Search results for "Transition"
showing 10 items of 3988 documents
Theoretical investigation of the spin crossover transition states of the addition of methane to a series of Group 6 metallocenes using minimum energy…
2016
International audience; Density functional calculations are reported on the addition of methane to Group 6 metallocenes, M(η-C5H5)2 (M), M(CH2(η-C5H4)2) (a-M) and M(η-C5Me5)2 (M*) where M = Mo and W. Full geometry optimisations were carried out on the singlet and triplet 16 electron complexes, 1[M] and 3[M], the η2-methane complexes, 1[M(η2-CH4)], and the hydridomethyl adducts, 1[M(CH3)(H)]. The triplet state for [M] was found to be more stable for all six metallocenes, the difference being least in the case of the ansa-bridged system. Formation of the hydridomethyl complexes was exoenergetic for all tungsten systems and for a-Mo, the other two Mo systems being endoenergetic. Minumum energy…
Effect of AlR3 (R = Me, Et, iBu) addition on the composition and microstructure of ethylene/1-olefin copolymers made with post-metallocene complexes …
2018
The effect of trialkylaluminum compound (AlR3, where R = Me, Et, iBu) addition on the performance of the [LigZrCl]2(μ-O)/AliBu3/Ph3CB(C6F5)4 and LigTiCl2/AliBu3/Ph3CB(C6F5)4 (Lig = Me2N(CH2)2N(CH2-2-O-3,5-tBu2-C6H2)2) catalysts in ethylene/1-olefin copolymerization was investigated. The presence of AlMe3 in the feed during the copolymerization process catalyzed by the diamine-bis(phenolate) zirconium catalyst greatly increases the amount of incorporated comonomer and leads to microstructural changes, e.g., the formation of blocky and alternating sequences of 1-olefin units. Moreover, the use of AlMe3 limits the reaction yield and decreases the molecular weight of the produced copolymers. Th…
The effect of rheological approximations in 3-D numerical simulations of subduction and collision
2018
Abstract Subduction and collision zones evolve differently from one another due to different rheological properties, different amounts of regional isostatic compensation, and the different mechanisms by which forces are applied to the convergent plates. The rheology of mantle and lithosphere is known to have the largest influence on the dynamics of subduction and continental collision. However, previous 3-D geodynamic models of subduction/collision processes have used various rheological approximations, making their results difficult to compare, since there is no clear understanding on the extent of these approximations on the dynamics. Here, we test the effect of rheological approximations…
Sulfide enrichment at an oceanic crust-mantle transition zone: Kane Megamullion (23°N, MAR)
2018
Abstract The Kane Megamullion oceanic core complex located along the Mid-Atlantic Ridge (23°30′N, 45°20′W) exposes lower crust and upper mantle directly on the ocean floor. We studied chalcophile elements and sulfides in the ultramafic and mafic rocks of the crust-mantle transition and the mantle underneath. We determined mineralogical and elemental composition and the Cu isotope composition of the respective sulfides along with the mineralogical and elemental composition of the respective serpentines. The rocks of the crust-mantle transition zone (i.e., plagioclase harzburgite, peridotite-gabbro contacts, and dunite) overlaid by troctolites are by one order of magnitude enriched in several…
Shallow vent architecture during hybrid explosive-effusive activity at Cordón Caulle (Chile, 2011-12): Evidence from direct observations and pyroclas…
2013
International audience; In June 2011, an eruption of rhyolite magma began at the Puyehue-Cordón Caulle volcanic complex, southern Chile. By January 2012, explosive activity had declined from sustained pyroclastic (Plinian to sub-Plinian) fountaining to mixed gas and ash jetting punctuated by Vulcanian blasts. This explosive activity was accompanied by synchronous effusion of obsidian lava in a hybrid explosive-effusive eruption. Fortuitous climatic conditions permitted ground-based observation and video recording of transient vent dynamics as well as real-time collection of proximal juvenile ash as it sedimented from the active plume. The main eruptive vent complex and site of lava effusion…
The Impact of a Very Weak and Thin Upper Asthenosphere on Subduction Motions
2019
Recent geophysical observations report the presence of a very weak and thin upper asthenosphere underneath subducting oceanic plates at convergent margins. Along these margins, trench migrations are significantly slower than plate convergence rates. We use numerical models to assess the role of a weak upper asthenospheric layer on plate and trench motions. We show that the presence of this layer alone can enhance an advancing trend for the motion of the plate and hamper trench retreat. This mechanism provides a novel and alternative explanation for the slow rates of trench migration and fast-moving plates observed globally at natural subduction zones.
Depositional environments and iron ooid formation in condensed sections (Callovian Oxfordian, South-eastern part of the Paris basin, France)
2005
Carbonate platforms across Western Europe were superseded at the Middle–Upper Jurassic (Callovian–Oxfordian) boundary either by alternating marl–limestone and widespread marl deposits or by condensed sections containing iron ooids. The characteristics of marine condensed sections in the south-eastern part of the Paris Basin (France) and their distribution pattern are examined here, and a model of iron ooid formation is developed. Iron ooids are found from the shoreface to the offshore zone. They are most abundant in the median-to-distal offshore transition zone, where they originally formed. They also occur commonly, albeit often as reworked grains, in the proximal offshore zone, to which t…
Taphonomic processes inconsistent with indigenous Mesolithic acculturation during the transition to the Neolithic in the Western Mediterranean
2018
Abstract We applied taphonomic analysis combined with geostatistical approaches to investigate the hypothesis that Cocina cave (Eastern Iberia) represents an acculturation context for the appearance of Neolithic Cardial pottery. In the 1970s, Fortea suggested that this important site was a prime example of acculturation because of the presence of early Neolithic pottery in late Mesolithic contexts. Since that time Cocina cave has been heralded as an example of indigenous hunter-gatherers incorporating Neolithic cultural elements into their lifeways. We analyzed the area excavated by Fortea in the 1970s by digitizing archaeological records and testing the spatial distribution of artifacts us…
Identifying Early Warning Signals for the Sudden Transition from Mild to Severe Tobacco Etch Disease by Dynamical Network Biomarkers
2019
This article belongs to the Special Issue The Complexity of the Potyviral Interaction Network.
Much more than a clasp: evolutionary patterns of amplexus diversity in anurans
2020
AbstractThe evolution and diversification of animal reproductive modes have been pivotal questions in behavioural ecology. Amphibians present the highest diversity of reproductive modes among vertebrates, involving various behavioural, physiological and morphological traits. One such feature is the amplexus, which is the clasp or embrace of males on females during reproduction and is found almost universally in anurans. Hypotheses about the origin of amplexus are limited and have not been tested thoroughly, nor have they taken into account evolutionary relationships in most comparative studies. However, these considerations are crucial to an understanding of the evolution of reproductive mo…