Search results for "Transform"
showing 10 items of 3975 documents
Added Value of Intangibles for Organizational Innovation
2012
The purpose of this paper is to present the theoretical basis for a measurement and improvement system that will help organizations create a more innovative climate. The role of intangible assets in contributing to organizational innovativeness is clarified within six hypotheses on the basis of a cross-disciplinary literature review combining studies from psychology, human resources management, communication, information technology, and marketing. These factors range from the individual level to interaction with the environment surrounding the organization, and involve (a) individual psychological flexibility, (b) institutional and interpersonal trust, (c) diverse human resources, (d) strat…
Domains of Convergence of Kam Type Iterations for Eigenvalue Problems
1999
The KAM technique was first introduced to deal with small denominator problems appearing in perturbation of invariant tori in classical mechanics [1, 2]. Similar methods were later applied to many different problems, like e.g. eigenvalue problems for time dependent problems in the Floquet representation [3, 4, 5, 6]. Most of the known results are valid for sufficiently small perturbation of some simple (integrable) system. The phenomena arising for large perturbations, in particular critical perturbations at which a given torus loses its stability, have been discussed in the framework of some approximate schemes inspired in renormalization group ideas [7, 8, 9]. In this framework, an iterat…
Importance of quantiser design compared to optimal multigrid motion estimation in video coding
2000
Adaptive flow computation and DCT quantisation play complementary roles in motion compensated video coding schemes. Since the introduction of the intuitive entropy-constrained motion estimation of Dufaux et al. (1995), several optimal variable-size block matching algorithms have been proposed. Many of these approaches put forward their intrinsic optimality, but the corresponding visual effect has not been explored. The relative importance of optimal multigrid motion estimation with regard to quantisation is addressed in the context of MPEG-like coding. It is shown that while simpler (suboptimal) motion estimates give subjective results as good as the optimal motion estimates, small enhancem…
Mid-infrared and Raman spectrometry for quality control of pesticide formulations
2005
This article deals with recent developments in the use of vibrational spectrometry for the quantitative analysis of active components in commercial pesticide formulations. We review the techniques, such as Fourier transform infrared (FTIR) and FT-Raman spectrometries, and measurement modes, such as stopped flow or flow injection. FTIR is being used increasingly in the determination of pesticides in agrochemical products because of its relatively short analysis time. However, FT-Raman spectrometry provides direct analysis of solid and aqueous samples. It is therefore clear that these techniques enable fast, non-destructive, precise and accurate measurements, so vibrational spectrometry appea…
Fourier transform infrared spectrometric strategies for the determination of Buprofezin in pesticide formulations
2002
Abstract Two different strategies for Buprofezin determination, an off-line extraction and stopped-flow determination and an automated procedure, based on the on-line extraction of Buprofezin samples with chloroform and flowing action analysis–fourier transform infrared (FIA–FT-IR) spectrometric measurement of the extracts, have been developed. For the treatment of the off-line extraction mode, data a three-factor partial least squares (PLSs) calibration was developed, using the region from 1465.7 to 1342.3 cm−1 with a single point baseline defined at 2051.9 cm−1 and based on the use of chloroform solutions of Buprofezin. The method provides a R.S.D. On the other hand, the recommended FIA m…
Fourier transform infrared spectrometric determination of Malathion in pesticide formulations
2004
Abstract An environmentally friendly methodology has been developed for quality control analysis of emulsifiable concentrate pesticide formulations containing Malathion as active ingredient, using flow injection analysis (FIA)–Fourier transform infrared (FTIR) spectrometry. Five microlitres samples were directly injected into a 3 ml closed FIA manifold, in which 2 ml of CHCl 3 was re-circulated at 1.96 ml min −1 . After homogenisation and sample measurement, 2 μl volumes of a Malathion standard were injected, taking absorbance measurements after each injection. Peak height of the chemigrams, established from peak area values between 1027 and 1017 cm −1 , corrected with a baseline fixed from…
Flow Injection Analysis– F ourier Transform Infrared Spectrometry ( FIA / FT ‐ IR )
2001
The sections in this article are Advantages and Historical Perspective of the Use of FIA in FT-IR Direct Analysis of Samples by FIA/FT-IR FIA/FT-IR Determinations after Liquid Extraction FIA/FT-IR Determinations after Solid-Phase Extraction Enzymatic Analysis by FIA/FT-IR Vapor Generation FT-IR New Developments
Determination of insolubles in diesel lubricating oil by FIA-visible spectrometry
2003
Insolubles determination is one of the parameters usually recommended to evaluate the residual life of oil because their presence at elevated levels in diesel lubricating oil changes the viscosity, prematurely clogs filters and is one of the major factors in causing abrasive engine wear. The proposed method employs visible spectrophotometric detection in association with flow injection analysis. The results obtained by this method were compared with the ones obtained by Fourier transform infrared spectrometry (FT-IR) since this is the most employed method for insolubles determination. The proposed method presented a linear response from 0 to 3% (w/w) of insolubles in pentane (ASTM D-893). T…
FTIR approaches for diuron determination in commercial pesticide formulations.
2005
Two strategies have been developed for Diuron determination by FTIR spectrometry, an off-line extraction and stopped-flow determination and a fully mechanized procedure, based on the on-line extraction of Diuron and FIA-FTIR measurement of the extracts. The aforementioned procedures have been compared with a reference chromatographic method. The off-line FTIR spectra were obtained at a nominal resolution of 4 cm(-1) from 4000 to 900 cm(-1) by accumulating 25 scans. Diuron was determined using peak height measurements at 1582 cm(-1) corrected using a baseline defined between 1562 and 1614 cm(-1). The waste generation of the off-line procedure was 3.4 mL chloroform for each sample, and the me…
Metamodel Specialization for DSL Tool Building
2016
Most of domain-specific tool building and especially diagram editor building nowadays involves some usage of metamodels. However normally the metamodel alone is not sufficient to define an editor. Frequently the metamodel just defines the abstract syntax of the domain, mappings or transformations are required to define the editor. Another approach [8] is based on a fixed type metamodel, there an editor definition consists of an instance of this metamodel to be executed by an engine. However there typically a number of functionality extensions in a transformation language is required. The paper offers a new approach based on metamodel specialization. First the metamodel specialization based …