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showing 10 items of 1686 documents

IEEE Magnetics Society Distinguished Lecturers for 2020

2019

With information technology consuming a sizeable part of the total energy, “Green IT” information storage and computing technology will have a major impact on addressing societal challenges.

010302 applied physicsGreen computingComputer sciencebusiness.industry0103 physical sciencesInformation technologyElectrical and Electronic EngineeringTotal energybusinessTelecommunications01 natural sciencesElectronic Optical and Magnetic MaterialsIEEE Transactions on Magnetics
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Topological two-dimensional Su–Schrieffer–Heeger analog acoustic networks: Total reflection at corners and corner induced modes

2021

In this work, we investigate some aspects of an acoustic analogue of the two-dimensional Su-Schrieffer-Heeger model. The system is composed of alternating cross-section tubes connected in a square network, which in the limit of narrow tubes is described by a discrete model coinciding with the two-dimensional Su-Schrieffer-Heeger model. This model is known to host topological edge waves, and we develop a scattering theory to analyze how these waves scatter on edge structure changes. We show that these edge waves undergo a perfect reflection when scattering on a corner, incidentally leading to a new way of constructing corner modes. It is shown that reflection is high for a broad class of edg…

010302 applied physicsPhysics[PHYS]Physics [physics]Total internal reflectionWork (thermodynamics)Condensed Matter - Mesoscale and Nanoscale PhysicsScatteringGeneral Physics and AstronomyClassical Physics (physics.class-ph)FOS: Physical sciencesPhysics - Classical Physics02 engineering and technologyEdge (geometry)021001 nanoscience & nanotechnologyTopology01 natural sciencesSquare (algebra)0103 physical sciencesMesoscale and Nanoscale Physics (cond-mat.mes-hall)Reflection (physics)Limit (mathematics)Scattering theory0210 nano-technologyComputingMilieux_MISCELLANEOUS
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Silicon dosimeters based on Floating Gate Sensor: design, implementation and characterization

2020

A rad-hard monolithic dosimeter has been implemented and characterized in a standard 180 nm CMOS technology. The radiation sensor (C-sensor) is based on a Floating Gate (FG) MOS discharge principle. The output current is processed by a current-to-voltage (I/V) interface and then converted by a 5-bit flash ADC. The dosimeter is re-usable (FG can be recharged) and can detect a dose up to 1krad (Si) with a resolution of 30rad (Si) typical over temperature 0 to 85°C range. The ADC allows easy further signal processing for calibration and averaging, etc. The power consumption of C-sensor plus I/V interface is < 2mW from a 5 V power supply. The overall layout area is less than 0.25mm2. The Rad…

010302 applied physicsSignal processingMaterials scienceDosimeterSettore ING-IND/20 - Misure E Strumentazione Nucleari010308 nuclear & particles physicsbusiness.industryAnalog-to-digital converterHardware_PERFORMANCEANDRELIABILITYFlash ADC01 natural sciencesPower (physics)law.inventionCMOSlawAnalog-to-Digital converter current-to-voltage interfaces Dosimeter edgeless transistors (ELT) Floating Gate MOS radiation hardening by design (RHBD) total ionizing dose (TID)Absorbed dose0103 physical sciencesHardware_INTEGRATEDCIRCUITSCalibrationOptoelectronicsbusiness2020 IEEE 20th Mediterranean Electrotechnical Conference ( MELECON)
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The Effect of the Harmonic Content Generated by AC/DC Modular Multilevel Converters on HVDC Cable Systems

2019

With the increasing penetration of renewable and decentralized energy sources into the power grid, an extended use of DC voltages is expected on both distribution and transmission levels. Generation of DC voltages by means of voltage source converters is associated with a wide spectrum of harmonic distortions at converter terminals, both on the ac and on the dc sides. This can lead to partial discharges in power cables, which deteriorate insulation material thus weakening its performance and reducing cable life-time. In the previously published paper, the effect of harmonic distortion on appearance of partial discharges in cable insulation was evaluated. Here, the study related to the PD be…

010302 applied physicsTotal harmonic distortionbusiness.industryComputer scienceripple020209 energyElectrical engineering02 engineering and technologyDC streConvertersmultilevel converter01 natural sciencesHarmonic analysisSynchronization (alternating current)partial dischargeSettore ING-IND/31 - ElettrotecnicaharmonicHarmonics0103 physical sciences0202 electrical engineering electronic engineering information engineeringHarmonicPDWaveformVoltage sourcebusiness2019 IEEE Conference on Electrical Insulation and Dielectric Phenomena (CEIDP)
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Synthesis of Lamellarin G Trimethyl Ether by von Miller-Plöchl-Type Cyclocondensation

2018

010405 organic chemistryChemistryLamellarin G trimethyl etherOrganic ChemistryTotal synthesisPhysical and Theoretical Chemistry010402 general chemistry01 natural sciencesMedicinal chemistry0104 chemical sciencesEuropean Journal of Organic Chemistry
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Total Synthesis of Stemoamide, 9a-epi-Stemoamide, and 9a,10-epi-Stemoamide: Divergent Stereochemistry of the Final Methylation Steps

2020

Total syntheses of stemoamide, 9a-epi-stemoamide, and 9a,10-epi-stemoamide by a convergent A + B ring-forming strategy is reported. The synthesis required a diastereoselective late-stage methylation of the ABC stemoamide core that successfully enabled access to three of the four possible diastereomeric structures. For the natural stemoamide series, the diastereoselectivity can be rationalized both by kinetic and thermodynamic arguments, whereas for the natural 9a-epi-stemoamide series, the kinetic selectivity is explained by the prepyramidalization of the relevant enolate.

010405 organic chemistryChemistryStereochemistryOrganic ChemistryDiastereomerTotal synthesisMethylation010402 general chemistrySelectivity01 natural sciencesStemoamide0104 chemical sciencesSynlett
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Total Synthesis of (±)-Scopolamine: Challenges of the Tropane Ring

2016

Scopolamine was synthesized using 6,7-dehydrotropine as a key intermediate. Rhodium-catalyzed [4 + 3] cycloaddition chemistry and a modified Robinson–Schopf reaction were each independently evaluated for their utility in constructing the tropane core. Both synthetic approaches gave comparable overall yields.

010405 organic chemistryChemistryStereochemistryOrganic ChemistryTotal synthesisTropane010402 general chemistryRing (chemistry)01 natural sciencesCycloaddition0104 chemical scienceschemistry.chemical_compoundScopolaminemedicineOrganic chemistryPhysical and Theoretical Chemistrymedicine.drugEuropean Journal of Organic Chemistry
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Total Synthesis of (-)-Oxycodone via Anodic Aryl-Aryl Coupling.

2019

A fully regio- and diastereoselective electrochemical 4a–2′-coupling of a 3′,4′,5′-trioxygenated laudanosine derivative enables the synthesis of the corresponding morphinandienone. This key intermediate is further transformed into (−)-oxycodone through conjugate nucleophilic substitution for E-ring closure and [4 + 2] cycloaddition with photogenerated singlet oxygen to accomplish diastereoselective hydroxylation at C-14. The anodic transformation provides high yields and can be performed under constant current conditions both in a simple undivided cell or in continuous flow.

010405 organic chemistrySinglet oxygenArylOrganic ChemistryTotal synthesis010402 general chemistryElectrochemistry01 natural sciencesBiochemistryCombinatorial chemistryCycloaddition0104 chemical sciencesHydroxylationchemistry.chemical_compoundchemistryNucleophilic substitutionPhysical and Theoretical ChemistryConjugateOrganic letters
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Volcanic structures investigation through SAR and seismic interferometric methods: The 2011-2013 Campi Flegrei unrest episode

2019

Observations from satellites provide high-resolution images of ground deformation allowing to infer deformation sources by developing advanced modeling of magma ascent and intrusion processes. Nevertheless, such models can be strongly biased without a precise model of the internal structure of the volcano. In this study, we jointly exploited two interferometric techniques to interpret the 2011–2013 unrest at Campi Flegrei caldera (CFc). The first is the Interferometric Synthetic Aperture Radar (InSAR) technique, which provides highly-resolved spatial and temporal images of ground deformation. The second is the Ambient Noise Tomography (ANT), which images subsurface structures, providing the…

010504 meteorology & atmospheric sciences0208 environmental biotechnologyAmbient noise levelSoil Science02 engineering and technologyInduced seismicityDeformation (meteorology)01 natural sciencesInSARTotal horizontal derivativeSillInterferometric synthetic aperture radarCalderaComputers in Earth SciencesNatural seismicity0105 earth and related environmental sciencesRemote sensinggeographygeography.geographical_feature_categoryGeology020801 environmental engineeringCampi Flegrei calderaVolcanoAmbient noise tomographyMagmaGeologySeismology
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Influence of Wind on Suspended Matter in the Water of the Albufera of Valencia (Spain)

2021

Wind is one of the factors that has a great influence on suspended matter in lakes, especially in shallow lagoons. In order to know how wind affects the water in Albufera of Valencia, a shallow coastal lagoon, the measured variables of turbidity and transparency have been correlated with the estimates by processing Sentinel-2 satellite images with the Sen2Cor processor. Data from four years of study show that most of them are light to gentle easterly breezes and moderate to fresh westerly breezes. The results obtained show significant correlations between the measured variables and those obtained from the satellite images for total suspended matter and water transparency and with the averag…

010504 meteorology & atmospheric sciences0208 environmental biotechnologyOcean Engineering02 engineering and technologyAtmospheric sciences01 natural sciencesWind speedlcsh:Oceanographylcsh:VM1-989Wind effectlcsh:GC1-1581TurbidityEcologia de les albuferesShallow lakeValencia0105 earth and related environmental sciencesWater Science and TechnologyCivil and Structural EngineeringtransparencyHydrologySuspended solidsbiologySedimentlcsh:Naval architecture. Shipbuilding. Marine engineeringbiology.organism_classificationTransparency (behavior)atmospheric_science020801 environmental engineeringTotal suspended matterwind effectshallow lakeEnvironmental scienceSatellitesuspended solidsSentinel-2Suspended matter
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