Search results for "Transition"

showing 10 items of 3988 documents

Role of Vibrational Dynamics in Electronic Relaxation of Cr(acac)3

2015

Ultrafast energy relaxation of Cr(acac)3 dissolved in tetrachloroethylene (TCE) is studied by time-resolved infrared (TRIR) spectroscopy by using electronic and vibrational excitation. After electronic excitation at 400 or 345 nm, the ground state recovers in two time scales: 15 ps (major pathway) and 800 ps (minor pathway), corresponding to fast electronic transition to the ground state and intermediate trapping on the long-lived (2)E state followed by intersystem crossing (ISC) to the ground state. The quantum yield for the fast recovery of the ground state depends on the excitation wavelength, being higher for 345 nm. Vibrational cooling (VC) occurs on the electronic excited states with …

ta114ChemistryRelaxation (NMR)kinetic modelsQuantum yieldMolecular physicsMolecular electronic transitiontransition metal complexesvibrationsIntersystem crossingComputational chemistryExcited statePhysical and Theoretical ChemistryGround stateSpectroscopyta116ExcitationThe Journal of Physical Chemistry A
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Equal access to the top? Measuring selection into finnish academia

2019

In this article, we draw a parallel between equality of opportunity in educational transitions and equality of opportunity in academic careers. In both cases, many methodological problems can be ameliorated by the use of longitudinal rather than cross-sectional data. We illustrate this point by using Finnish full-population register data to follow the educational and academic careers of the 1964–1966 birth cohorts from birth to the present day. We show how the Finnish professoriate is highly selected both in terms of parental background and in terms of gender. Individuals of different backgrounds differ greatly in the likelihood of completing different educational and academic transitions, …

ta520Sociology and Political ScienceEconomicsacademic career0211 other engineering and technologies02 engineering and technologyuniversity level of educationacademiaSociology & anthropologyacademiceducational transition050602 political science & public administrationgenderta516FrauequalityHochschulbildungFinlandOccupational Research Occupational Sociologyequal opportunityeducationSozialwissenschaften SoziologiePoint (typography)05 social sciencesContrast (statistics)Wirtschaft021107 urban & regional planning0506 political sciencetasa-arvokorkeakoulutetutlcsh:Sociology (General)equality of rightshigher educationwomanddc:300ddc:301Sociology of Science Sociology of Technology Research on Science and TechnologyPsychologyBirth cohortWissenschaftssoziologie Wissenschaftsforschung Technikforschung TechniksoziologieSocial PsychologyHigher educationacademic (female)lcsh:HM401-1281academysukupuolicareerGleichberechtigungddc:330Berufsforschung BerufssoziologieSocial sciences sociology anthropologySelection (genetic algorithm)Academic careerChancengleichheitAkademikerinbusiness.industryGeschlechtAkademikerKarriereurakehitysFinnlandFrauen- und GeschlechterforschungRegister dataSoziologie AnthropologieAkademiesiirtymäaikaDemographic economicsWomen's Studies Feminist Studies Gender StudiesbusinessBildung
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From single to multi-variable Calculus: a transition?

2018

International audience; We recently used the notion of praxeology from the Anthropological Theory of the Didactic to model the knowledge that is necessary for students to learn in order to succeed in an undergraduate multivariable Calculus course. We considered the presence and absence of elements of the knowledge to be taught, as proposed by curricular documents, in the knowledge to be learned, as indicated by final exams. Our results indicate that the mathematical activities expected of students at this level align with the activities observed in differential and integral Calculus, where exercise-driven assessments set students' work mainly in the recognition of types of tasks and recolle…

teaching and learning of analysis and calculus[SHS.EDU]Humanities and Social Sciences/Education[MATH.MATH-HO]Mathematics [math]/History and Overview [math.HO][SHS.EDU] Humanities and Social Sciences/Education[MATH.MATH-HO] Mathematics [math]/History and Overview [math.HO]ComputingMilieux_COMPUTERSANDEDUCATIONAnthropological Theory of the Didacticassessment practices in university mathematics educationTransition to and across university mathematicspraxeology
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A study of transitions in an undergraduate mathematics program

2018

International audience; In this paper, we introduce an in-progress study of the transitions students face as they advance in their mathematics courses. Previous work has discussed the changes that occur in the transition from high school to university. With regards to the knowledge students are expected to learn, however, significant similarities have been noted: to do well in introductory university courses, students can learn to solve a particular subset of tasks through routinized techniques, with limited awareness of the supporting mathematical theory. In contrast, students in advanced courses are required to work with and on that theory. The first stage of our project aims to better un…

teaching and learning of analysis and calculusteachers' and students' practices at university level[SHS.EDU]Humanities and Social Sciences/Education[MATH.MATH-HO]Mathematics [math]/History and Overview [math.HO][SHS.EDU] Humanities and Social Sciences/Education[MATH.MATH-HO] Mathematics [math]/History and Overview [math.HO]ComputingMilieux_COMPUTERSANDEDUCATIONTransition to and across university mathematics
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Effect of Core–Shell Rubber Nanoparticles on the Mechanical Properties of Epoxy and Epoxy-Based CFRP

2022

This research was funded by M-Era.Net project MERF “Matrix for carbon reinforced epoxy laminates with reduced flammability” grant No. 1.1.1.5/ERANET/20/04 from the Latvian State Education Development Agency and M-Era.Net project “EPIC—European Partnership for Improved Composites“ funded by grant No. TH06020001. A.S., K.S. and A.Z. are grateful to funding received from the European Union Horizon 2020 Framework program H2020-WIDESPREAD-01-2016-2017-TeamingPhase2 under grant agreement No. 739508, project CAMART2.

tensile propertiescore–shell rubber nanoparticlesepoxy; CFRP; core–shell rubber nanoparticles; tensile properties; fracture toughness; glass transition temperatureGeneral Materials Science:NATURAL SCIENCES::Physics [Research Subject Categories]glass transition temperatureCFRPepoxyfracture toughness
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Présentation du Réseau de recherche et d’innovation sur la transition socio-écologique

2014

National audience

territoireécologie territoriale[SHS.ENVIR] Humanities and Social Sciences/Environmental studies[SHS.ENVIR]Humanities and Social Sciences/Environmental studies[ SHS ] Humanities and Social Sciencestransition[SHS] Humanities and Social Sciences[ SHS.ENVIR ] Humanities and Social Sciences/Environmental studiesdéveloppmement durableComputingMilieux_MISCELLANEOUS[SHS]Humanities and Social Sciences
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’Civilising’ the Transitional Generation: The Politics of Civic Education in Post-Communist Romania

2019

Abstract The paper examines the introduction of civic education in post-communist Romania as an educational means of civilising in a democratic ethos the children of the transition. Particularly close analytical attention is paid to a) the political context that shaped the decision to introduce civic education, b) the radical changes in both content and end purpose of civics brought about by educational policies adopted for accelerating the country’s efforts of integrating into the Euro-Atlantic structures (NATO and the European Union), and c) the actual consequences that these educational policies betting on civics have had on the civic values expressed by Romanian teenagers. The analysis …

textbook researcheducation policyPoliticsPost communistPolitical economyPolitical scienceSociology (General)national memorytransition to democracypost-communismHM401-1281Social Change Review
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Latvijas rūpniecībai aktuālu farmaceitiski aktīvo vielu kristālsolvāti

2013

ANOTĀCIJA Promocijas darbs veltīts Latvijas tautsaimniecībai aktuālu farmaceitiski aktīvo vielu (FAV) izpētei. Veikti apskatīto vielu kristālsolvātu meklējumi un iegūtas līdz šim neaprakstītas vielu kristāliskās formas. Novērtēta iegūto formu stabilitāte iegūšanas, ražošanas un uzglabāšanas apstākļos. Atsevišķām FAV veikta struktūras noteikšana, gan izmantojot pulvera rentgendifraktometriju, gan monokristālu rentgendifraktometriju. Iegūtie rezultāti ir aktuāli zāļu ražotājiem, kā arī tiem ir zinātniska nozīme no FAV īpašību apzināšanas un metožu attīstības viedokļa. Atslēgas vārdi: kristālsolvāti, vielas stāvokļa diagramma, nestehiometriskie solvāti, vielu termodinamiskā stabilitāte, fāžu p…

thermodynamical stabilityChemistrykristālsolvātinestehiometriskie solvātivielu termodinamiskā stabilitātenonstoichiometric solvatesphase transition kineticsĶīmija ķīmijas tehnoloģijas un biotehnoloģijafāžu pāreju kinētikavielas stāvokļa diagrammacrystal solvatesĶīmijaphase diagram
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From South to North? Mobility of Southern Italian Students at the Transition from the First to the Second Level University Degree

2018

In the last decades, the Italian University System has encountered several structural reforms aimed at making it more internationally competitive. Among them, the introduction of the University financial autonomy has triggered an “internal” competition among Universities to attract students from the entire country. Students’ enrollment at the first level has decreased significantly especially after the economic crisis of 2008, while the students’ migration from the South to the Central and Northern regions of the country has increased. These phenomena have created further inequalities within the country and a cultural and socio-economic loss for the South that does not appear to slow down. …

time to eventInequalitymedia_common.quotation_subjectTransition (fiction)Financial autonomyDegree (music)Competition (economics)GeographyWork (electrical)Order (exchange)discrete-time competing risk modelMathematics educationstudents’ mobilityDemographic economicsSettore SECS-S/05 - Statistica Socialestudents’ mobility time to event discrete-time competing risk modelUniversity systemmedia_common
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A Time-Non-Homogeneous Double-Ended Queue with Failures and Repairs and Its Continuous Approximation

2018

We consider a time-non-homogeneous double-ended queue subject to catastrophes and repairs. The catastrophes occur according to a non-homogeneous Poisson process and lead the system into a state of failure. Instantaneously, the system is put under repair, such that repair time is governed by a time-varying intensity function. We analyze the transient and the asymptotic behavior of the queueing system. Moreover, we derive a heavy-traffic approximation that allows approximating the state of the systems by a time-non-homogeneous Wiener process subject to jumps to a spurious state (due to catastrophes) and random returns to the zero state (due to repairs). Special attention is devoted to the cas…

time-non-homogeneous jump-diffusion processesComputer scienceGeneral Mathematicsdouble-ended queues01 natural sciencestransition densitiesdouble-ended queues; time-non-homogeneous birth-death processes; catastrophes; repairs; transient probabilities; periodic intensity functions; time-non-homogeneous jump-diffusion processes; transition densities; first-passage-time010104 statistics & probabilitysymbols.namesakeZero state responseWiener processrepairsComputer Science (miscellaneous)Applied mathematicstime-non-homogeneous birth-death processes0101 mathematicsSpurious relationshipEngineering (miscellaneous)Queuefirst-passage-timeQueueing theorytransient probabilitieslcsh:Mathematics010102 general mathematicslcsh:QA1-939catastrophesperiodic intensity functionssymbolsDouble-ended queueFirst-hitting-time modelConstant (mathematics)Mathematics; Volume 6; Issue 5; Pages: 81
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