Search results for "Troposphere"

Global sensitivity of aviation NO<sub>x</sub> effects to the HNO<sub>3</sub>-forming channel …

2013

Abstract. The impact of a recently proposed HNO3-forming channel of the HO2 + NO reaction on atmospheric ozone, methane and their precursors is assessed with the aim to investigate its effects on aviation NOx induced radiative forcing. The first part of the study addresses the differences in stratospheric and tropospheric HOx-NOx chemistry in general, by comparing a global climate simulation without the above reaction to two simulations with different rate coefficient parameterizations for HO2 + NO → HNO3. A possible enhancement of the reaction by humidity, as found by a laboratory study, particularly reduces the oxidation capacity of the atmosphere, increasing methane lifetime significantl…

The pattern of radiative heating and cooling in the troposphere and lower stratosphere

1956

For any meteorological effects of radiation, only those constituents of the air which have a very strong absorption in the infra-red are involved; these are water vapour and carbon dioxide. Several methods have been developed (Mügge & Möller 1932 a, b ; Elsasser 1942; Yamamoto 1952) for computing the radiation flux, and numerous calculations of these fluxes and of the cooling rates have been performed in the last 25 years (Ludwig 1935; Kortiim 1939; Thompson & Neiburger 1955). The results are summarized in figure 1, which shows the distribution of the tem­perature and of the cooling rate by water vapour in some characteristic atmospheres. The lower levels of the tropical atmosphere…

Contribution of the gas-phase reaction between hydroxyl radical and sulfur dioxide to the sulfate aerosol over West Pacific

2021

Sulfate is among the major components of atmospheric aerosols or fine particulate matters. Aerosols loaded with sulfate result in low air quality, damage to ecosystems, and influences on climate change. Sulfate aerosols could originate from that directly emitted to the atmosphere and that produced by atmospheric physicochemical processes. The latter is generated from sulfur dioxide (SO2) via oxidation either in the gas phase reactions or in the aqueous phase. Several mechanisms of SO2 oxidation have been proposed, but the differentiation of the various mechanisms and identification of the sources remain challenging. To meet this need, a new method to estimate the contribution of the gas-pha…

Sensitivity of shortwave radiative fluxes to the vertical distribution of aerosol single scattering albedo in the presence of a desert dust layer

2010

Abstract The aim of this work is to quantify the sensitivity of shortwave radiative fluxes to changes in the vertical distribution of aerosol absorption, taken into account through the aerosol Single Scattering Albedo (SSA). The case study represents a real atmospheric situation with a desert dust layer (DDL) in the mid troposphere over an urban Boundary Layer (BL) observed at Rome on 20 June 2007. A moderately high aerosol optical depth (AOD), 0.292 at 550 nm, and low Angstrom exponent of 0.30 were measured. The observed case was reconstructed with a radiative transfer model, in which the SSA of the boundary layer aerosols was varied from that of a highly absorbing aerosol type (urban) to …

In situ observations of CH<sub>2</sub>Cl<sub>2</sub> and CHCl<sub>3</sub…

2021

Abstract. Efficient transport pathways for ozone-depleting very short-lived substances (VSLSs) from their source regions into the stratosphere are a matter of current scientific debate; however they have yet to be fully identified on an observational basis. Understanding the increasing impact of chlorine-containing VSLSs (Cl-VSLSs) on stratospheric ozone depletion is important in order to validate and improve model simulations and future predictions. We report on a transport study using airborne in situ measurements of the Cl-VSLSs dichloromethane (CH2Cl2) and trichloromethane (chloroform, CHCl3) to derive a detailed description of two transport pathways from (sub)tropical source regions in…

2013

Abstract. It has become possible to retrieve the global, long-term trends of trace gases that are important to atmospheric chemistry, climate, and air quality from satellite data records that span more than a decade. However, many of the satellite remote sensing techniques produce measurements that have variable sensitivity to the vertical profiles of atmospheric gases. In the case of constrained retrievals like optimal estimation, this leads to a varying amount of a priori information in the retrieval and is represented by an averaging kernel (AK). In this study, we investigate to what extent the estimation of trends from retrieved data can be biased by temporal changes of averaging kernel…

2015

In 2011, the MOZAIC (Measurement of Ozone by AIRBUS In-Service Aircraft) successor programme IAGOS (In-service Aircraft for a Global Observing System) started to equip their long-haul passenger aircraft with the modified capacitive hygrometer Vaisala HUMICAP ® of type H. The assurance of the data quality and the consistency of the data set during the transition from MOZAIC Capacitive Hygrometers to IAGOS Capacitive Hygrometers were evaluated within the CIRRUS-III and AIRTOSS-ICE field studies. During these performance tests, the capacitive hygrometers were operated aboard a Learjet 35A aircraft together with a closed-cell Lyman-α fluorescence hygrometer, an open-path tunable diode laser (TD…

2009

Abstract. In-situ ice crystal size distribution measurements are presented within the tropical troposphere and lower stratosphere. The measurements were performed using a combination of a Forward Scattering Spectrometer Probe (FSSP-100) and a Cloud Imaging Probe (CIP), which were installed on the Russian high altitude research aircraft M55 "Geophysica" during the SCOUT-O3 campaign in Darwin, Australia. One of the objectives of the campaign was to characterise the Hector convective system, which appears on an almost daily basis during the pre-monsoon season over the Tiwi Islands, north of Darwin. In total 90 encounters with ice clouds, between 10 and 19 km altitude were selected from the dat…

The influence of ENSO on winter rainfall in South Africa

2011

Whereas the impact of ENSO on the African summer rainfall regions is largely documented and still regularly investigated, little is known about its impact on the winter rainfall regions located at the southwestern and northwestern tips of Africa. Yet, these regions are densely inhabited and are net exporters of high-quality agricultural products. Here we analyze the relationship between El Nino Southern Oscillation (ENSO) and South Africa austral winter rainfall using a 682 raingauges daily rainfall database documenting the period 1950–1999. The May, June and July (MJJ) seasonal rainfall amount shows a positive correlation with the Nino3.4 index that becomes significant since the so-called …

Observations of Kinematics and Thermodynamic Structure Surrounding a Convective Storm Cluster over a Low Mountain Range

2009

Abstract Measurements of a convective storm cluster in the northern Black Forest in southwest Germany have revealed the development of a warm and dry downdraft under its anvil cloud that had an inhibiting effect on the subsequent development of convection. These measurements were made on 12 July 2006 as part of the field campaign Prediction, Identification and Tracking of Convective Cells (PRINCE) during which a number of new measurement strategies were deployed. These included the collocation of a rotational Raman lidar and a Doppler lidar on the summit of the highest mountain in the region (1164 m MSL) as well as the deployment of teams carrying radiosondes to be released in the vicinity …