Search results for "VOLUME"

Energy intensity of treating drinking water: Understanding the influence of factors

2017

Abstract To provide safe drinking water to urban populations, raw water must be treated in drinking water treatment plants, which are energy-intensive facilities. Previous studies have assessed energy intensity (EI: unit of energy required per unit of treated water) of conventional drinking water treatment plants, but they ignored variations related to water treatment trains. By modeling 179 facilities of four water treatment trains, we explored factors potentially affecting energy intensity, such as removal efficiencies of pollutants and treatment capacities of drinking water treatment plants. We also investigated the economies of scale in energy intensity of drinking water treatment plant…

Global patterns of polycyclic aromatic hydrocarbons (PAHs) in soil

2007

Abstract Recent findings suggest a higher natural contribution to PAH concentrations in soil than previously thought. I hypothesized that the PAH pattern in soil is dominated by two main types, which are indicative of background conditions on the one side (i.e., by biological and diffuse PAHs) and a strong impact by atmospheric deposition of anthropogenic emissions on the other side. To test this hypothesis, concentrations of 20 PAHs in 225 topsoil samples from 12 geographic regions were evaluated. The Σ20PAHs concentrations ranged between 4.8 and 186,000 μg kg− 1. In soils with low concentrations of Σ20PAHs, naphthalene (NAPH), phenanthrene (PHEN), and perylene (PERY), together defined as …

Characteristics of current roadside pollution using test-monitoring plots

2014

Abstract The aim of the study was the qualitative recognition of the existing roadside pollutants deposited in topsoils located close to roads with high traffic volume. So far, the studies have helped to determine the content of pollutants that accumulated over a long period of time. Traditionally, it has been difficult to distinguish between roadside pollution and pollution from other industrial sources. In order to avoid such problems and to accurately recognize present threats originating from road traffic, test-monitoring plots were installed in Poland (Gliwice and Opole), Germany (Tubingen, Ulm and Boblingen), Finland (Helsinki), Tajikistan (Dushanbe) and China (Lanzhou). To install th…

2019

Lamella-forming ABC triblock terpolymers are convenient building blocks for the synthesis of soft Janus nanoparticles (JNPs) by crosslinking the B domain that is “sandwiched” between A and C lamellae. Despite thorough synthetic variation of the B fraction to control the geometry of the sandwiched microphase, so far only Janus spheres, cylinders, and sheets have been obtained. In this combined theoretical and experimental work, we show that the blending of polybutadiene homopolymer (hPB) into lamella morphologies of polystyrene-block-polybutadiene-block-polymethylmethacrylate (SBM) triblock terpolymers allows the continuous tuning of the polybutadiene (PB) microphase. We systematically vary …

Enthalpy and Entropy Contributions to Solvent Quality and Inversions of Heat Effects with Polymer Concentration

2006

Vapor pressures above the solutions of polystyrene in either cyclohexane (32-60 °C) or toluene (10-70 °C) have been measured by a combination of head space sampling and gas chromatography as a function of the volume fraction φ of the polymer. The thus obtained Flory-Huggins interaction parameters Χ (φ; T) were complemented by data for three other systems (tert-butyl acetate/polystyrene, cyclohexane/poly(vinyl methyl ether), 2-propanol/poly(butyl methacrylate)) reported in the literature and analyzed in terms of their enthalpy and entropy parts Χ H and Χ s . Furthermore these experimental findings were modeled by means of an approach splitting the mixing process conceptually into two parts a…

Structure of Polymer Brushes in Cylindrical Tubes: A Molecular Dynamics Simulation

2006

Molecular Dynamics simulations of a coarse-grained bead-spring model of flexible macromolecules tethered with one end to the surface of a cylindrical pore are presented. Chain length $N$ and grafting density $\sigma$ are varied over a wide range and the crossover from ``mushroom'' to ``brush'' behavior is studied for three pore diameters. The monomer density profile and the distribution of the free chain ends are computed and compared to the corresponding model of polymer brushes at flat substrates. It is found that there exists a regime of $N$ and $\sigma$ for large enough pore diameter where the brush height in the pore exceeds the brush height on the flat substrate, while for large enoug…

Calorimetric and Volumetric Investigations of the Effect of the Hydrophobicity of the Surfactant on the Binding between (Ethylene oxide)13-(propylene…

2004

The enthalpy and the volume of transfer (DeltaY(t)) of the unassociated (ethylene oxide)(13)-(propylene oxide)(30)-(ethylene oxide)(13) (L64) from water to the aqueous sodium alkanoate solutions as functions of the surfactant concentrations (m(S)) were determined at 298 K. The surfactants studied are sodium hexanoate, sodium heptanoate, sodium octanoate, sodium undecanoate, and sodium dodecanoate. As a general feature, for the short alkyl chain surfactants, DeltaY(t) describes an S-shaped curve in the range of m(S) analyzed whereas for the more hydrophobic surfactants the DeltaY(t) vs m(S) trends exhibit maxima which appear at ms values very close to the critical micellar concentration in w…

Model of the mechanical response of short flax fiber reinforced polymer matrix composites

2011

Abstract Natural-fiber-reinforced short-fiber composites are finding more applications lately, therefore there is a need for estimation of the mechanical properties of such composites based on the properties of the constituents. The fibers themselves also possess complicated internal structure, resulting in anisotropy of their properties. Taking into account the internal structure of bast fiber, we evaluate the elastic properties of a composite unit cell, consisting of a fiber of average length and matrix according to the fiber volume fraction in the composite. The unit cell properties are used to estimate the stiffness of a misaligned short-fiber composite by means of orientation averaging…

Time–temperature correspondence prediction of stress relaxation of polymeric materials from a minimum of data

2002

Abstract We have determined the stress relaxation of a longitudinal polymer liquid crystal (PLC), polypropylene and their blends containing 10 and 20% of the PLC at the constant strain of 0.5%. The results for nine temperature levels in the range between 20 and 100 °C were used to create master curves for T ref =20 ° C . The temperature shift factors aT were calculated using a general formula derived by one of us and based on free volume vf and the chain relaxation capability model. The predicted values agree with the experimental ones for all materials studied within limits of the experimental accuracy. Moreover, the relation between the shift factor aT and the reduced volume ṽ has been us…

Chapter 8 Native and Bonded Silicas in Aqueous Sec

1988

Publisher Summary This chapter deals with the properties of packings and columns in correlation to chromatographic separations in size exclusion chromatography (SEC) and provides guidelines for optimum support design. The chapter provides a survey of the current state-of-the-art with respect to the surface modification of silica for SEC packings in aqueous eluents. The properties of commercial packings and columns are listed and compared. An advice is also discussed on the operation and maintenance of columns with a view to achieving high resolution and long life-time. In SEC, solute elution is based on equilibrium, entropy­-controlled size exclusion process. According to their size, the so…