Search results for "Trace Element"
showing 10 items of 321 documents
Trace elements in hair of urban schoolboys: a diagnostic tool in environmental risk assessment.
2011
Hair analysis may represent a means to quantify the relationship between human exposure to metal contamination and the environmental conditions of workplaces or residence sites. Hair are stable and their composition does not change over short time period. Furthermore, sampling procedure is very easy, requires no specific professional skills, is painless and non-invasive. 334 hair samples were collected from Caucasian children 11-13 years old, of both genders, without colored or treated hair, living in several Sicilian towns characterized by different geochemical environments: urban (Palermo), volcanic (Etna), mining area (Antillo-Fiumedinisi), industrial site (Pace del Mela), uncontamined a…
Trace Element Concentration and Stable Isotope Ratio Analysis in Blueberries and Bilberries: A Tool for Quality and Authenticity Control
2021
Vaccinium genus berries—wild bilberries (Vaccinium myrtillus L.) and cultivated highbush blueberries (Vaccinium corymbosum L.)—are consumed worldwide, and their consumption has a trend of stable increase. Thus, considering their wide use in ethnomedicine, for juice and jam production, as functional food, as well as their use in preparations of extracts which have application potential in pharmaceutical and cosmetics industries, studies regarding the composition of these berries are of special importance. The aim of this study is to characterise the elemental and isotopic composition, as well as variation in element concentration in bilberries gathered from different sites in Northern Europe…
Sea urchin coelomocytes as a novel cellular biosensor of environmental stress: a field study in the Tremiti Island Marine Protected Area, Southern Ad…
2007
The aim of the present study was to investigate on the suitability of the sea urchin as a sentinel organism for the assessment of the macro-zoobenthos health state in bio-monitoring programmes. A field study was carried out during two oceanographic campaigns using immuno-competent cells, the coelomocytes, from sea urchins living in a marine protected area. In particular, coelomocytes subpopulations ratio and heat shock protein 70 (HSC70) levels were measured in specimens of Paracentrotus lividus (Lamark, 1816) collected in two sampling sites, namely Pianosa and Caprara Islands, both belonging to the Tremiti Island Marine Protected Area (MPA) in the Southern Adriatic Sea, Italy. By density g…
Major and trace elements in Boletus aereus and Clitopilus prunulus growing on volcanic and sedimentary soils of Sicily (Italy)
2017
The aim of this study was to determine and compare the content of 28 elements (Ag, Al, As, Ba, Be, Bi, Ca, Cd, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Mo, Na, Ni, Pb, Rb, Sb, Se, Sr, Tl, U, V and Zn) in fruiting bodies of Boletus aereus Bull. and Clitopilus prunulus P. Kumm collected from eleven unpolluted sites of Sicily (Italy) and, also to relate the abundance of chemical elements in soil with their concentration in mushrooms. Median concentrations of the most abundant elements in Boletus aereus ranged from 31,290 μg/g (K) to 107 μg/g (Zn) in caps and from 24,009 μg/g (K) to 57 μg/g (Zn) in stalks with the following abundance order: K > Na > Ca > Mg > Fe > Al > Rb > Zn. The s…
Assessing soil contamination and temporal trends of heavy metal contents in greenhouses on semiarid land
2018
Information about the behavior and temporal evolution of heavy metals in agricultural soils is limited, particularly about greenhouse soils on semiarid lands, indeed it nonexistent. Western Almería (Southern Spain) is a semiarid land where some 30,000 ha are occupied by greenhouses with high productivity. As these greenhouses are fundamental to the socioeconomic development of this area, they should be maintained and well conserved. However, there are indications that long-term intensive agriculture with considerable agrochemicals use can deteriorate soil quality, which in turn, would reduce productivity and food quality. This study was conducted to investigate soil contamination and the te…
Laminated carbonate deposits in Roman aqueducts: Origin, processes and implications
2013
Carbonate deposits in Roman aqueducts of Patara and Aspendos (southern Turkey) were studied to analyse the nature of their regular layering. Optical microscopy and electron-backscattered diffraction results show an alternation of dense, coarsely crystalline, translucent laminae composed of bundles and fans of elongate calcite crystals with their c-axes parallel to the long axis, and porous, fine-grained laminae with crystals at near-random orientation. The ?18O and ?13C data show a strong cyclicity and anti-correlation, whereby high and low ?18O values correspond to dense columnar and porous fine-grained laminae, respectively. Geochemical analyses show similar cyclic changes in carbonate co…
The impact of natural and anthropogenic factors on groundwater quality in an active volcanic/geothermal system under semi-arid climatic conditions: T…
2017
Abstract A comprehensive hydrogeochemical study of the cold and thermal groundwaters of the presently quiescent volcanic system at Methana was undertaken that involved collecting 71 natural water samples. Methana is a peninsula in Peloponnesus, Greece whose arid climate and hydrological situation is similar to that of the nearby small islands of the Aegean Sea. Similarly, the chemical and isotopic compositions of its water are dominated by the mixing of seawater with meteoric water both through direct intrusion and meteoric recharge. However, the simple mixing trends at Methana are modified by water–rock interaction processes, enhanced by the dissolution of endogenous CO2, which lead to str…
Hydrogeochemistry and Water Balance in the Coastal Wetland Area of “Biviere di Gela,” Sicily, Italy
2006
In the study area physical and chemical factors control the composition of surface and groundwaters, which in turn determine the water quality of the "Biviere di Gela" lake. These factors combine to create diverse water types which change their compositional character spatially as rainfall infiltrates the soil zone, moves down a topographically defined flow path, and interacts with bedrock minerals. Low-salinity waters, which represent the initial stage of underground circulation, start dissolving calcium carbonate from the local rocks. The progressive increase in salinity, characterized by substantially higher Ca, SO4, Na and Cl concentrations, suggests that dissolution of CaSO4 and NaCl i…
MPI-DING reference glasses for in situ microanalysis: New reference values for element concentrations and isotope ratios
2006
We present new analytical data of major and trace elements for the geological MPI-DING glasses KL2-G, ML3B-G, StHs6/80-G, GOR128-G, GOR132-G, BM90/21-G, T1-G, and ATHO-G. Different analytical methods were used to obtain a large spectrum of major and trace element data, in particular, EPMA, SIMS, LA-ICPMS, and isotope dilution by TIMS and ICPMS. Altogether, more than 60 qualified geochemical laboratories worldwide contributed to the analyses, allowing us to present new reference and information values and their uncertainties (at 95% confidence level) for up to 74 elements. We complied with the recommendations for the certification of geological reference materials by the International Associ…
Preservation of successive diagenetic stages in Middle Triassic bonebeds: Evidence from in situ trace element and strontium isotope analysis of verte…
2015
Abstract Bonebeds comprise reworked and time averaged constituents of different phosphatic vertebrate remains and, hence, provide an ideal substrate for the study of long and short term diagenetic processes. To test whether trace elements (U, Sr, REE) and 87 Sr/ 86 Sr ratios can be used for distinguishing between successive diagenetic signals, we performed geochemical analyses on vertebrate remains (bones, teeth, scales and coprolites) from two Triassic bonebeds located near Palzem (Germany). Trace element analysis was done on 170 vertebrate remains by LA-ICP-MS while 87 Sr/ 86 Sr ratios were determined for 39 bioclasts using LA-MC-ICP-MS. Although a low inter- and intra-bioclast REE variab…