Search results for "Transitions"
showing 10 items of 251 documents
Dielectric-Optical Switches: Photoluminescent, EPR, and Magnetic Studies on Organic–Inorganic Hybrid (azetidinium)2MnBr4
2022
A new organic–inorganic hybrid, AZEMnBr, has been synthesized and characterized. The thermal differential scanning calorimetry, differential thermal analysis, and thermogravimetric analyses indicate one structural phase transition (PT) at 346 and 349 K, on cooling and heating, respectively. AZEMnBr crystallizes at 365 K in the orthorhombic, Pnma, structure, which transforms to monoclinic P21/n at 200 K. Due to the X-ray diffraction studies, the anionic MnBr42– moiety is discrete. The azetidinium cations show dynamical disorder in the high-temperature phase. In the proposed structural PT, the mechanism is classified as an order–disorder type. The structural changes affect the dielectric resp…
Optical transitions and excitonic recombination in InAs/InP self-assembled quantum wires
2001
InAs self-assembled quantum wire structures have been grown on InP substrates and studied by means of photoluminescence and polarized-light absorption measurements. According to our calculations, the observed optical transitions in each sample are consistent with wires of different heights, namely from 6 to 13 monolayers. The nonradiative mechanism limiting the emission intensity at room temperature is related to thermal escape of carriers out of the wires.
Numerical evidence of hyperscaling violation in wetting transitions of the random-bond Ising model in d = 2 dimensions
2017
We performed extensive simulations of the random-bond Ising model confined between walls where competitive surface fields act. By properly taking the thermodynamic limit we unambiguously determined wetting transition points of the system, as extrapolation of localization-delocalization transitions of the interface between domains of different orientation driven by the respective fields. The finite-size scaling theory for wetting with short-range fields establishes that the average magnetization of the sample, with critical exponent β, is the proper order parameter for the study of wetting. While the hyperscaling relationship given by γ+2β=ν +ν requires β=1/2 (γ=4, ν =3, and ν =2), the therm…
Dynamical Ising-like model for the two-step spin-crossover systems
2003
In order to reproduce the two-step relaxation observed experimentally in spin-crossover systems, we investigate analytically the static and the dynamic properties of a two-sublattice Ising-like Hamiltonian. The formalism is based on a stochastic master equation approach. It is solved in the mean-field approximation, and yields two coupled differential equations that correspond to the HS fractions of the sublattices A and B. Virginie.Niel@uv.es ; Jose.A.Real@uv.es
X(5) critical-point symmetries in 138Gd
2011
International audience; The lifetimes of low-lying transitions in 138Gd have been measured using the recoil-distance Doppler-shift technique. The resultant reduced transition probabilities have been compared to X(5) critical-point calculations to assess the potential 'phase-transitional' behaviour of 138Gd. The X(5) symmetry describes the first order 'phase transition' between sphericity, U(5) and an axially deformed nuclear shape, SU(3). Although a high degree of correspondence is observed between the experimental and theoretical excitation energies, the large uncertainties of the experimental B(E2) values cannot preclude contributions from either vibrational or rotational modes of excitat…
Temporal phase control of bound-bound and bound-free two-photon transitions in NO with two time-delayed cross-polarized pulses
2001
0953-4075; Temporal phase control over the multi-photoionization of NO is investigated experimentally The coherent excitation of the molecular system is achieved by a sequence of two phase-related non-Fourier-transform-limited laser pulses delivered by a nanosecond dye laser, The phase-locked pulses are produced by making use of an actively stabilized interferometer with a tunable pathlength difference. As the coherence time of the laser is comparable with the inhomogenous dephasing time of the medium, the measurements are performed with temporally overlapped pulses. In order to avoid the modulation of the ionic signal coming from optical interference, the linear polarizations of the two pu…
Investigation of the Δn = 0 selection rule in Gamow-Teller transitions: The β-decay of 207Hg
2019
5 pags., 3 figs., 1 tab. -- Open Access funded by Creative Commons Atribution Licence 4.0
Size effect in phase transition kinetics
1988
The growth of a spontaneous lattice average magnetization in a magnetic system which is suddenly brought below the transition temperature is a stochastic process in which the very small fluctuations of the initial magnetization are amplified to a macroscopic size. The initial magnetization fluctuates in time around the zero average value because of the finite size of the system. As a consequence of the fluctuation-amplification phenomenon the nonlinear relaxation of the finite system is qualitatively different from that of the infinite one. The present paper studies this feature of phase-transition kinetics in the framework of a very simple model: the dynamical generalization of the spheric…
Effects of heat flux on lambda transition in liquid 4He,
2014
This paper is concerned with the derivation of a phase field model for λ-transition in 4He, when the liquid is subject to pressure and heat flux. As parameter that controls the transition, a field f that is the geometrical mean between the density of the fluid and that of the superfluid is used. The resulting model, that is a generalization of previous papers on the same subject, chooses as field variables the density, the velocity, the temperature and the heat flux, in addition to this field f. The restrictions on the constitutive quantities are obtained by using the Liu method of Lagrange multipliers. New results with respect to previous models are the presence of non-local terms to descr…
Influence effect of an external electric field and dissipative tunneling on intracenter optical transitions in quantum molecules with D2- states
2020
In the zero-range potential model and in the effective mass approximation, dispersion equations have been obtained, that describe dependence of the average binding energies of the quasistationary g- and u-states of the D − 2 - center in the QD, as well as the widths of energy levels on the magnitude of the external electric field and the parameters of 1D-dissipative tunneling. Dips in the field dependences of the binding energies average values for quasi-stationary g- and u-states have been revealed. It is shown that the field dependences of the energy level widths for the g- and u- states of the D − 2 -center have a resonance structure at the external electric field strengths corresponding…