Search results for "VISCOSITY"

Shear Thinning: Determination of Zero‐Shear Viscosities from Measurements in the Non‐Newtonian Region

2020

Solvent hydrodynamics speed up crystal nucleation in suspensions of hard spheres

2014

We present a computer simulation study on the crystal nucleation process in suspensions of hard spheres, fully taking into account the solvent hydrodynamics. If the dynamics of collodial crystallization were purely diffusive, the crystal nucleation rate densities would drop as the inverse of the solvent viscosity. However, we observe that the nucleation rate densities do not scale in this way, but are enhanced at high viscosities. This effect might explain the large discrepancy between the nuclation rate densities obtained by simulation and experiment that have reported in the literature so far.

TeO2 liquid phase: Viscosity measurements and evaluation of the thermal conductivity from crystal growth experiments

2008

Current applications of paratellurite TeO{sub 2} in optics and nuclear physics require improving the yield and optical quality of synthesized single crystals. Modelling of the growth process is a useful tool for such purpose, however, involving the knowledge of several thermodynamic parameters of both solid and liquid phase of the compound. This work describes the determination of two main unknown ones, namely dynamic viscosity {eta} and thermal conductivity {lambda}{sub l} of the liquid phase. Measurements of {eta} are performed by means of a specifically designed apparatus; over a 40 K temperature interval above the melting point we find a mean value of 0.028 Pa.s. This data is used in co…

Fibre break processes in unidirectional composites

2014

International audience; A model to predict the effects of the accumulation of fibre breakages in unidirectional carbon fibre composites has been developed that takes into account several physical phenomena controlling fibre failure, including the stochastic nature of fibre strength, stress transfer between fibres due to the shear of the matrix, interfacial debonding and viscosity of the matrix. The damage processes leading up to failure are discussed and quantified, first in terms of fibre breaks for the case of monotonically increasing tensile loading, then for sustained loading and finally the implications for more complex loads and structures are discussed. It is clearly shown that the f…

Investigation and modeling of the anomalous yield point phenomenon in pure tantalum

2014

International audience; The monotonic and cyclic behavior of commercially pure tantalum has been investigated at room temperature, in order to capture and understand the occurrence of the anomalous yield point phenomenon. Interrupted tests have been performed, with strain reversals (tensile or compressive loading) after an aging period. The stress drop is attributed to the interactions between dislocations and solute atoms (oxygen) and its macroscopic occurrence is not systematically observed. InfraRed Thermography (IRT) measurements supported by Scanning Electron Microscopy (SEM) pictures of the polished gauge length of a specimen during an interrupted tensile test reveal the nucleation an…

Quality control of manufacturing and hot storage of crumb rubber modified binders

2020

The ultimate performance of crumb rubber modified (CRM) binders is linked to the accurate control of the properties during manufacturing and hot storage. However, due to their complexity, asphalt technologists find the characterisation of these materials still challenging. In this study, the adoption of a Dual Helical Ribbon (DHR), a novel mixing/measuring device for rotational viscometers, is proposed for the real-time monitoring of CRM binders during manufacturing and hot storage. According to the laboratory results, manufacturing periods of 45-60 min at 195 degrees, as well as storage temperatures not exceeding 150 degrees C, are recommended for this type of modified binders. (C) 2019 El…

Navier-Stokes equations on an exterior circular domain: construction of the solution and the zero viscosity limit

1997

Abstract In this Note, we consider the limit of Navier-Stokes equations on a circular domain. By an explicit construction of the solution, it is proved that, when viscosity goes to zero, solution converges to the Euler solution outside the boundary layer and to the Prandtl solution inside the boundary layer.

Optimal Impulse Control When Control Actions Have Random Consequences

1997

We consider a generalised impulse control model for controlling a process governed by a stochastic differential equation. The controller can only choose a parameter of the probability distribution of the consequence of his control action which is therefore random. We state optimality results relating the value function to quasi-variational inequalities and a formal optimal stopping problem. We also remark that the value function is a viscosity solution of the quasi-variational inequalities which could lead to developments and convergence proofs of numerical schemes. Further, we give some explicit examples and an application in financial mathematics, the optimal control of the exchange rate…

Verzweigungsgrad und viskositätszahl bei polystyrolen

1961

Das Quadrat des Tragheitsradius r2 eines verzweigten Molekuls ist gegenuber dem des unverzweigten Molekuls r02 um den Faktor g = r2/r02 herabgesetzt. Hieraus ergibt sich nach ZIMM und KILB eine Verringerung der Viskositatszahl (STAUDINGER-Index) um den Betrag Diese Beziehung wird an Polystyrolen verschiedenen Verzweigungsgrades nachgepruft. Hierzu werden trifunktionell verzweigte Polystyrole mit definiertem Verzweigungsgrad hergestellt. Die relative Ubertragungskonstante am Polystyrol wurde fruher durch reaktionskinetische Messungen zu Cpol = 1,9·10−4 bei 60°C bestimmt. Die Kenntnis dieser Grose ermoglicht es, durch thermische Polymerisation bis zu verschieden hohen Umsatzen unverzweigte Po…

Computer Simulations of the Dynamics of Amorphous Silica

1999

We present the results of a large scale computer simulation we performed to investigate the dynamical properties of supercooled silica. We show that parallel supercomputers such as the CRAY-T3E are very well suited to solve these type of problems. We find that at low temperatures the transport properties such as the diffusion constants and the viscosity agree well with the experimental data. At high temperatures this simulation predicts that in the transport quantities significant deviations from the Arrhenius law should be observed. Finally we show that such types of simulations can be used to investigate also complex dynamical quantities, such as the dynamical structure factor, and that t…