Search results for "VOLUME"

Stress path dependence of hydromechanical behaviour of compacted scaly clay in wetting and drying suction controlled oedometer tests at constant vert…

2008

The results are presented of an experimental programme devoted to investigating the volumetric strain and water ratio (volume of water to volume of solids) evolution of a compacted scaly clay stressed by wetting and drying cycles in suction-controlled oedometer tests. The stress paths applied included loading and unloading cycles at constant matric suction and suction controlled wetting-drying cycles at constant vertical net stress. The test results show that during wetting and drying cycles the samples experienced irreversible shrinkage or swelling strains depending on the stress path applied. Irreversible water ratio increases were always observed in these cycles. However, a quasi-reversi…

Volume change behaviour of a compacted scaly clay during cyclic suction changes

2010

The research presented in this paper focuses on the investigation and modelling of the volume change response of compacted tectonised clay samples subjected to several wetting and drying cycles in controlled-suction oedometers. Oedometer tests were carried out under different values of constant vertical net stress, and wetting and drying cycles were performed varying applied matric suction between 10 and 800 kPa. The investigation was complemented with a study of the material microstructure to support the interpretation of the overall mechanical response. At a microscopic level, the material is characterized by different types of particle assemblages, scales, and clay aggregates. One of th…

Experimental analysis of the water retention behaviour of shales

2014

Shales are among the most commonly considered geomaterials in current energy-related geomechanical investigations, as they are involved in engineering applications such as the unconventional extraction of natural gas, CO2 sequestration and nuclear waste geological storage. A deep understanding of their behaviour with regard to variations in the degree of saturation is of primary significance for such applications. With the aim to establish a sound protocol for shale retention behaviour analysis, this paper presents an advanced experimental methodology that takes into account the specificities of shales such as small pore size dimensions and the large variations in water potential to be appl…

Direct Metal‐Free Chemical Vapor Deposition of Graphene Films on Insulating Substrates for Micro‐Supercapacitors with High Volumetric Capacitance

2019

Direct, metal‐free synthesis of graphene films on insulating substrates in a controlled manner is of great importance for applications in (opto)electronic and energy storage devices. Graphene films are fabricated on fused silica substrates without metal catalyst via chemical vapor deposition (CVD), using propionic acid as a carbon source. Film‐thickness is readily adjustable between 5 and 45 nm by changing the deposition time and flow rate of the precursor, displaying sheet resistance in the range of 0.27–1.86 kΩ□−1. The resulting graphene films are directly integrated into micro‐supercapacitors without film transfer or liquid‐phase processing, and demonstrate ultrahigh operation rates up t…

Cover Picture: Direct Metal‐Free Chemical Vapor Deposition of Graphene Films on Insulating Substrates for Micro‐Supercapacitors with High Volumetric …

2019

Effective recovery of perfluoropolyether surfactants from PVDF and PTFE by supercritical carbon dioxide extraction

2007

Abstract The extraction of ammonium carboxylate perfluoropolyether surfactants from poly(vinylidenefluoride) (PVDF) and poly(tetrafluoroethylene) (PTFE) was performed with supercritical carbon dioxide. When proper conditions in terms of temperature, pressure and flow rate were used, extraction recoveries higher than 90% were obtained. For PVDF (with a concentration of surfactant of 5% w/w), at low pressure (12 MPa) and 40 °C, more than 100 min are necessary to have a quantitative extraction. On the other hand, at higher pressure (20 MPa) a quantitative recovery was obtained after few minutes. A strong influence of the temperature on the extraction recovery was also found. In the case of PTF…

Ripening-dominated crystallization in polydisperse hard-sphere-like colloids

2009

We report on the crystal growth scenario in gravity-matched, polydisperse hard-sphere-like colloids at increasing particle concentration. In the fluid-crystal coexistence region, the crystal size as a function of time shows two separate regimes corresponding to crystal growth and crystal ripening. At higher supersaturation the crystal size grows according to the same power law through the whole experimental window of a few days: crystal growth and ripening merge together. We show that our observations cannot be explained by considering the slowing down of single-particle dynamics due to increasing volume fraction. We suggest that size fractionation occurring at the crystal-fluid interface i…

CFD Simulation of Particle Distribution in a Multiple-impeller High-Aspect-Ratio Stirred Vessel

2000

Publisher Summary This chapter describes fully predictive simulations of solid–liquid suspensions in a high-aspect-ratio, multiple-impeller stirred tank. These are performed by using the Inner Outer impeller modeling technique coupled with the Multi Fluid Model (MFM) for the treatment of the dispersed phase. The strongly simplified Settling Velocity Model (SVM) is also tested. The effects of free-stream turbulence on the drag coefficient CD and particle settling velocity are accounted for by means of a recently proposed correlation. Comparison of simulation results with experimental particle concentration profiles shows that the MFM approach leads to fair agreement with experimental data. R…

Size and shape effects on the thermodynamic properties of nanoscale volumes of water

2017

Small systems are known to deviate from the classical thermodynamic description, among other things due to their large surface area to volume ratio compared to corresponding big systems. As a consequence, extensive thermodynamic properties are no longer proportional to the volume, but are instead higher order functions of size and shape. We investigate such functions for second moments of probability distributions of fluctuating properties in the grand-canonical ensemble, focusing specifically on the volume and surface terms of Hadwiger's theorem, explained in Klain, Mathematika, 1995, 42, 329–339. We resolve the shape dependence of the surface term and show, using Hill's nanothermodynamics…

GEPOL: An improved description of molecular surfaces. III. A new algorithm for the computation of a solvent-excluding surface

1994

To understand and calculate the interactions of a solute with a solvent, a good method of computing the molecular surface is needed. Three kinds of surfaces may be used: the van der Waals Surface, the Accessible Surface, and the Molecular Surface. The latter is redefined in this article as the Solvent-Excluding Surface. The new algorithm for computing the Solvent-Excluding Surface included in the GEPOL93 program is described. GEPOL93 follows the same concept as former versions of GEPOL but with a full new algorithm. Thus, it computes the Solvent-Excluding Surface by filling the spaces not accessible to the solvent with a set of new spheres. The computation is controlled by three parameters:…