Search results for "Urethane"

showing 8 items of 78 documents

Geometrical and conformational preferences of the 9‐fluorenylmethoxycarbonyl‐amino moiety

2004

Structural parameters, originating from x-ray crystallographic data, have been compiled for 13 derivatives of amino acids, peptides and related compounds, which contain a total of 14 Fmoc-NH- moieties. For these moieties, molecular geometries and conformations--described by the omegao, theta1, theta2 and theta3' torsion angles--were analysed and compared with the corresponding parameters for the Z-NH- and Boc-NH-moieties (290 and 553, respectively). To gain a deeper insight into the conformational features of the Fmoc-NH- moiety, ab initio free molecule calculations were performed for fully relaxed minima. Also the potential energy surface as a function of the torsion angles (theta3', theta…

crystal structureStereochemistryAb initioMolecular ConformationCrystal structureCrystallography X-RayBiochemistryBoc amino protectionStructure-Activity RelationshipfluoreneStructural BiologyAb initio quantum chemistry methodsDrug DiscoveryMoleculeMoietyurethane geometryFmoc amino protectionAmino AcidsMolecular BiologyPharmacologyFluorenesMolecular StructureChemistryHydrogen bondab initio calculationsOrganic ChemistryHydrogen BondingGeneral MedicineZ amino protectionMolecular geometryPotential energy surfaceMolecular MedicineCrystallizationPeptidesN‐terminally protected peptidesJournal of Peptide Science
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Polytetrafluoroethylene Films in Rigid Polyurethane Foams' Dielectric Permittivity Measurements with a One-Side Access Capacitive Sensor.

2021

As a non-metallic composite material, widely applied in industry, rigid polyurethane (PUR) foams require knowledge of their dielectric properties. In experimental determination of PUR foams’ dielectric properties protection of one-side capacitive sensor’s active area from adverse effects caused by the PUR foams’ test objects has to be ensured. In the given study, the impact of polytetrafluoroethylene (PTFE) films, thickness 0.20 mm and 0.04 mm, in covering or simulated coating the active area of one-side access capacitive sensor’ electrodes on the experimentally determined true dielectric permittivity spectra of rigid PUR foams is estimated. Penetration depth of the low frequency excitation…

dielectric permittivityMaterials sciencePolymers and PlasticsCapacitive sensing02 engineering and technologyDielectricengineering.materialLow frequency01 natural sciencesArticlelcsh:QD241-441chemistry.chemical_compoundlcsh:Organic chemistryCoatingone-side access0103 physical sciencesComposite materialPenetration depthPolyurethane010302 applied physicsPolytetrafluoroethylenepolyurethane foamscapacitive sensorGeneral Chemistryprotectionpolyurethane foams; dielectric permittivity; capacitive sensor; one-side access; adverse effects; protection; PTFE films021001 nanoscience & nanotechnologychemistryPTFE filmsElectrodeadverse effectsengineering0210 nano-technologyPolymers
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Finite element analysis of a Bionate ring-shaped customized lumbar disc nucleus prosthesis

2021

[EN] Study design: Biomechanical study of a nucleus replacement with a finite element model. Objective: To validate a Bionate 80A ring-shaped nucleus replacement. Methods: The ANSYS lumbar spine model made from lumbar spine X-rays and magnetic resonance images obtained from cadaveric spine specimens were used. All materials were assumed homogeneous, isotropic, and linearly elastic. We studied three options: intact spine, nucleotomy, and nucleus implant. Two loading conditions were evaluated at L-3-L-4, L-4-L-5, and L-5-S-1 discs: a 1000 N axial compression load and this load after the addition of 8 Nm flexion moment in the sagittal plane plus 8 Nm axial rotation torque. Results: Maximum nuc…

finite element modelLumbar VertebraeINGENIERIA MECANICABiochemistry (medical)Finite Element AnalysisBiomedical EngineeringArtificial LimbsGeneral Chemistrymotion preservationArticleBiomechanical PhenomenaBiomaterialsdisc herniapolycarbonate urethanedegenerative disc diseaseHumansCirurgia Aparells i instrumentsRange of Motion Articularnucleus disc replacement
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Deviance detection in sound frequency in simple and complex sounds in urethane-anesthetized rats

2019

Mismatch negativity (MMN), which is an electrophysiological response demonstrated in humans and animals, reflects memory-based deviance detection in a series of sounds. However, only a few studies on rodents have used control conditions that were sufficient in eliminating confounding factors that could also explain differential responses to deviant sounds. Furthermore, it is unclear if change detection occurs similarly for sinusoidal and complex sounds. In this study, we investigated frequency change detection in urethane-anesthetized rats by recording local-field potentials from the dura above the auditory cortex. We studied change detection in sinusoidal and complex sounds in a series of …

medicine.medical_specialtyMismatch negativityhavaitseminenLocal field potentialBiologyStimulus (physiology)AudiologyAuditory cortexUrethane050105 experimental psychologyhäiriöt03 medical and health sciences0302 clinical medicinelocal-field potentialsotorhinolaryngologic diseasesmedicineAnimalsauditory cortex0501 psychology and cognitive scienceschange detectionAudio frequencyHuman studies05 social sciencestaajuusElectroencephalographykuuloSensory SystemsRatsratsElectrophysiologySoundaivokuoriAcoustic StimulationAuditory PerceptionEvoked Potentials Auditorymismatch negativityelektrofysiologiaääni (fysikaaliset ilmiöt)koe-eläinmallitärsykkeet030217 neurology & neurosurgeryChange detectionHearing Research
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Auditory cortical and hippocampal local-field potentials to frequency deviant tones in urethane-anesthetized rats: An unexpected role of the sound fr…

2015

Abstract The human brain can automatically detect auditory changes, as indexed by the mismatch negativity of event-related potentials. The mechanisms that underlie this response are poorly understood. We recorded primary auditory cortical and hippocampal (dentate gyrus, CA1) local-field potentials to serial tones in urethane-anesthetized rats. In an oddball condition, a rare (deviant) tone ( p  = 0.11) randomly replaced a repeated (standard) tone. The deviant tone was either lower (2200, 2700, 3200, 3700 Hz) or higher (4300, 4800, 5300, 5800 Hz) in frequency than the standard tone (4000 Hz). In an equiprobability control condition, all nine tones were presented at random ( p  = 0.11). Diffe…

medicine.medical_specialtyacoustic frequencyhippocampusMismatch negativityHippocampusLocal field potentialHippocampal formationAudiologyAuditory cortexUrethaneta3112Rats Sprague-DawleyTone (musical instrument)local-field potentialsprimary auditory cortexPhysiology (medical)medicineAnimalschange detectionta515Auditory CortexAnalysis of VarianceCommunicationAuditory maskingbusiness.industryGeneral NeuroscienceDentate gyrusRatsNeuropsychology and Physiological PsychologyAcoustic StimulationAuditory PerceptionEvoked Potentials AuditorybusinessPsychologyAnesthetics IntravenousPsychoacousticsInternational Journal of Psychophysiology
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Dressings and Securement Devices of Peripheral Arterial Catheters in Intensive Care Units and Operating Theaters

2020

Background: Hemodynamic monitoring, implemented by the placement of peripheral arterial catheters (PACs), is a characterizing aspect of the intensive care units. Peripheral arterial catheters can continually detect blood pressure and quickly conduct blood sampling. The use of PACs is generally considered safe, without serious complications. Currently, only 25% of the implanted catheters are actually subject to complications, including accidental removal, dislocation, occlusion, and infection. All of these complications arise from inadequate catheter stabilization at the level of the skin. This study aimed to summarize and describe the effectiveness and characteristics of dressings and secur…

medicine.medical_specialtydressingPolyurethanesMEDLINEEmergency NursingCritical Care Nursing03 medical and health sciencesCatheters Indwelling0302 clinical medicinenursingIntensive careCatheterization PeripheralmedicineHumansIntensive care medicine030504 nursingbusiness.industry030208 emergency & critical care medicineArterial catheterSettore MED/45 - Scienze Infermieristiche Generali Cliniche E PediatricheBandagesIntensive Care UnitsCatheterSystematic reviewICU0305 other medical sciencebusinessArterial CatheterBlood samplingDimensions of Critical Care Nursing
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The Effects of Epinine on Arterial Blood Pressure and Regional Vascular Resistances in Anesthetized Rats

1998

1. We carried out experiments in anesthetized rats to study the hemodynamic effects of intravenous injections of epinine. 2. Epinine (1-320 micrograms/kg) produced a biphasic effect on mean arterial blood pressure (n = 30). At doses lower than 40 micrograms/kg, arterial blood pressure decreased (by as much as 21.5 +/- 3.4%), though at higher doses it increased dose dependently (by as much as 73.2 +/- 14.5%). Epinine also produced bradicardia in a dose-dependent manner (by as much as 26.4 +/- 4.9%). Sulpiride (100 micrograms/kg) suppressed the hypotensive effect of epinine but did not change the hypertensive effect. In the presence of prazosin (1,000 micrograms/kg), arterial blood pressure r…

medicine.medical_specialtymedicine.medical_treatmentHemodynamicsBlood PressureAntiarrhythmic agentUrethaneRenal CirculationHeart RateInternal medicinemedicinePrazosinAnimalsSplanchnic CirculationRats WistarPharmacologybusiness.industryBlood flowRatsDeoxyepinephrinemedicine.anatomical_structureBlood pressureEndocrinologyDopamine AgonistsCirculatory systemVascular resistanceVascular ResistanceSulpiridebusinessAnesthetics Intravenousmedicine.drugGeneral Pharmacology: The Vascular System
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Encapsulation of AgNPs in a Lignin Isocyanate Film : Characterization and Antimicrobial Properties

2023

Lignin isolated from agricultural residues is a promising alternative for petroleum-based polymers as feedstocks in development of antimicrobial materials. A polymer blend based on silver nanoparticles and lignin–toluene diisocyanate film (AgNPs–Lg–TDIs) was generated from organosolv lignin and silver nanoparticles (AgNPs). Lignin was isolated from Parthenium hysterophorus using acidified methanol and used to synthesize lignin capped silver nanoparticles. Lignin–toluene diisocyanate film (Lg–TDI) was prepared by treating lignin (Lg) with toluene diisocyanate (TDI) followed by solvent casting to form films. Functional groups present and thermal properties of the films were evaluated using Fo…

silver nanoparticlespolyurethane filmshopealigninligniininanohiukkasetpolyuretaani
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