites are good alternatives to the established phosphate-based synthesis routes as they have high vapor pressure and are compatible with water as a coreactant during deposition. The deposited materials have been characterized using XPS, x-ray fluorescence…
Luminescence properties of KNbO3 crystals
1997
Thermostimulated luminescence, X-ray-induced luminescence, photostimulated luminescence as well as the time-resolved luminescence and absorption after pulsed electron beam irradiation were studied in KNbO3 crystals at 80–400 K. A correlation between defects causing the luminescence and blue-light-induced IR absorption effects supressing the second harmonic generation efficiency in KNbO3 is discussed.
Nonlinear optical properties of silver nanoparticles: separating thermo-optical and Kerr effects
2021
In this paper, we present a study on thermo-optical effect in core-shell silver/thiol-termination ligand nanoparticles. Nanoparticles were dissolved in Dichloromethane. Experimental measurements were carried out using a Z-scan setup. As laser sources we used two 1064 nm lasers: i) 28 ps pulse width laser with 1000 Hz pulse repetition rate; ii) 8 ns pulse width laser with changeable pulse repetition rate 200 – 40 000 Hz. To study what processes lead to refractive index changes we used the polarization-resolved Z-scan method. Comparing ps and ns results showed that response time of single pulse thermal effects for organic solvents depends on beam size while for nanoparticles it corresponds to…
Volume integrated phase modulator based on funnel waveguides for reconfigurable miniaturized optical circuits.
2015
We demonstrate the integration of a miniaturized 30(x) μm × 30(y) μm × 2.7(z) mm electro-optic phase modulator operating in the near-IR (λ = 980 nm) based on the electro-activation of a funnel waveguide inside a paraelectric sample of photorefractive potassium lithium tantalate niobate. The modulator forms a basic tassel in the realization of miniaturized reconfigurable optical circuits embedded in a single solid-state three-dimensional chip.
Improvement of photocatalytic and photoelectrochemical activity of ZnO/TiO2 core/shell system through additional calcination: Insight into the mechan…
2017
Abstract ZnO/TiO2 composites were prepared by sol-gel deposition of TiO2 on ZnO nanorods hydrothermally grown on electrically conductive indium tin oxide substrate (ITO). It has been shown that the ZnO/TiO2 interface plays a key role in enhancement of photodecomposition of methylene blue (MB) used as a model test pollutant, under monochromatic light irradiation (400 nm). The increase of photocatalytic activity was attributed to the shift of absorption edge of ZnO/TiO2 towards visible light in comparison with bare TiO2. Further enhancement of photocatalytic activity of ZnO/TiO2 was achieved through its additional calcination at 450 °C for 3 h. This treatment brings 40% increase in the rate o…
How does an In-containing underlayer prevent the propagation of defects in InGaN QW LEDs?: identification of SRH centers and modeling of trap profile
2021
Recent reports indicated that the use of an InAlN underlayer (UL) can significantly improve the efficiency of InGaN/GaN quantum well (QW) LEDs. Currently, this result is explained by considering that the UL reduces the density of nonradiative recombination centers in the QWs. However, an experimental proof of the reduction of defects in the QWs is not straightforward. In this paper, we use combined electrical (I-V), optical (L-I), capacitance (C-V), steady-state photocapacitance (SSPC) and light-assisted capacitance-voltage (LCV) measurements to explain why devices with UL have a much higher efficiency than identical LEDs without UL. Specifically, we demonstrated an improvement in both elec…
The manipulation of ions using electromagnetic traps
1992
Electromagnetic traps, in addition to providing very clean and gentle confinement for very precise and sensitive observation of charged particles, are very versatile devices for collecting and preparing charged particles from outside sources for observation by devices which are also outside, devices which may in themselves be other electromagnetic traps. This paper introduces the basic principles of using electromagnetic traps for collecting and cooling and presents some preliminary test results from using Paul traps for these purposes. Specifically, in relatively modest Paul traps with 28 mm between end electrodes a collection efficiency of 0.2% was achieved for a 60 keV DC beam of 132Xe i…
Continuously tunable diamond Raman laser for resonance ionization experiments at CERN
2019
We demonstrate a highly efficient, continuously tunable, diamond Raman laser operating in the blue region of the spectrum. The linewidth and tunability characteristics of a frequency-doubled Ti:Sapphire laser were transferred directly to the Stokes output, offering great potential for spectroscopic applications using an all-solid-state platform.
Laser ablation of a silicon target in chloroform: formation of multilayer graphite nanostructures
2013
With the use of high-resolution transmission electron microscopy, selected area electron diffraction and x-ray photoelectron spectroscopy methods of analysis we show that the laser ablation of a Si target in chloroform (CHCl3) by nanosecond UV pulses (40 ns, 355 nm) results in the formation of about 50–80 nm core–shell nanoparticles with a polycrystalline core composed of small (5–10 nm) Si and SiC mono-crystallites, the core being coated by several layers of carbon with the structure of graphite (the shell). In addition, free carbon multilayer nanostructures (carbon nano-onions) are also found in the suspension. On the basis of a comparison with similar laser ablation experiments implement…