Search results for "Tungsten"
showing 10 items of 372 documents
Growth, Structure, and Stability of KxWO3 Nanorods on Mica Substrate
2012
International audience; KxWO3 nanorods, interesting as gas sensors, were elaborated on mica muscovite substrate and characterized by atomic force microscopy, scanning electron microscopy, X-ray photoelectron spectroscopy, and mainly transmission electron microscopy. A combination of structural analyses allowed determining the morphology of these rods, and selected area electron diffraction experiments pointed out the simultaneous presence of the exotic hexagonal and stable monoclinic phases. Moreover, the presence of potassium inside the nanorods, coming from the mica substrate, was revealed. By combining all the observations, a growth model is proposed, consisting of the stacking of two di…
Characterisation of scheelite LaW0.16Nb0.84O4.08 ion conductor by combined synchrotron techniques: Structure, W oxidation state and interdiffusion
2021
Abstract Scheelite-type materials such as LaNbO4 are increasingly attracting attention as a possible alternative to the most common fluorite and perovskite structure as ion conductors. However, they are much less used and investigated. The introduction of tungsten in lanthanum orthoniobate leads to conduction properties that are compatible with oxygen ion conductivity. In this paper, we studied the effect of the introduction of tungsten in the LaNbO4 structure. High resolution X-ray diffraction showed that in LaNb1-xWxO4+x/2 with x = 0.16 the monoclinic distortion is largely suppressed and the tetragonal phase is predominant at room temperature. By XANES/EXAFS we proved that tungsten is in …
One-step formation of nanostructures on silicon surfaces using pure hydrogen-radical-initiated reactions
2013
One-step formation of silicon nanowires, sheets, and texture surface on a silicon substrate has been achieved using hydrogen-radical etching reactions. Metallic tungsten and for comparison purposes a tungsten hot wire, were used as catalysts for the hydrogen-molecular cracking. It was shown that a variety of surface structures on silicon such as inverted pyramid texture, V-groove texture, dense silicon nanowire growth over texture, and nanosheet structure can be obtained by controlling the process conditions. The obtained results suggested that the formation of nanotungsten silicide particle is an essential prerequisite to obtain these structures. The particles work as an etching mask again…
Confocal spectromicroscopy of amorphous and nanocrystalline tungsten oxide films
2007
A Raman confocal spectromicroscopic system was used to study in situ phase composition and surface morphology in amorphous and nanocrystalline tungsten oxide and tungstate thin films, prepared on silicon and glass substrates by dc magnetron co-sputtering technique. The possible use of these films for the phase-change optical recording was demonstrated using 442 nm He–Cd laser with a variable power of up to 50 mW. The formation of nanocrystalline tungsten trioxide or tungstate phases was observed under the laser irradiation. These nanocrystalline phases show relatively strong Raman activity, which can be used for information reading purposes. A multilayer structure composed of several tungst…
<title>Vibrational spectra of tungsten oxides with different lattice topology</title>
1997
It is determined that vibrations of linear chains -O-W-O-W- in tungsten-oxygen network are rather independent. The value of vibrational frequency is determined by asymmetry of O equals W - O bonds.© (1997) COPYRIGHT SPIE--The International Society for Optical Engineering. Downloading of the abstract is permitted for personal use only.
Cutting performance and indentation behaviour of diamond films on Co-cemented tungsten carbide
2000
Abstract Diamond films were grown by Hot Filament Chemical Vapour Deposition (HFCVD) on differently pretreated ISO-grade K10 cemented carbide (WC-5.8 wt.%Co) cutting inserts. Etching with diluted HNO3 and surface roughening by Murakami's reagent were used as substrate pretreatments. The adhesion of the films was evaluated by indentation tests. In order to obtain a reliable estimation of the adhesion by the slope of the crack radius–indentation load curves, a careful SEM measurement of the crack lengths was performed. Bare and diamond-coated cutting inserts were used for turning tests of Al2O3-reinforced aluminum alloy. The adhesion levels obtained from the indentation curves correlated well…
WS2 2D Semiconductor Down to Monolayers by Pulsed-Laser Deposition for Large-Scale Integration in Electronics and Spintronics Circuits
2020
International audience; We report on the achievement of a large-scale tungsten disulfide (WS2) 2D semiconducting platform derived by pulsed-laser deposition (PLD) on both insulating substrates (SrTiO3), as required for in-plane semiconductor circuit definition, and ferromagnetic spin sources (Ni), as required for spintronics applications. We show thickness and phase control, with highly homogeneous wafer-scale monolayers observed under certain conditions, as demonstrated by X-ray photoelectron spectroscopy and Raman spectroscopy mappings. Interestingly, growth appears to be dependent on the substrate selection, with a dramatically increased growth rate on Ni substrates. We show that this 2D…
<title>Long-term testing results of WO<formula><inf><roman>3</roman></inf></formula>-based electrochromic c…
1997
Two batches of the samples of electrochromic cell with WO3 and IrOx electrodes and Sb2O5 (DOT) water based solid electrolyte were tested at constant contrast ratio up to 107 cycles or stored during five years and the changes of current-voltage characteristics were studied. Two kinds of the changes were observed. The shift of curves along the voltage axis is supposed to be associated with the changes in the oxidation degree of tungsten oxide, while the changes in their shapes are associated with changes of water content in pores. The processes in the samples during cycling and storing are discussed.© (1997) COPYRIGHT SPIE--The International Society for Optical Engineering. Downloading of the…
<title>Influence of treatment on stability of electrochromic WO<formula><inf><roman>3</roman></inf></formula&g…
1997
The influence of exposure in vacuum of 10-2 - 10-3 Pa and temperature treatment at 720 - 730 K in water vapor atmosphere on stability of tungsten oxide films in 0.1 N H2SO4 electrolyte were studied. The processes that take place during the film exposure in vacuum, determine the reduction of charge injection at the constant voltage change condition. In the case of temperature treatment the opposite changes of charge injection were observed. This indicates to opposite processes in films during both expositions. According to exposures characters, they could be a reduction of tungsten oxide initiated by oxygen evacuation from film in vacuum and film oxidation in water vapor media at high temper…
Advanced approach to the local structure reconstruction and theory validation on the example of the W L 3 -edge extended x-ray absorption fine struct…
2018
The authors gratefully acknowledge the assistance of the ELETTRA XAFS beamline staff members during the EXAFS experiment No 20150303. This work has been carried out within the framework of the EUROfusion Consortium and has received funding from the Euratom research and training programme 2014-2018 under grant agreement No 633053. The views and opinions expressed herein do not necessarily reflect those of the European Commission.