Search results for "Ultra"
showing 10 items of 4451 documents
Luminescence and transient absorption in ZnWO4 and ZnWO4–Fe crystals
2001
Abstract The transient absorption spectra and relaxation kinetics under pulse electron beam excitation in ZnWO 4 and ZnWO 4 –Fe, as well as luminescence spectra and decay kinetics, were studied. It is shown that a fraction of transient absorption is due to luminescence center excited state. The energy transfer from intrinsic excitations to the defect or impurity states is not efficient. The role of Fe-impurities in the decay process is discussed.
Charge transfer in the novel donor-acceptor complexes tetra- and hexamethoxypyrene with tetracyanoquinodimethane studied by HAXPES
2012
Abstract The effect of charge transfer (CT) in complexes of the donors tetra - and hexamethoxyprene ( TMP and HMP ) with the classical acceptor tetracyanoquinodimethane ( TCNQ ) was studied using hard X-ray photoemission (HAXPES). Microcrystals of the complex were grown via vapour diffusion from donor–acceptor mixtures. The bulk sensitivity of HAXPES at a photon energy of 6 keV completely eliminates the problem of surface contamination for such delicate organic materials grown from solution. The donor molecules were produced using a novel synthesis route functionalizing polycyclic aromatic hydrocarbons at their periphery. For comparison, spectra were also taken from thin-film samples of the…
Ten years of measured UV Index from the Spanish UVB Radiometric Network.
2013
An analysis is made of the UV Index (UVI) obtained from the ultraviolet erythemal solar radiation (UVER) data measured by the Spanish UVB Radiometric Network between the years 2000 and 2009. Previously, the daily UVI has been evaluated using two different criteria: (a) the value corresponding to solar noon; and (b) the daily maximum value. The mean percentage of agreement is 92% if we consider the cases for which the difference is zero or one UVI unit. These results are similar to those obtained in a previous work where only 2 years were analyzed. In all the stations the UVI reaches very high values (8-10) in spring-summer, and the very high and extreme (≥ 11) UVI values are more dependent …
RFID passive gas sensor integrating carbon nanotubes
2011
Carbon nanotube (CNT) composites are sensitive to the presence of gases due to their high surface-to-volume ratio and hollow structure that are well suited for gas molecule absorption and storage. Such sensing capability is here integrated with UHF RF identification (RFID) technology to achieve passive and low-cost sensors, remotely readable. CNT film (buckypaper) is used as a localized variable resistive load integrated into a tag antenna, which becomes able to transduce the presence of hazardous gas in the environment, ammonia in this case, into a change of its electromagnetic features. The dynamic range and the hysteresis of the radio sensor are investigated by simulations, equivalent ci…
Photoemission microscopy with microspot-XPS by use of undulator radiation and a high-throughput multilayer monochromator at BESSY
1999
We present a new experiment for photoelectron microspectroscopy by use of undulator radiation, which has been set up at the beamline U2 at the Berlin electron storage ring BESSY 1. This approach employs a non-imaging simulated hemispherical electron energy analyser attached to an imaging photoemission electron microscope (FOCUS IS-PEEM) with integrated microarea selector. The photoemission microscope exhibits a lateral resolution of 25 nm (with 4.9 eV UV-excitation), while the resolution with incident synchrotron radiation in the soft X-ray range is about 100-120 nm (mainly due to chromatic aberrations). Photoemission microscopy as well as photoelectron microspectroscopy of selected areas o…
Glow Rate Technique for Spectroscopy of Complex Thermostimulated Relaxation Processes
1996
The glow rate technique (GRT) developed for the analysis of complex trap spectra, is the extension of the known heating rate method to the full glow curve. It is shown that using two glow curves measured at different heating rate constants, a special mean activation energy of simultaneously emptied traps can be obtained as a function of temperature or emitted light sum to a good approximation. Expressions have been derived for the calculation of the mean activation energy function from data measured using a linear, logarithmic or a hyperbolic heating mode. Theoretical expressions for the mean activation energy function have been obtained and discussed for arbitrary trap distribution functio…
Time-resolved optical absorption in YAlO3 crystals
2004
Abstract The present work is devoted to the investigation of transient absorption (TA) induced by a pulsed electron beam (E=250 keV ) in pure and doped YAlO3 (YAP) single crystals. The nature of centers responsible for TA is discussed.
NanoESCA: imaging UPS and XPS with high energy resolution
2005
Abstract A novel imaging electron spectrometer has been used for laterally resolved ultraviolet photoelectron spectroscopy (UPS) and X-ray photoelectron spectroscopy (XPS) in the soft X-ray range. The instrument is based on a high-resolution emission microscope optics using a cathode lens and an imaging dispersive analyser. The analyser is corrected for the leading aberration term ( α 2 -term) by means of two hemispherical analysers in antisymmetric configuration with an appropriate transfer lens. Small-area spectra as well as energy-filtered images have been taken in the soft X-ray range for a meteorite sample and in the range of the d-band of a Cu polycrystal. An energy resolution of 106 …
Isolation and characterization of a photosystem I-associated antenna (LHC I) and a photosystem I—core complex from the chlorophyll c-containing alga …
1993
Abstract A photosystem (PS) I holocomplex was isolated from Pleurochloris meiringensis Vischer (Xanthophyceae) using sucrose density centrifugation. This complex exhibited a fluorescence emission maximum at 715 nm, which is in accordance with the long wavelength emission of whole cells. The complex was further dissociated into a core complex and a light-harvesting protein (LHC I). The core protein contains mainly Chl a and β-carotene, is 8.25 times enriched in P700 and has its main emission maximum at 715 nm. Therefore, the longest wavelength emission of P. meiringensis is due to the PS I core, which is in contrast to higher plants. The LHC I differs from LHC II with regard to its polypepti…
Temperature-dependent angular resolved UV-photoemission spectroscopy from CeNi2Ge2
2001
Abstract Pronounced temperature effects in angular resolved ultraviolet photoelectron spectroscopy from the (001) surface of the ternary heavy fermion compound CeNi 2 Ge 2 are presented. The measurements were performed on atomically clean and well-ordered thin films grown on a W(110) substrate. A strongly enhanced intensity at the Fermi edge ( ϵ F ) is observed at low-temperatures if the spectra are excited by means of HeI light ( hν =21.2 eV). In addition, the work function is dramatically increased with temperature, exhibiting an unusually high positive temperature coefficient of about 0.65 meV/K. The observed temperature dependency suggests a strong redistribution of the states near the …